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We propose and demonstrate a novel technique that combines Raman scattering and optical cycling in molecules with diagonal Franck-Condon factors. This resonance Raman optical cycling manipulates molecules to behave like efficient…

Atomic Physics · Physics 2021-08-26 J. C. Shaw , J. C. Schnaubelt , D. J. McCarron

We present a general review of the bifurcation sequences of periodic orbits in general position of a family of resonant Hamiltonian normal forms with nearly equal unperturbed frequencies, invariant under $Z_2 \times Z_2$ symmetry. The rich…

Dynamical Systems · Mathematics 2016-06-28 Antonella Marchesiello , Giuseppe Pucacco

When molecules interact with intense light sources of femtosecond or shorter duration the rotational degrees of freedom are frozen during the response to the strong nonperturbative interaction. We show how the frozen degrees of freedom…

Atomic Physics · Physics 2007-09-25 C. B. Madsen , A. S. Mouritzen , T. K. Kjeldsen , L. B. Madsen

We consider several aspects of high-order harmonic generation in solids: the effects of elastic and inelastic scattering; varying pulse characteristics; and inclusion of material-specific parameters through a realistic band structure. We…

Other Condensed Matter · Physics 2013-02-07 A. F. Kemper , B. Moritz , J. K. Freericks , T. P. Devereaux

The generation of high-order harmonics in a medium of chiral molecules driven by intense bi-elliptical laser fields can lead to strong chiroptical response in a broad range of harmonic numbers and ellipticities [D. Ayuso et al, J. Phys. B…

Optics · Physics 2018-07-04 David Ayuso , Piero Decleva , Serguei Patchkovskii , Olga Smirnova

Given a two-dimensional conformal field theory with a global symmetry, we propose a method to implement an orbifold construction by taking orbits of the modular group. For the case of cyclic symmetries we find that this approach always…

High Energy Physics - Theory · Physics 2020-05-27 Daniel Robbins , Thomas Vandermeulen

We investigate the photon emission in coupled quantum dots based on symmetry considerations. With the help of a new theorem we proved, we reveal the origin of the various emission patterns, which is the combinative symmetry in the time…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Shi-Fang Guo , Suqing Duan , Yan Xie , Wei-Dong Chu , Wei Zhang

We report the observation of macroscopic field-free orientation, i.e. more than 73 % of CO molecules pointing in the same direction. This is achieved through an all-optical scheme operating at high particle densities ($>10^{17}$cm$^{-3}$)…

Chemical Physics · Physics 2014-07-09 P. M. Kraus , D. Baykusheva , H. J. Wörner

Attosecond metrology sensitive to sub-optical-cycle electronic and structural dynamics is opening up new avenues for ultrafast spectroscopy of condensed matter. Using intense lightwaves to precisely control the extremely fast carrier…

The selection rules of high harmonic generation (HHG) are investigated using three-dimensional time-dependent density functional theory (TDDFT). From the harmonic spectra obtained with various real molecules and different forms of laser…

Atomic Physics · Physics 2016-09-28 Xi Liu , Xiaosong Zhu , Liang Li , Yang Li , Qingbin Zhang , Pengfei Lan , Peixiang Lu

We investigate the alignment-dependent high-order harmonic spectrum generated from nonadiabatically aligned molecules around the first half rotational revival. It is found that the evolution of the molecular alignment is encoded in the…

Atomic Physics · Physics 2014-03-13 Meiyan Qin , Xiaosong Zhu , Yang Li , Qingbin Zhang , Pengfei Lan , Peixiang Lu

We show that a polynomial H(N) of degree N of a harmonic oscillator hamiltonian allows us to devise a fully solvable continuous quantum system for which the first N discrete energy eigenvalues can be chosen at will. In general such a choice…

Quantum Physics · Physics 2021-02-02 Ole Steuernagel , Andrei Klimov

Symmetries essentially provide conservation rules in nonlinear light-matter interactions, that facilitate control and understanding of photon conversion processes or electron dynamics. Since anisotropic solids have rich symmetries, they are…

This tutorial presents the most important aspects of the molecular self-probing paradigm, which views the process of high harmonic generation as "a molecule being probed by one of its own electrons". Since the properties of the electron…

Atomic Physics · Physics 2021-03-31 Stefan Haessler , Jérémie Caillat , Pascal Salières

To understand the photophysics of molecular aggregates, exciton model of J- and H-aggregate has been extensively utilized. However, it lacks consideration of crystal symmetry. Although discrete molecules may lack symmetry, their aggregates…

Mesoscale and Nanoscale Physics · Physics 2023-10-10 Qingyun Wan , Chi-Ming Che

We study the strong-field interaction of a helical bi-chromatic pump with an anisotropic and inhomogeneous molecular system in the form of planar distribution of radially aligned molecular ensemble. This setting gives rise to macroscopic…

Chemical Physics · Physics 2026-02-13 Uriel Zanzuri , Sharly Fleischer , Tamar Seideman , Eldad Yahel , Amir Natan , Alon Bahabad

We explore the nonlinear response of ultrafast strong-field driven excitons in a one-dimensional solid with ab initio simulations. We demonstrate from our simulations and analytical model that a finite population of excitons imprints unique…

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

Extremely fast rotating molecules carrying significantly more energy in their rotation than in any other degree of freedom are known as "super rotors". It has been speculated that super rotors may exhibit a number of unique properties.…

Optics · Physics 2013-06-11 Aleksey Korobenko , Alexander A. Milner , Valery Milner

The possibility of coherent radiation by molecular magnets is investigated. It is shown that to realize the coherent radiation, it is necessary to couple the considered sample to a resonant electric circuit. A theory for describing this…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 V. I. Yukalov , E. P. Yukalova