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This paper studies an efficient numerical method for solving modified Poisson-Boltzmann (MPB) equations with the self Green's function as a state equation to describe electrostatic correlations in ionic systems. Previously, the most…

Computational Physics · Physics 2022-05-11 Yihui Tu , Qiyuan Pang , Haizhao Yang , Zhenli Xu

The modified Poisson-Boltzmann (MPB) equations are often used to describe equilibrium particle distribution of ionic systems. In this paper, we propose a fast algorithm to solve MPB equations with the self Green's function as the self…

Computational Physics · Physics 2023-07-04 Yihui Tu , Zhenli Xu , Haizhao Yang

Developing accurate solvers for the Poisson Boltzmann (PB) model is the first step to make the PB model suitable for implicit solvent simulation. Reducing the grid size influence on the performance of the solver benefits to increasing the…

Numerical Analysis · Mathematics 2016-07-18 Bao Wang , Guowei Wei

The size-modified Poisson-Boltzmann equation (SMPBE) is one important variant of the popular dielectric model, the Poisson-Boltzmann equation (PBE), to reflect ionic size effects in the prediction of electrostatics for a biomolecule in an…

Numerical Analysis · Mathematics 2016-10-21 Jinyong Ying , Dexuan Xie

We present the theory and implementation of a Poisson-Boltzmann implicit solvation model for electrolyte solutions. This model can be combined with arbitrary electronic structure methods that provide an accurate charge density of the…

Computational Physics · Physics 2020-01-08 Christopher J. Stein , John M. Herbert , Martin Head-Gordon

The Linearized Poisson--Boltzmann (LPB) equation is a popular and widely accepted model for accounting solvent effects in computational (bio-) chemistry. In the present article we derive the analytical forces of the…

Numerical Analysis · Mathematics 2023-09-14 Abhinav Jha , Michele Nottoli , Aleksandr Mikhalev , Chaoyu Quan , Benjamin Stamm

The ab-initio computational treatment of electrochemical systems requires an appropriate treatment of the solid/liquid interfaces. A fully quantum mechanical treatment of the interface is computationally demanding due to the large number of…

A numerical method using implicit surface representations is proposed to solve the linearized Poisson-Boltzmann equations that arise in mathematical models for the electrostatics of molecules in solvent. The proposed method used an implicit…

Numerical Analysis · Mathematics 2018-04-04 Yimin Zhong , Kui Ren , Richard Tsai

We show that classical molecular density functional theory (MDFT), here in the homogeneous reference fluid approximation in which the functional is inferred from the properties of the bulk solvent, is a powerful new tool to study, at a…

The multipole-expansion (MPE) model is an implicit solvation model used to efficiently incorporate solvent effects in quantum chemistry. Even within the recent direct approach, the multipole basis used in MPE to express the dielectric…

Chemical Physics · Physics 2021-12-10 Jakob Filser , Karsten Reuter , Harald Oberhofer

A Green's function based solver for the modified Bessel equation has been developed with the primary motivation of solving the Poisson equation in cylindrical geometries. The method is implemented using a Discrete Hankel Transform and a…

Numerical Analysis · Mathematics 2011-10-11 Michael Carley

A new method is presented for solving Poisson's equation inside an open-ended rectangular pipe. The method uses Fast Fourier Transforms (FFTs) to perform mixed convolutions and correlations of the charge density with the Green function.…

Accelerator Physics · Physics 2011-11-22 Robert D. Ryne

Poisson-Boltzmann (PB) model is one of the most popular implicit solvent models in biophysical modeling and computation. The ability of providing accurate and reliable PB estimation of electrostatic solvation free energy, $\Delta…

Biomolecules · Quantitative Biology 2016-06-10 Duc D. Nguyen , Bao Wang , Guo-wei Wei

Physics-informed neural networks (PINN) is a machine learning (ML)-based method to solve partial differential equations that has gained great popularity due to the fast development of ML libraries in the last few years. The…

Chemical Physics · Physics 2024-12-31 Martin A. Achondo , Jehanzeb H. Chaudhry , Christopher D. Cooper

We present a soft-potential-enhanced Poisson-Boltzmann (SPB) theory to efficiently capture ion distributions and electrostatic potential around rodlike charged macromolecules. The SPB model is calibrated with a coarse-grained particle-based…

Soft Condensed Matter · Physics 2022-06-07 Hossein Vahid , Alberto Scacchi , Xiang Yang , Tapio Ala-Nissila , Maria Sammalkorpi

The pointwise space-time behaviors of the Green's function and the global solution to the modified Vlasov- Poisson-Boltzmann (mVPB) system in one-dimensional space are studied in this paper. It is shown that, the Green's function admits the…

Analysis of PDEs · Mathematics 2023-03-29 Yanchao Li , Mingying Zhong

Monte Carlo (MC) methods are important computational tools for molecular structure optimizations and predictions. When solvent effects are explicitly considered, MC methods become very expensive due to the large degree of freedom associated…

Biomolecules · Quantitative Biology 2022-02-09 Jiahui Chen , Weihua Geng , Guo-Wei Wei

To accurately model the electron density and polarization, a polarizable multipole (PM) model using the AMOEBA force field has been introduced \cite{Ren:2003, Shi:2013} recently. In the AMOEBA force field, the traditional point atomic…

Mathematical Physics · Physics 2025-11-05 Xin Yang , Shan Zhao , Weihua Geng

The Poisson-Boltzmann equation is a widely used model to study the electrostatics in molecular solvation. Its numerical solution using a boundary integral formulation requires a mesh on the molecular surface only, yielding accurate…

Numerical Analysis · Mathematics 2020-09-25 Vicente Ramm , Jehanzeb H. Chaudhry , Christopher D. Cooper

The behavior of electrolyte solutions close to a charged surface is studied theoretically. A modified Poisson-Boltzmann equation which takes into account the volume excluded by the ions in addition to the electrostatic interactions is…

Soft Condensed Matter · Physics 2007-05-23 I. Borukhov , D. Andelman , H. Orland
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