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We introduce a new functional for simulating ground-state and time-dependent electronic systems within density-functional theory. The functional combines an expression for the exact Kohn-Sham (KS) potential in the limit of complete electron…

Mesoscale and Nanoscale Physics · Physics 2021-01-15 M. J. P. Hodgson , J. D. Ramsden , T. R. Durrant , R. W. Godby

In this work we study in a formal way the density dependent hadron field theory at finite temperature for nuclear matter. The thermodynamical potential and related quantities, as energy density and pressure are derived in two different…

Nuclear Theory · Physics 2008-11-26 S. S. Avancini , M. E. Bracco , M. Chiapparini , D. P. Menezes

The one-body density matrix is derived within the Extended Thomas-Fermi approximation. This has been done starting from the Wigner-Kirkwood distribution function for a non-local single-particle potential. The links between this new approach…

Nuclear Theory · Physics 2009-10-31 V. B. Soubbotin , X. Vinas

Within exact electron density-functional theory, we investigate Kohn-Sham (KS) potentials, orbital energies, and non-interacting kinetic energies of the fractional ions of Li, C and F. We use quantum Monte Carlo densities as input, which…

Chemical Physics · Physics 2014-11-14 Tim Gould , Julien Toulouse

The density-functional (DF) theory provides a simple method for calculating the properties of an interacting system under an external potential by associating it with a corresponding non-interacting system. Here, we find some relations in…

Chemical Physics · Physics 2009-11-10 Junzo Chihara , Mitsuru Yamagiwa

The properties of warm symmetric and asymmetric nuclear matter are investigated in the frame of the Thomas-Fermi approximation using a recent modern parametrization of the effective nucleon-nucleon interaction of Myers and Swiatecki.…

Nuclear Theory · Physics 2015-06-26 Klaus Strobel , Fridolin Weber , Manfred K. Weigel

A long-standing puzzle in density-functional theory is the issue of the long-range behavior of the Kohn-Sham exchange-correlation potential at metal surfaces. As an important step towards its solution, it is proved here, through a rigurouos…

Materials Science · Physics 2015-05-18 C. M. Horowitz , C. R. Proetto , J. M. Pitarke

Correlation functions related to the dynamic density response of the one-dimensional Bose gas in the model of Lieb and Liniger are calculated. An exact Bose-Fermi mapping is used to work in a fermionic representation with a pseudopotential…

Statistical Mechanics · Physics 2007-05-23 Alexander Yu. Cherny , Joachim Brand

We present a non-perturbative regularization scheme for Quantum Field Theories which amounts to an embedding of the originally unregularized theory into a spacetime with an extra compactified dimensions of length L ~ Lambda^{-1} (with…

High Energy Physics - Theory · Physics 2009-11-07 C. D. Fosco , F. A. Schaposnik

A new approach to quantum field theory at finite temperature and density in arbitrary space-time dimension D is developed. We focus mainly on relativistic theories, but the approach applies to non-relativistic ones as well. In this…

High Energy Physics - Theory · Physics 2009-11-10 Andre LeClair

This article generalizes the notion of the local density of a many-body system to introduce collective coordinates as explicit degrees of freedom. It is shown that the energy of the system can be expressed as a functional of this object.…

Nuclear Theory · Physics 2014-04-23 Thomas Lesinski

An approximate solution to the time-dependent density functional theory (TDDFT) response equations for finite systems is developed, yielding corrections to the single-pole approximation. These explain why allowed Kohn-Sham transition…

Materials Science · Physics 2009-11-07 H. Appel , E. K. U. Gross , K. Burke

We rely on a variational approach to derive a set of equations governing a trapped self-interacting Bose gas at finite temperature. In this work, we analyze the static situation both at zero and finite temperature in the Thomas-Fermi limit.…

Statistical Mechanics · Physics 2008-01-21 M. Benarous , H. Chachou Samet

Typical density functional theory (DFT) and approximations thereto solve the many-electron ground state problem by working from a numerically efficient non-interacting Kohn-Sham reference system; and benefit from useful minimization…

Chemical Physics · Physics 2025-04-02 Tim Gould

The energy spectra of atomic ions are re-examined from the point of view of Thomas-Fermi scaling relations. For the first ionization potential, which sets the energy scale for the true discrete spectrum, Thomas-Fermi theory predicts the…

Atomic Physics · Physics 2015-05-13 Robert Carcasses , Augusto Gonzalez

Thermal density functional theory calculations often use the Mermin-Kohn-Sham scheme, but employ ground-state approximations to the exchange-correlation (XC) free energy. In the simplest solvable nontrivial model, an asymmetric Hubbard…

Strongly Correlated Electrons · Physics 2016-06-29 Justin C Smith , Aurora Pribram-Jones , Kieron Burke

Thermal vibrations alter the external potential. Allen (Phys. Rev. B 18 (1978) 5217) proved that at finite temperatures the pseudopotential form factors are corrected by a Debye-Waller Factor (DWF). We generalize this result to the crystal…

Materials Science · Physics 2015-05-22 T. R. S. Prasanna , M. P. Gururajan

The exchange-correlation energy in Kohn-Sham density functional theory can be expressed exactly in terms of the change in the expectation of the electron-electron repulsion operator when, in the many-electron hamiltonian, this same operator…

Strongly Correlated Electrons · Physics 2009-08-05 Paola Gori-Giorgi , Giovanni Vignale , Michael Seidl

A previous analysis of scaling, bounds, and inequalities for the non-interacting functionals of thermal density functional theory is extended to the full interacting functionals. The results are obtained from analysis of the related…

Statistical Mechanics · Physics 2016-12-14 James W. Dufty , S. B. Trickey

In approximate Kohn-Sham density-functional theory, self-interaction manifests itself as the dependence of the energy of an orbital on its fractional occupation. This unphysical behavior translates into qualitative and quantitative errors…

Materials Science · Physics 2010-09-28 Ismaila Dabo , Andrea Ferretti , Nicolas Poilvert , Yanli Li , Nicola Marzari , Matteo Cococcioni
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