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In Boltzmannian statistical mechanics macro-states supervene on micro-states. This leads to a partitioning of the state space of a system into regions of macroscopically indistinguishable micro-states. The largest of these regions is…

Statistical Mechanics · Physics 2015-10-09 Charlotte Werndl , Roman Frigg

Equilibrium is a central concept of statistical mechanics. In previous work we introduced the notions of a Boltzmannian alpha-epsilon-equilibrium and a Boltzmannian gamma-varepsilon-equilibrium (Werndl and Frigg 2015a, 2015b). This was done…

Statistical Mechanics · Physics 2016-07-25 Charlotte Werndl , Roman Frigg

The Boltzmann and Gibbs approaches to statistical mechanics have very different definitions of equilibrium and entropy. The problems associated with this are discussed and it is suggested that they can be resolved, to produce a version of…

Statistical Mechanics · Physics 2007-10-11 David A. Lavis

Boltzmannian statistical mechanics partitions the phase space of a system into macro-regions, and the largest of these is identified with equilibrium. What justifies this identification? Common answers focus on Boltzmann's combinatorial…

Statistical Mechanics · Physics 2023-06-22 Charlotte Werndl , Roman Frigg

This paper analyzes the ergodic hypothesis in the context of Boltzmann's late work in statistical mechanics, where Boltzmann lays the foundations for what is today known as the typicality account. I argue that, based on the concepts of…

Statistical Mechanics · Physics 2023-07-13 Paula Reichert

A century ago, the foundations of equilibrium statistical mechanics were laid. For a system in equilibrium with a thermal bath, much is understood through the Boltzmann factor, exp{-H[C]/kT}, for the probability of finding the system in any…

Statistical Mechanics · Physics 2009-10-31 R. K. P. Zia , L. B. Shaw , B. Schmittmann , R. J. Astalos

We examine the question of whether the formal expressions of equilibrium statistical mechanics can be applied to time independent non-dissipative systems that are not in true thermodynamic equilibrium and are nonergodic. By assuming the…

Statistical Mechanics · Physics 2007-11-09 Stephen R. Williams , Denis J. Evans

This paper reviews various applications of the theory of smooth dynamical systems to conceptual problems of nonequilibrium statistical mechanics. We adopt a new point of view which has emerged progressively in recent years, and which takes…

chao-dyn · Physics 2015-06-24 David Ruelle

We use a Hamiltonian dynamics to discuss the statistical mechanics of long-lasting quasi-stationary states particularly relevant for long-range interacting systems. Despite the presence of an anomalous single-particle velocity distribution,…

Statistical Mechanics · Physics 2009-11-11 Fulvio Baldovin , Enzo Orlandini

Boltzmann provided a scenario to explain why individual macroscopic systems composed of a large number $N$ of microscopic constituents are inevitably (i.e., with overwhelming probability) observed to approach a unique macroscopic state of…

Mathematical Physics · Physics 2017-11-23 Stephan De Bievre , Paul E. Parris

The mathematical physics of mechanical systems in thermal equilibrium is a well studied, and relatively easy, subject, because the Gibbs distribution is in general an adequate guess for the equilibrium state. On the other hand, the…

Mathematical Physics · Physics 2007-05-23 Jean-Pierre Eckmann

Equilibrium is a rather ideal situation, the exception rather than the rule in Nature. Whenever the external or internal parameters of a physical system are varied its subsequent relaxation to equilibrium may be either impossible or take…

Statistical Mechanics · Physics 2016-10-04 Leticia F. Cugliandolo

We propose a new formulation of the fluctuating lattice Boltzmann equation that is consistent with both equilibrium statististical mechanics and fluctuating hydrodynamics. The formalism is based on a generalized lattice-gas model, with each…

Soft Condensed Matter · Physics 2009-11-13 Burkhard Duenweg , Ulf D. Schiller , Anthony J. C. Ladd

We search for steady states in a class of fluctuating and driven physical systems that exhibit sustained currents. We find that the physical concept of a steady state, well known for systems at equilibrium, must be generalised to describe…

Soft Condensed Matter · Physics 2020-04-15 Tanniemola B. Liverpool

Quasistationary states are long-lived nonequilibrium states, observed in some systems with long-range interactions under deterministic Hamiltonian evolution. These intriguing non-Boltzmann states relax to equilibrium over times which…

Statistical Mechanics · Physics 2015-03-17 Shamik Gupta , David Mukamel

Why do gases reach equilibrium when left to themselves? The canonical answer, originally proffered by Boltzmann, is that the systems have to be ergodic. This answer is now widely regarded as flawed. We argue that some of the main…

History and Philosophy of Physics · Physics 2013-10-08 Roman Frigg , Charlotte Werndl

There are three levels of description in classical statistical mechanics, the microscopic/dynamic, the macroscopic/statistical and the thermodynamic. At one end there is a well-used concept of equilibrium in thermodynamics and at the other…

Statistical Mechanics · Physics 2007-05-23 D. A. Lavis

Statistical mechanics is one of the most comprehensive theories in physics. From a boiling pot of water to the complex dynamics of quantum many-body systems it provides a successful connection between the microscopic dynamics of atoms and…

Quantum Gases · Physics 2016-10-06 B. Rauer , T. Schweigler , T. Langen , J. Schmiedmayer

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati

Bridging equilibrium and nonequilibrium statistical physics attracts sustained interest. Hallmarks of nonequilibrium systems include a breakdown of detailed balance, and an absence of a priori potential function corresponding to the…

Statistical Mechanics · Physics 2015-04-24 Ying Tang , Ruoshi Yuan , Jianhong Chen , Ping Ao
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