Rethinking Boltzmannian Equilibrium
Statistical Mechanics
2023-06-22 v1 Dynamical Systems
Chaotic Dynamics
History and Philosophy of Physics
Abstract
Boltzmannian statistical mechanics partitions the phase space of a system into macro-regions, and the largest of these is identified with equilibrium. What justifies this identification? Common answers focus on Boltzmann's combinatorial argument, the Maxwell-Boltzmann distribution, and maximum entropy considerations. We argue that they fail and present a new answer. We characterise equilibrium as the macrostate in which a system spends most of its time and prove a new theorem establishing that equilibrium thus defined corresponds to the largest macro-region. Our derivation is completely general, and does not rely on assumptions about the dynamics or internal interactions.
Cite
@article{arxiv.1510.02467,
title = {Rethinking Boltzmannian Equilibrium},
author = {Charlotte Werndl and Roman Frigg},
journal= {arXiv preprint arXiv:1510.02467},
year = {2023}
}
Comments
arXiv admin note: substantial text overlap with arXiv:1510.02260