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Classical density functional theory (DFT) is the primary method for investigations of inhomogeneous fluids in external fields. It requires the excess Helmholtz free energy functional as input to an Euler-Lagrange equation for the one-body…

Soft Condensed Matter · Physics 2026-02-05 S. M. Tschopp , H. Vahid , J. M. Brader

We present a theoretical study based on the Anderson model of the transport properties of a Kondo impurity (atom or quantum dot) connected to ferromagnetic leads, which can sustain a non-equilibrium spin current. We analyze the case where…

Mesoscale and Nanoscale Physics · Physics 2013-10-08 Jong Soo Lim , Rosa Lopez , Laurent Limot , Pascal Simon

Two-terminal spintronic devices remain challenging to model under realistic operating conditions, where the interplay of complex electronic structures, correlation effects and bias-driven non-equilibrium dynamics may significantly impact…

Strongly Correlated Electrons · Physics 2025-11-25 Declan Nell , Milos Radonjic , Ivan Rungger , Liviu Chioncel , Stefano Sanvito , Andrea Droghetti

Recent progress in the field of (time-independent) ensemble density-functional theory (DFT) for excited states are reviewed. Both Gross-Oliveira-Kohn (GOK) and $N$-centered ensemble formalisms, which are mathematically very similar and…

Chemical Physics · Physics 2021-11-29 Filip Cernatic , Bruno Senjean , Vincent Robert , Emmanuel Fromager

The coupling between localized magnetic moments and itinerant electrons presents a plethora of interesting physics. The low-energy physics of some quantum impurity systems can be described using conformal field theory (CFT). In this paper,…

High Energy Physics - Theory · Physics 2019-11-26 Ying-Hai Wu , Hong-Hao Tu

We outline a Kohn-Sham-Dirac density-functional-theory (DFT) scheme for graphene sheets that treats slowly-varying inhomogeneous external potentials and electron-electron interactions on an equal footing. The theory is able to account for…

Strongly Correlated Electrons · Physics 2008-09-23 Marco Polini , Andrea Tomadin , Reza Asgari , A. H. MacDonald

We introduce DeepDFT, a deep learning model for predicting the electronic charge density around atoms, the fundamental variable in electronic structure simulations from which all ground state properties can be calculated. The model is…

Computational Physics · Physics 2020-11-09 Peter Bjørn Jørgensen , Arghya Bhowmik

The twofold degenerate Anderson impurity model [1-4] is investigated and the strong electronic correlations of d-electrons of impurity ion are taken into account by elaborating suitable diagram technique. We discuss the properties of the…

Strongly Correlated Electrons · Physics 2015-06-12 V. A. Moskalenko , L. A. Dohotaru , D. F. Digor , I. D. Cebotari

We present novel methods implemented within the non-equilibrium Green function code (NEGF) transiesta based on density functional theory (DFT). Our flexible, next-generation DFT-NEGF code handles devices with one or multiple electrodes…

Mesoscale and Nanoscale Physics · Physics 2016-12-30 Nick Papior , Nicolás Lorente , Thomas Frederiksen , Alberto García , Mads Brandbyge

We present a model intended for rapid sampling of ground and excited state potential energy surfaces for first-row transition metal active sites. The method is computationally inexpensive and is suited for dynamics simulations where (1)…

Chemical Physics · Physics 2009-11-10 M. X. LaBute , R. G. Endres , D. L. Cox

Density functional theory (DFT) is an efficient instrument for describing a wide range of nanoscale phenomena: wetting transition, capillary condensation, adsorption, etc. In this paper, we suggest a method for obtaining the equilibrium…

Computational Physics · Physics 2021-06-18 Yuriy Kanygin , Irina Nesterova , Pavel Lomovitskiy , Aleksey Khlyupin

In the past decade, classical dynamical density functional theory (DDFT) has been developed and widely applied to the Brownian dynamics of interacting colloidal particles. One of the possible derivation routes of DDFT from the microscopic…

Soft Condensed Matter · Physics 2014-01-28 Raphael Wittkowski , Hartmut Löwen , Helmut R. Brand

An exact relation between the conductance maximum $G_0$ at zero temperature and a ratio of lead densities is derived within the framework of the single impurity Anderson model: $G_0={\mathfrak R}[n] \frac{2e^2}{h}$, where ${\mathfrak…

Strongly Correlated Electrons · Physics 2015-06-17 Ferdinand Evers , Peter Schmitteckert

Practical density functional theory (DFT) owes its success to the groundbreaking work of Kohn and Sham that introduced the exact calculation of the non-interacting kinetic energy of the electrons using an auxiliary mean-field system.…

Chemical Physics · Physics 2023-11-17 P. del Mazo-Sevillano , J. Hermann

In this work we exploit the integrability of the two-lead Anderson model to compute transport properties of a quantum dot, in and out of equilibrium. Our method combines the properties of integrable scattering together with a…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Robert Konik , Hubert Saleur , Andreas Ludwig

An in-principle exact working equation to compute electronic affinity and ionization Fukui functions is derived within the $N$-centered (Nc) ensemble extension of density functional theory (DFT). It circumvents the kernel derivative…

Chemical Physics · Physics 2026-02-12 Lucien Dupuy , Emmanuel Fromager

Starting from Newton's equations of motion, we derive a dynamical density functional theory (DDFT) applicable to atomic liquids. The theory has the feature that it requires as input the Helmholtz free energy functional from equilibrium…

Soft Condensed Matter · Physics 2007-05-23 A. J. Archer

The practical success of density functional theory (DFT) is largely credited to the Kohn-Sham approach, which enables the exact calculation of the non-interacting electron kinetic energy via an auxiliary noninteracting system. Yet, the…

Computational Physics · Physics 2025-03-21 Sangita Majumdar , Zekun Shi , Giovanni Vignale

Density functional theory (DFT) provides convenient electronic structure methods for the study of molecular systems and materials. Regular Kohn-Sham DFT calculations rely on unitary transformations to determine the ground-state electronic…

Chemical Physics · Physics 2022-10-10 Greta Jacobson , Juan M. Marmolejo-Tejada , Martín A. Mosquera

Classical dynamical density functional theory (DDFT) is one of the cornerstones of modern statistical mechanics. It is an extension of the highly successful method of classical density functional theory (DFT) to nonequilibrium systems.…

Soft Condensed Matter · Physics 2020-12-29 Michael te Vrugt , Hartmut Löwen , Raphael Wittkowski