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While in principle exact, Kohn-Sham density functional theory -- the workhorse of computational chemistry -- must rely on approximations for the exchange-correlation functional. Despite staggering successes, present-day approximations still…

We showcase the advantages of orbital-free density-potential functional theory (DPFT), a more flexible variant of Hohenberg-Kohn density functional theory. DPFT resolves the usual trouble with the gradient-expanded kinetic energy functional…

Quantum Gases · Physics 2021-06-16 Martin-Isbjörn Trappe , Jun Hao Hue , Berthold-Georg Englert

Using the Thomas-Fermi approximation, we show that an interacting two dimensional electron gas may be described in terms of fractional exclusion statistics at zero and finite temperatures when the interaction has a short-range component. We…

Condensed Matter · Physics 2009-10-28 R. K. Bhaduri , M. V. N. Murthy , M. K. Srivastava

Time-dependent (current) density functional theory for many-electron systems strongly coupled to quantized electromagnetic modes of a microcavity is proposed. It is shown that the electron-photon wave function is a unique functional of the…

Mesoscale and Nanoscale Physics · Physics 2013-12-10 I. V. Tokatly

The self-energy functional theory (SFT) is generalized to describe the real-time dynamics of correlated lattice-fermion models far from thermal equilibrium. This is achieved by means of a reformulation of the original equilibrium theory in…

Strongly Correlated Electrons · Physics 2013-10-21 Felix Hofmann , Martin Eckstein , Enrico Arrigoni , Michael Potthoff

It seems self-evident that a density functional calculation should be normalized to the number of electrons in the system. We present multiple examples where the accuracy of the approximate energy is improved (sometimes greatly) by…

Chemical Physics · Physics 2026-03-13 Adam Clay , Kiril Datchev , Wenlan Miao , Adam Wasserman , Kimberly J. Daas , Kieron Burke

In this paper, we study a few theoretical issues in the discretized Kohn-Sham (KS) density functional theory (DFT). The equivalence between either a local or global minimizer of the KS total energy minimization problem and the solution to…

Computational Physics · Physics 2014-02-21 Xin Liu , Zaiwen Wen , Xiao Wang , Michael Ulbrich , Yaxiang Yuan

The dissociation of molecules, even the most simple hydrogen molecule, cannot be described accurately within density functional theory because none of the currently available functionals accounts for strong on-site correlation. This problem…

Strongly Correlated Electrons · Physics 2011-01-14 N. Helbig , I. V. Tokatly , A. Rubio

We study the minimizers of an energy functional with a self-consistent magnetic field, which describes a quantum gas of almost-bosonic anyons in the average-field approximation. For the homogeneous gas we prove the existence of the…

Mathematical Physics · Physics 2018-02-28 Michele Correggi , Douglas Lundholm , Nicolas Rougerie

For quantum fermion problems, many accurate solvers are limited by the temperature regime in which they can be usefully applied. The Mermin theorem implies the uniqueness of an effective potential from which both the exact density and free…

Chemical Physics · Physics 2018-09-12 Justin Clifford Smith , Kieron Burke

Density-functional theory is applied to compute the ground-state energies of quantum hard-sphere solids. The modified weighted-density approximation is used to map both the Bose and the Fermi solid onto a corresponding uniform Bose liquid,…

Statistical Mechanics · Physics 2009-10-30 A. R. Denton , P. Nielaba , N. W. Ashcroft

We propose a way to improve energy density functionals (EDFs) in the density functional theory based on the combination of the inverse Kohn--Sham method and the density functional perturbation theory. Difference between the known EDF and…

Chemical Physics · Physics 2019-11-22 Tomoya Naito , Daisuke Ohashi , Haozhao Liang

A survey on the dynamical and thermodynamical properties of plasmas with strong Coulomb interactions in the quasi-classical density-temperature region is given. First the basic theoretical concepts describing nonideality are discussed. The…

Plasma Physics · Physics 2009-10-31 W. Ebeling , J. Ortner

We study the form factors of local operators of integrable QFT's between states with finite energy density. These states arise, for example, at finite temperature, or from a generalized Gibbs ensemble. We generalize Smirnov's form factor…

High Energy Physics - Theory · Physics 2019-01-23 Axel Cortés Cubero , Miłosz Panfil

Due to efficient scaling with electron number N, density functional theory (DFT) is widely used for studies of large molecules and solids. Restriction of an exact mean-field theory to local potential functions has recently been questioned.…

Other Condensed Matter · Physics 2015-06-24 Robert K. Nesbet

We investigate the thermal properties of $\mathcal{PT}$-symmetric scalar field theories with purely imaginary couplings. The free energy governs the asymptotic density of states, providing an effective measure of the number of degrees of…

High Energy Physics - Theory · Physics 2026-04-10 Oleksandr Diatlyk , Andrei Katsevich , Fedor K. Popov

Exact density-functional theory is reconstructed here from its convex variational structure as two parallel exact ensemble hierarchies: an interacting hierarchy rooted in Lieb's ensemble formulation and a noninteracting hierarchy rooted in…

Chemical Physics · Physics 2026-05-01 Nan Sheng

A novel method to determine the density and temperature of a system based on quantum Fermionic fluctuations is generalized to the limit where the reached temperature T is large compared to the Fermi energy {\epsilon}f . Quadrupole and…

Nuclear Theory · Physics 2015-06-03 Hua Zheng , Aldo Bonasera

I introduce and discuss models of finite quark matter using the formalism of the Thomas-Fermi statistical model. Similar to bag models, a vacuum energy term is introduced to model long distance confinement, but the model produces bound…

High Energy Physics - Phenomenology · Physics 2009-06-23 Walter Wilcox

We investigate Fermi gases at finite temperature for which the in-medium effective mass may not be constant as a function of the density, the temperature, or the chemical potential. We suggest a formalism that separates the terms for which…

Nuclear Theory · Physics 2023-07-17 Mariana Dutra , Odilon Lourenço , Jérôme Margueron
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