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We report that the surface conductivity of Na$_{2}$IrO$_3$ crystal is extremely tunable by high energy Ar plasma etching and can be tuned from insulating to metallic with increasing etching time. Temperature dependent electrical transport…

Strongly Correlated Electrons · Physics 2017-05-29 Kavita Mehlawat , Yogesh Singh

The honeycomb lattice iridate Na$_2$IrO$_3$ shows frustrated magnetism and can potentially display Kitaev-like exchange interactions. Recently, it was shown that the electronic properties of the surface of crystalline Na$_2$IrO$_3$ can be…

Materials Science · Physics 2018-09-25 Aastha Vasdev , Lalit Yadav , Suman Kamboj , Kavita Mehlawat , Yogesh Singh , Goutam Sheet

The Kitaev model of spin-1/2 on a honeycomb lattice supports degenerate topological ground states and may be useful in topological quantum computation. Na$_{2}$IrO$_{3}$ with honeycomb lattice of Ir ions have been extensively studied as…

Materials Science · Physics 2018-10-03 Kaige Hu , Zhimou Zhou , Yi-Wen Wei , Chao-Kai Li , Ji Feng

We have investigated experimentally and theoretically the series (Na$_{1-x}$Li$_{x}$)$_{2}$IrO$_{3}$. Contrary to what has been believed so far, only for $x\leq0.25$ the system forms uniform solid solutions. For larger Li content, as…

Strongly Correlated Electrons · Physics 2014-06-17 S. Manni , Sungkyun Choi , I. I. Mazin , R. Coldea , Michaela Altmeyer , Harald O. Jeschke , Roser Valenti , P. Gegenwart

Kitaev's honeycomb spin-liquid model and its proposed realization in materials such as $\alpha$-RuCl$_3$, Li$_2$IrO$_3$ and Na$_2$IrO$_3$ continue to present open questions about how the dynamics of a spin-liquid are modified in the…

Strongly Correlated Electrons · Physics 2020-02-12 R. Sarkar , Z. Mei , A. Ruiz , G. Lopez , H. -H. Klauss , J. G. Analytis , I. Kimchi , N. J. Curro

We report a polarized Raman scattering study of the lattice dynamics of $\beta$-Li$_2$IrO$_3$ under hydrostatic pressures up to 7.62 GPa. At ambient pressure, $\beta$-Li$_2$IrO$_3$ exhibits the hyperhoneycomb crystal structure and a…

We report the structure, magnetic, and thermal property measurements on single crystalline and polycrystalline samples of Ru substituted honeycomb lattice iridate Na$_2$Ir$_x$Ru$_{1-x}$O$_3$ (x = 0, 0.05, 0.1, 0.15, 0.2, 0.3, 0.5). The…

Strongly Correlated Electrons · Physics 2015-10-20 Kavita Mehlawat , Yogesh Singh

We report high-resolution angle-resolved photoemission spectroscopy measurements on the honeycomb iridate Na2IrO3. Our measurements reveal the existence of a metallic surface band feature crossing the Fermi level with nearly linear…

We have synthesized single crystals of Na$_2$(Ir$_{1-x}$Ti$_x$)O$_3$ and polycrystals of Li$_2$(Ir$_{1-x}$Ti$_x$)O$_3$ and studied the effect of magnetic depletion on the magnetic properties by measurements of the magnetic susceptibility,…

Strongly Correlated Electrons · Physics 2014-06-18 S. Manni , Y. Tokiwa , P. Gegenwart

We report magnetization and neutron diffraction studies on crystal and magnetic structures of Ir- and Rh-substituted honeycomb lattice $\alpha$-RuCl$_3$. The iridium or rhodium atoms are distributed at the Ru site with little structural…

Materials Science · Physics 2023-10-05 Zachary Morgan , Iris Ye , Colin L. Sarkis , Xiaoping Wang , Stephen Nagler , Jiaqiang Yan

The low-temperature magnetic properties of \tcr{polycrystalline} Na$_2$IrO$_3$, a candidate material for the realization of a quantum spin-liquid state, were investigated by means of muon-spin relaxation and nuclear magnetic resonance…

Li$_2$RuO$_3$ is known to crystallize in either $C2/m$ or $P2_1/m$ structures at room temperature. We report the first single crystal growth of Li$_2$RuO$_3$ and Na substituted crystals (Li$_{0.95}$Na$_{0.05}$)$_{2}$RuO$_3$ crystallizing in…

Strongly Correlated Electrons · Physics 2017-02-08 Kavita Mehlawat , Yogesh Singh

We report that Na2IrO3, which has a layered honeycomb iridium oxide sublattice interleaved by Na planes, decomposes in laboratory air while maintaining the same basic crystal structure. The decomposition reaction was monitored by…

Materials Science · Physics 2014-05-06 Jason W. Krizan , John H. Roudebush , Gary M. Fox , Robert J. Cava

Honeycomb Na$_2$IrO$_3$ is a prototype spin-orbit Mott insulator and Kitaev magnet. We report a combined structural and electrical resistivity study of Na$_2$IrO$_3$ single crystals. Laue back-scattering diffraction indicates twinning with…

Strongly Correlated Electrons · Physics 2023-12-12 Franziska A. Breitner , Julian Kaiser , Anton Jesche , Philipp Gegenwart

A new-type structural transition has been found in Li2RuO3 with honeycomb lattice of edge-sharing RuO6-octahedra. With decreasing temperature T, the electrical resistivity exhibits an anomalous increase at T=Tc~540 K, suggesting the (metal…

Strongly Correlated Electrons · Physics 2015-06-25 Yoko Miura , Yukio Yasui , Masatoshi Sato , Naoki Igawa , Kazuhisa Kakurai

The electrical resistivity rho of the iron-arsenide superconductor Ba1-xKxFe2As2 was measured in applied pressures up to 2.6 GPa for four underdoped samples, with x = 0.16, 0.18, 0.19 and 0.21. The antiferromagnetic ordering temperature…

Single-crystal x-ray diffraction studies with synchrotron radiation on the honeycomb iridate $\alpha$-Li$_{2}$IrO$_{3}$ reveal a pressure-induced structural phase transition with symmetry lowering from monoclinic to triclinic at a critical…

Combining thermodynamic measurements with theoretical density functional and thermodynamic calculations we demonstrate that the honeycomb lattice iridates A2IrO3 (A = Na, Li) are magnetically ordered Mott insulators where the magnetism of…

Strongly Correlated Electrons · Physics 2012-03-26 Yogesh Singh , S. Manni , J. Reuther , T. Berlijn , R. Thomale , W. Ku , S. Trebst , P. Gegenwart

We report the dependence of magnetic properties on the crystalline disorder in Li$_{2}$RuO$_3$ with Ru honeycomb lattice. This oxide exhibits unconventional Ru-dimer transition below $T_\text{d} \sim$ 540 K. We demonstrate that the cell…

Strongly Correlated Electrons · Physics 2016-02-23 Marco-Polo Jimenez-Segura , Atsutoshi Ikeda , Shingo Yonezawa , Yoshiteru Maeno

The structural and magnetic properties of a new series of iridium-based honeycomb lattices with the formula Na3-delta(Na1-xMgx)Ir2O6 (x = 0 to 1) are reported. As x and delta are increased, the honeycomb lattice contracts and the strength…

Strongly Correlated Electrons · Physics 2014-04-18 D. C. Wallace , C. M. Brown , T. M. McQueen
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