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We determine the stability, the geometry, the electronic and magnetic structure of hydrogen-terminated graphene-nanoribbons edges as a function of the hydrogen content of the environment by means of density functional theory.…

Materials Science · Physics 2008-08-28 Tobias Wassmann , Ari P. Seitsonen , A. Marco Saitta , Michele Lazzeri , Francesco Mauri

We present a comprehensive study of graphene grown by chemical vapor deposition on copper single crystals with exposed (100), (110) and (111) faces. Direct examination of the as-grown graphene by Raman spectroscopy using a range of visible…

Mesoscale and Nanoscale Physics · Physics 2014-02-03 Otakar Frank , Jana Vejpravova , Vaclav Holy , Ladislav Kavan , Martin Kalbac

We use density functional theory to determine the equilibrium shape of graphene flakes, through the calculation of the edge orientation dependence of the edge energy and edge stress of graphene nanoribbons. The edge energy is a nearly…

Mesoscale and Nanoscale Physics · Physics 2011-08-08 Chee Kwan Gan , David J. Srolovitz

Efforts aimed at scaling fabrication processes to the level of single atoms, dubbed atom-by-atom fabrication or atomic fabrication, invariably encounter the obstacle of atomic scale cleanliness. When considering atomic fabrication,…

Materials Science · Physics 2024-12-03 Ondrej Dyck , Aisha Okmi , Kai Xiao , Sidong Lei , Andrew R. Lupini , Stephen Jesse

We report the synthesis and evidence of graphene fluoride, a two-dimensional wide bandgap semiconductor derived from graphene. Graphene fluoride exhibits hexagonal crystalline order and strongly insulating behavior with resistance exceeding…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 S. -H. Cheng , K. Zou , F. Okino , H. R. Gutierrez , A. Gupta , N. Shen , P. C. Eklund , J. O. Sofo , J. Zhu

We observe mechanical effects of an exfoliated graphene monolayer deposited on a quartz crystal substrate designed to operate as an extremely low-loss bulk-acoustic-wave cavity at liquid-helium temperature.This is achieved by sensing…

The electronic structure, bonding and magnetism in graphene containing vacancies are studied using density-functional methods. The single-vacancy graphene ground state is spin polarized and structurally flat. The unpolarized state is non…

Mesoscale and Nanoscale Physics · Physics 2008-07-11 M. W. C. Dharma-wardana , Marek Z. Zgierski

Graphene placed in a magnetic field possesses an extremely high mid/far-infrared optical nonlinearity originating from its unusual band structure and selection rules for the optical transitions near the Dirac point. Here we study the linear…

Mesoscale and Nanoscale Physics · Physics 2016-11-26 Xianghan Yao , Alexey Belyanin

Here we report chemical vapor deposition of graphene on gold surface at ambient pressure. We studied effects of the growth temperature, pressure and cooling process on the grown graphene layers. The Raman spectroscopy of the samples reveals…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Tuba Oznuluer , Ercag Pince , Emre O. Polat , Osman Balci , Omer Salihoglu , Coskun Kocabas

Graphene is well known to grow as flat sheets aligned with the growth substrate. Oriented graphene structures typically normal to the substrate have recently gained major attention. Most often, normal orientation is achieved in…

Materials Science · Physics 2022-06-07 Subrata Ghosh , S. R. Polaki , M. Kamruddin , Sang Mun Jeong , Kostya , Ostrikov

We develop a density matrix formalism in the length gauge to calculate the nonlinear response of intrinsic monolayer graphene at terahertz frequencies. Employing a tight-binding model, we find that the interplay of the interband and…

Optics · Physics 2014-12-17 Ibraheem Al-Naib , J. E. Sipe , Marc M. Dignam

Using atomistic simulations we determine the roughness and the thermal properties of a suspended graphane sheet. As compared to graphene we found that hydrogenated graphene has: 1) a larger thermal contraction, 2) the roughness exponent at…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 M. Neek-Amal , F. M. Peeters

We performed a first principles investigation on the structural and electronic properties of group-IV (C, SiC, Si, Ge, and Sn) graphene-like sheets in flat and buckled configurations and the respective hydrogenated or fluorinated…

Materials Science · Physics 2012-04-16 Joelson Cott Garcia , Denille B. de Lima , Lucy V. C. Assali , João F. Justo

The mechanical and electronic properties of a graphene membrane placed on top of a superlattice of nanopillars are investigated. We use molecular dynamics (MD) simulations to access the deformation fields and the tight-binding approaches to…

Mesoscale and Nanoscale Physics · Physics 2019-02-20 S. P. Milovanovic , L. Covaci , F. M. Peeters

Chemically doped graphene could support plasmon excitations up to telecommunication or even visible frequencies. Apart from that, the presence of dopant may influence electron scattering mechanisms in graphene and thus impact the plasmon…

Materials Science · Physics 2017-10-06 Dino Novko

We study the effects of insulating oxides in their crystalline forms on the energy band structure of monolayer and bilayer graphene using a \textit{first principles} density functional theory based electronic structure method and a local…

Materials Science · Physics 2011-12-09 Priyamvada Jadaun , Sanjay K. Banerjee , Leonard F. Register , Bhagawan Sahu

Spatially nonuniform strain is important for engineering the pseudomagnetic field and band structure of graphene. Despite the wide interest in strain engineering, there is still a lack of control on device-compatible strain patterns due to…

Results of a study on the electrochemical properties of exfoliated single and multilayer graphene flakes are presented. Graphene flakes were deposited on silicon/silicon oxide wafers to enable fast and accurate characterization by optical…

Mesoscale and Nanoscale Physics · Physics 2011-10-11 Anna T. Valota , Ian A. Kinloch , Kostya S. Novoselov , Cinzia Casiraghi , Axel Eckmann , Ernie W. Hill , Robert A. W. Dryfe

Graphene is the stiffest material known so far but, due to its one-atom thickness, it is also very bendable. Consequently, free-standing graphene exhibit ripples that has major effects on its elastic properties. Here we will summarize three…

Materials Science · Physics 2021-07-01 Guillermo Lopez-Polin , Cristina Gomez-Navarro , Julio Gomez-Herrero

Experimental and theoretical results on chemical functionalization of graphene are reviewed. Using hydrogenated graphene as a model system, general principles of the chemical functionalization are formulated and discussed. It is shown that,…

Materials Science · Physics 2009-01-05 D. W. Boukhvalov , M. I. Katsnelson
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