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We investigated the crystal and magnetic structures of the spin-1/2 frustrated antiferromagnet Cu3Mo2O9 in which the spin system consists of antiferromagnetic chains and dimers. The space group at room temperature has been reported to be…

The domain structure of a MnSb$_2$Te$_4$ single crystal with a Curie temperature $T_C \approx 45~K$ was studied using the high-resolution Bitter decoration technique. Magnetotransport measurements confirm a soft ferromagnetic ordering with…

We present the results of susceptibility \chi(T) and magnetisation M(H) measurements performed on single crystal samples of the rare-earth oxides SrLn2O4 (Ln = Er, Dy and Ho). The measurements reveal the presence of magnetic ordering…

Strongly Correlated Electrons · Physics 2012-01-17 Thomas J. Hayes , Olga Young , Geetha Balakrishnan , Oleg A. Petrenko

SrMoO4 was studied under compression up to 25 GPa by angle-dispersive x-ray diffraction. A phase transition was observed from the scheelite-structured ambient phase to a monoclinic fergusonite phase at 12.2(9) GPa with cell parameters a =…

Materials Science · Physics 2008-02-04 Daniel Errandonea , Ravhi S. Kumar , Xinghua Ma , Chaoyang Tu

AMn6Bi5 materials (A = Na, K, Rb and Cs) consisting of unique Mn-cluster chains emerge as a new family of superconductors with the suppression of their antiferromagnetic (AFM) order under high pressures. Here, we report transverse…

Single crystals of the novel strontium osmate Sr3Os4O14 have been grown by the hydrothermal method using opposed anvil high-pressure and high-temperature technique. The reaction took place in sealed gold capsules at 3 GPa and a temperature…

Materials Science · Physics 2023-09-13 N. D. Zhigadlo

In this work we study the interplay between the crystal structure and magnetism of the pyroarsenate \alpha-Cu_2As_2O_7 by means of magnetization, heat capacity, electron spin resonance and nuclear magnetic resonance measurements as well as…

We report the growth of mm-sized Pmnb-Li2FeSiO4 single crystals by means of the optical floating-zone method at high argon pressure and describe the conditions required for a stable growth process. The crystal structure is determined and…

Fe pnictides and related materials have been a topic of intense research for understanding the complex interplay between magnetism and superconductivity. Here we report on the magnetic structure of SrMn$_{2}$As$_{2}$ that crystallizes in a…

Strongly Correlated Electrons · Physics 2016-12-13 Pinaki Das , N. S. Sangeetha , Abhishek Pandey , Zackery A. Benson , T. W. Heitmann , D. C. Johnston , A. I. Goldman , A. Kreyssig

The synthesis, infra-red, Raman and NMR spectra and crystal structure of 2, 4, 4- trimethyl-4, 5- dihydro-3H-benzo[b] [1, 4] diazepin-1-ium tetrachlorocadmate, [C12H17N2]2CdCl4 and benzene-1,2-diaminium decachlorotricadmate(II)…

Materials Science · Physics 2008-05-22 Iskandar Chaabane , Faouzi Hlel , Kamel Guidara

In the R1/2D1/2MnO3 manganites (R: rare earth, D: divalent cation), the structural phase transition at Tco is commonly interpreted as a concomitant charge and orbital ordering (CO/OO) process driven by a cooperative Jahn-Teller effect and…

Strongly Correlated Electrons · Physics 2007-05-23 A. Daoud-Aladine , J. Rodriguez-Carvajal , L. Pinsard-Gaudart , M. T. Fernandez-Diaz , A. Revcolevschi

Sawtooth chain magnets have been a subject of historical interest in the field of frustrated magnetism, with classical olivine family $M_2TX_4$, ($M$ - 3d, $T$ - 4p, $X$ - chalcogen elements) typically realizing simple $\mathbf{k} = (000)$…

Crystallographic, electronic transport, thermal and magnetic properties are reported for SrMn2As2 and CaMn2As2 single crystals grown using Sn flux. Rietveld refinements of powder x-ray diffraction data show that the two compounds are…

Strongly Correlated Electrons · Physics 2016-12-13 N. S. Sangeetha , Abhishek Pandey , Zackery A. Benson , D. C. Johnston

We report the synthesis, structure and magnetic properties of two 1:3 ordered quadruple perovskites Sr4MRu3O12 (M = Li and Na). Sr4NaRu3O12 crystallizes in the centrosymmetric space group R-3 and Sr4LiRu3O12 appears to be isostructural to…

In order to study the magnetic and crystal structures in the Nd{1-x}Sr{x}MnO{3} system, we have peformed neutron diffraction measurements on melt-grown polycrystalline samples with 0.49 < x < 0.75. As a function of hole concentration x, the…

Strongly Correlated Electrons · Physics 2009-10-31 R. Kajimoto , H. Yoshizawa , H. Kawano , H. Kuwahara , Y. Tokura , K. Ohoyama , M. Ohashi

The sodium rhodate NaRh2O4 was synthesized for the first time and characterized by neutron and x-ray diffraction studies, measurements of magnetic susceptibility, specific heat, electrical resistivity, and the Seebeck coefficient. NaRh2O4…

Strongly Correlated Electrons · Physics 2007-05-23 K. Yamaura , Q. Huang , M. Moldovan , D. P. Young , A. Sato , Y. Baba , Y. Matsui , E. Takayama-Muromachi

The magnetic properties of the two isostructural molecule-based magnets, Ni(NCS)$_{2}$(thiourea)$_{2}$, $S$ = 1, [thiourea = SC(NH$_2$)$_2$] and Co(NCS)$_{2}$(thiourea)$_{2}$, $S$ = 3/2, are characterised using several techniques in order…

At ambient conditions SrAl4 adopts the BaAl4 structure type with space group I4/mmm. It undergoes a charge-density-wave (CDW) transition at TCDW = 243 K, followed by a structural transition at TS = 87 K. Temperature-dependent single-crystal…

The crystal and magnetic structure of (La0.70Ca0.30)(CryMn1-y)O3 for y = 0.70, 0.50 and 0.15 has been investigated using neutron powder diffraction. The three samples crystallize in the Pnma space group at both 290 K and 5 K and exhibit…

FeVO$_4$ has been studied by heat capacity, magnetic susceptibility, electric polarization and single crystal neutron diffraction experiments. The triclinic crystal structure is made of \emph{S}-shaped clusters of six Fe$^{3+}$ ions, linked…

Superconductivity · Physics 2015-05-13 A. Daoud-Aladine , B. Kundys , C. Martin , P. G. Radaelli , P. J. Brown , C. Simon , L. C. Chapon