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While BiFeO3-based solid solutions show great promise for applications in energy conversion and storage, realizing this promise necessitates understanding the structure-property relationship in particular pertaining to the relaxor-like…

Ferroelectric materials with switchable spontaneous polarization underpin non-volatile memories, transistors, sensors, and emerging neuromorphic chips. Their performance and stability are governed by polarization dynamics and domain…

Materials Science · Physics 2026-03-20 Dongyu Bai , Ri He , Junxian Liu , Liangzhi Kou

Ferroelectric field-effect transistors (FE-FETs) consisting of tunable dielectric layers are utilized to investigate interfacial transport processes. Large changes in the dielectric constant as a function of temperature are observed in…

Materials Science · Physics 2015-06-04 Satyaprasad P. Senanayak , S. Guha , K. S. Narayan

HfO2-based ferroelectric materials are promising for the next generation of memory devices, attracting significant attention. However, their potential applications are significantly limited by fatigue and imprint phenomena, which affect…

Materials Science · Physics 2024-07-30 Muting Xie , Hongyu Yu , Binhua Zhang , Changsong Xu , Hongjun Xiang

This paper is concerned with modeling the polarization process in ferroelectric media. We develop a thermodynamically consistent model, based on phenomenological descriptions of free energy as well as switching and saturation conditions in…

Numerical Analysis · Mathematics 2020-09-17 Martin Meindlhumer , Astrid Pechstein , Alexander Humer

A microstructure-based model is presented to predict the fatigue life of polycrystalline metallic alloys which present a bilinear Coffin-Manson relationship. The model is based in the determination of the maximum value of a fatigue…

Materials Science · Physics 2017-11-07 A. Cruzado , S. Lucarini , J. LLorca , J. Segurado

Electric field plays an important role in ferroelectric phase transition. There have been numerous phase field formulations attempting to account for electrostatic interactions subject to different boundary conditions. In this paper, we…

Computational Physics · Physics 2019-10-18 Qiang Du , Ruotai Li , Lei Zhang

Negative activation volumes for dielectric relaxation are rarely reported in solid state physics and are limited to atomic scale processes. Broadband Dielectric Spectroscopy on heterogeneous systems, such as polycrystalline calcite and…

Geophysics · Physics 2025-05-23 Anthony N. Papathanassiou

We have proposed the phenomenological description of polarization switching peculiarities in ferroelectric semiconductors with charged defects and prevailing extrinsic conductivity. Exactly we have modified Landau-Ginsburg approach shown…

Materials Science · Physics 2009-11-10 Anna N. Morozovska , Eugeny A. Eliseev

The discovery of two-dimensional (2D) ferroelectrics with switchable out-of-plane polarization such as monolayer $\alpha$-In$_2$Se$_3$ offers a new avenue for ultrathin high-density ferroelectric-based nanoelectronics such as ferroelectric…

Materials Science · Physics 2021-12-01 Jing Wu , Liyi Bai , Jiawei Huang , Liyang Ma , Jian Liu , Shi Liu

A multi-scale methodology is developed in conjunction with a probabilistic fatigue lifetime model for structures with pores whose exact distribution, i.e. geometries and locations, is unknown. The method takes into account uncertainty in…

Computational Engineering, Finance, and Science · Computer Science 2024-09-27 Abhishek Palchoudhary , Cristian Ovalle , Vincent Maurel , Pierre Kerfriden

Solids subjected to repeated cycles of stress or deformation can fail after several cycles, a phenomenon termed fatigue failure. Although intensely investigated for a wide range of materials owing to its obvious practical importance, a…

Soft Condensed Matter · Physics 2024-09-27 Swarnendu Maity , Himangsu Bhaumik , Shivakumar Athani , Srikanth Sastry

For forty years researchers on ferroelectric switching have used the Kay-Dunn theory to model the thickness-dependence of the coercive field; it works surprisingly well, despite the fact that it is based upon homogeneous nucleation and a…

Materials Science · Physics 2007-05-23 P. Chandra , M. Dawber , P. B. Littlewood , J. F. Scott

The charge transport mechanism and the macroscopic dielectric constant in polycrystalline device materials commonly exhibit several components such as electrode-sample interface, grain boundary and bulk contributions. In order to gain…

Materials Science · Physics 2007-05-23 Rainer Schmidt , Andrew W. Brinkman

The thermodynamics and kinetics of tip-induced polarization switching in Piezoresponse Force Microscopy in the presence of surface charge defects is studied using the combination of analytical and numerical techniques. The signature of the…

Fatigue damages and failure widely exist in engineering structures. However, predicting fatigue life for various structural materials subjected to multiaxial loading paths remains a challenging problem. A novel multi-view deep learning…

Applied Physics · Physics 2024-05-15 Shuonan Chen , Xuhong Zhou , Yongtao Bai

The switching polarization of a ferroelectric is a characterization of the current that flows due to changes in polarization when the system is switched between two states. Computation of this change in polarization in crystal systems has…

Materials Science · Physics 2020-07-29 John Bonini , David Vanderbilt , Karin M. Rabe

Fluorite ferroelectrics are exciting candidates for next-generation non-volatile memory devices because their unique ferroelectric mechanism, which arises from unconventional oxygen displacements, permits ferroelectricity with minimal…

We consider ferroelectric phase transitions in both short-circuited and biased ferroelectric-semiconductor films with a space (depletion) charge which leads to some unusual behavior. It is shown that in the presence of the charge the…

Statistical Mechanics · Physics 2009-10-31 A. M. Bratkovsky , A. P. Levanyuk

The impact of flexoelectric coupling on polarization reversal kinetics and space charge dynamics in thin films of ferroelectric-semiconductors has been theoretically studied. The relaxation-type Landau-Khalatnikov equation together with the…

Materials Science · Physics 2017-01-18 Ivan S. Vorotiahin , Anna N. Morozovska , Eugene A. Eliseev , Yuri A. Genenko