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The rich information content of measurements in the molecular frame rather than the laboratory frame has motivated the development of several methods for aligning gas phase molecules in space. Even so, for asymmetric tops the problem of…

Atomic Physics · Physics 2016-11-23 Varun Makhija , Xiaoming Ren , Drue Gockel , Anh-Thu Le , Vinod Kumarappan

Ultrafast all-optical control of light emission is a central goal of extreme nonlinear optics, with implications for compact short-wavelength sources, petahertz optoelectronics, and label-free superresolution microscopy. High-harmonic…

We show that combining vibrational spectroscopy with signal processing can result in a scheme for ultrasensitive detection of molecules. We consider the vibrational spectrum as a signal on the energy axis and apply a matched filter on that…

Computational Physics · Physics 2018-12-10 Tay Yong Boon , Ian Tay Rongde , Loy Liang Yi , Aw Ke Fun , Ong Zhi Li , Sergei Manzhos

A theory of ultra-fast pump-probe experiments proposed by us earlier [F.H.M. Faisal et al., Phys. Rev. Lett. 98, 143001 (2007) and F.H.M. Faisal and A. Abdurrouf, Phys. Rev. Lett. 100, 123005 (2008)] is developed here fully and applied to…

Atomic and Molecular Clusters · Physics 2009-11-13 A. Abdurrouf , F. H. M. Faisal

We investigate high-order harmonic spectra from aligned diatomic molecules in intense driving fields whose components have orthogonal polarizations. We focus on how the driving-field ellipticity influences structural interference patterns…

In a molecule subjected to no external fields, motion of nuclei is governed by a function V of nuclear coordinates. This function (potential energy) is a sum of two terms: Coulomb repulsion between nuclei and the electronic effective…

Mathematical Physics · Physics 2015-09-01 Vladimir Damljanovic

The influence of the orbital symmetry on the ellipticity of the high-order harmonics is investigated. It is found that the ellipticity maps have distinct shapes for the molecular orbital with different symmetry. Our analysis shows that the…

Optics · Physics 2013-12-30 Meiyan Qin , Xiaosong Zhu , Kunlong Liu , Qingbin Zhang , Peixiang Lu

High-order harmonic responses from three $C_{20}$ isomers: fullerene, ring, and bowl, are calculated within the modified Lewenstein model for molecular systems. Spectra for all three structures exhibit intense modulations of the harmonic…

Quantum Physics · Physics 2022-03-31 F. Cajiao - Vélez , A. Jaron

Using numerical simulations, we show that atomic high order harmonic generation, HHG, with a circularly polarized laser field offers an ideal framework for quantum-classical correspondence in strong field physics. With an appropriate…

Atomic Physics · Physics 2014-02-06 Francois Mauger , A. D. Bandrauk , Adam Kamor , Turgay Uzer , Cristel Chandre

The purpose of this article is the study of the symmetries in a circular and linear harmonic oscillator chains system, and consequently use them as a means to find the eigenvalues of these configurations. Furthermore, a hidden…

Mathematical Physics · Physics 2023-10-03 Edoardo Spezzano , Alberto Iommi

Asymmetric molecules look different when viewed from one side or the other. This difference influences the electronic structure of the valence electrons, thereby giving stereo sensitivity to chemistry and biology. We show that attosecond…

The first scheme for quasi-phase-matching high harmonic generation of circularly polarized radiation is proposed: optical rotation quasi-phase-matching (ORQPM). In ORQPM propagation of the driving radiation in a system exhibiting circular…

Optics · Physics 2013-03-19 Lewis Z. Liu , Kevin O'Keeffe , Simon M. Hooker

The spectrum of cyclotron radiation produced by electrons with a strongly anisotropic velocity distribution is calculated taking into account higher harmonics. The motion of the electrons is assumed to be ultrarelativistic along the…

Astrophysics · Physics 2009-11-13 A. N. Baushev

We propose an approach to probe coherent spin-state dynamics of molecules using circularly polarized hard x-ray pulses. For the dynamically aligned nitric oxide molecules in a coherent superposition spin-orbit coupled electronic state that…

Optics · Physics 2024-01-02 Xiaoyu Mi , Ming Zhang , Zheng Li

Molecular representation learning plays a crucial role in AI-assisted drug discovery research. Encoding 3D molecular structures through Euclidean neural networks has become the prevailing method in the geometric deep learning community.…

Machine Learning · Computer Science 2023-03-29 Yiqun Wang , Yuning Shen , Shi Chen , Lihao Wang , Fei Ye , Hao Zhou

A classical microscopic theory of rovibrational motion at high angular momenta in symmetrical non-linear molecules AB$_2$ is derived within the framework of small oscillations near the stationary states of a rotating molecule. The…

chem-ph · Physics 2009-10-28 I. N. Kozin , I. M. Pavlichenkov

Present photoionization experiments cannot measure molecular frame photoelectron angular distributions (MFPAD) from the outermost valence electrons of molecules. We show that details of the MFPAD can be retrieved with high-order harmonics…

Atomic Physics · Physics 2009-05-24 Anh-Thu Le , R. R. Lucchese , M. T. Lee , C. D. Lin

High-harmonic generation is typically thought of as a sub-laser-cycle process, with the electron's excursion in the continuum lasting a fraction of the optical cycle. However, it was recently suggested that long-lived Rydberg states can…

We show that high-order harmonics generated from molecules by intense laser pulses can be expressed as the product of a returning electron wave packet and the photo-recombination cross section (PRCS) where the electron wave packet can be…

Atomic Physics · Physics 2008-04-04 Anh-Thu Le , R. Della Picca , P. D. Fainstein , D. A. Telnov , M. Lein , C. D. Lin

The control of ultrafast molecular rotational motion has benefited from the development of innovative techniques in strong-field laser physics. Here, we theoretically demonstrate a novel type of coherent control by inducing rotation of an…

Chemical Physics · Physics 2018-08-27 Alec Owens , Andrey Yachmenev , Jochen Küpper