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In a recent Letter Lee et al. studied the spin 1/2 photoluminescence-detected magnetic resonance (PLDMR) of a soluble derivative of poly-phenylene vinylene [MEH-PPV] and argued that it originates from the interaction of triplet excitons…

Other Condensed Matter · Physics 2009-11-11 C. G. Yang , E. Eherenfreund , Z. V. Vardeny

The effect of a magnetic field on the electroluminescence of organic light emitting devices originates from the hyperfine interaction between the electron/hole polarons and the hydrogen nuclei of the host molecules. In this paper, we…

Spin-dependent processes play a crucial role in organic electronic devices. Spin coherence can give rise to spin mixing due to a number of processes such as hyperfine coupling, and leads to a range of magnetic field effects. However, it is…

Mesoscale and Nanoscale Physics · Physics 2016-09-07 Marzieh Kavand , Douglas Baird , Kipp van Schooten , Hans Malissa , John M. Lupton , Christoph Boehme

In a recent paper Segal et al. [1] attempted to explain the dynamics of spin 1/2 photoluminescence detected magnetic resonance (PLDMR) in films of a pi-conjugated polymer, namely a soluble de-rivative of poly(phenylene-vinylene) [MEH-PPV]…

Materials Science · Physics 2009-11-11 C. G. Yang , E. Ehrenfreund , Z. V. Vardeny

Characteristic properties of magnetic field effects on spin selective geminate and bulk electron-hole polaron pair (PP) recombination are analyzed in detail within the approach based on the stochastic Liouville equation. Simple expressions…

Materials Science · Physics 2015-05-28 A. I. Shushin

In weakly spin-orbit coupled materials, the spin-selective nature of recombination can give rise to large magnetic-field effects, for example on electro-luminescence from molecular semiconductors. While silicon has weak spin-orbit coupling,…

Mesoscale and Nanoscale Physics · Physics 2018-02-21 F. Chiodi , S. L. Bayliss , L. Barast , D. Débarre , H. Bouchiat , R. H. Friend , A. D. Chepelianskii

We perform charge-induced absorption and electroluminescence spectroscopy in a polyfluorene organic magnetoresistive device. Our experiments allow us to measure the singlet exciton, triplet exciton and polaron densities in a live device…

Soft Condensed Matter · Physics 2009-11-13 T. D. Nguyen , J. Rybicki , Y. Sheng , M. Wohlgenannt

The magneto-electronic field effects in organic semiconductors at high magnetic fields are described by field-dependent mixing between singlet and triplet states of weakly bound charge carrier pairs due to small differences in their Land\'e…

Mesoscale and Nanoscale Physics · Physics 2018-08-15 G. Joshi , M. Y. Teferi , S. Jamali , M. Groesbeck , J. van Tol , R. McLaughlin , Z. V. Vardeny , J. M. Lupton , H. Malissa , C. Boehme

The unique properties of organic semiconductors make them versatile base materials for many applications ranging from light emitting diodes to transistors. The low spin-orbit coupling typical for carbon-based materials and the resulting…

We investigated photogeneration yield and recombination dynamics in blends of poly(3-hexyl thiophene) (P3HT) and poly[2-methoxy-5-(30,70-dimethyloctyloxy)-1,4-phenylenevinylene] (MDMO-PPV) with [6,6]- phenyl-C61 butyric acid methyl ester…

Materials Science · Physics 2012-05-09 Markus Mingebach , Stefan Walter , Vladimir Dyakonov , Carsten Deibel

Organic semiconductors have the remarkable property that their optical excitation not only generates charge-neutral electron-hole pairs (excitons) but also charge-separated polaron pairs with high yield. The microscopic mechanisms…

The magneto-optical longitudinal, transverse Hall and circularly-polarized response of silicene and other materials described by a Kane-Mele Hamiltonian are calculated. Particular attention is paid to the effects of an external electric…

Mesoscale and Nanoscale Physics · Physics 2013-08-29 Calvin J. Tabert , Elisabeth J. Nicol

At low temperatures and high magnetic fields, electron and hole spins in an organic light-emitting diode (OLED) become polarized so that recombination preferentially forms molecular triplet excited-state species. For low device currents,…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 Tobias Scharff , Wolfram Ratzke , Jonas Zipfel , Philippe Klemm , Sebastian Bange , John M. Lupton

We measure electrically detected magnetic resonance (EDMR) on organic light-emitting diodes (OLEDs) made of the polymer poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) at room temperature and high magnetic fields, where…

Mesoscale and Nanoscale Physics · Physics 2018-04-18 H. Malissa , R. Miller , D. L. Baird , S. Jamali , G. Joshi , M. Bursch , S. Grimme , J. van Tol , J. M. Lupton , C. Boehme

We use spectrally-resolved magneto-electroluminescence (EL) measurements to study the energy dependence of hyperfine interactions between polaron and nuclear spins in organic LEDs. Using layered devices based on Bphen/MTDATA -- a well-known…

Conjugated polymers exhibit unique spin-dependent phenomena arising from weak yet critical hyperfine interactions. Understanding these spin effects, particularly the spin-dependent formation and decay of correlated spin pairs, is important…

Quantifying the spin-spin interactions which influence electronic transitions in organic semiconductors is crucial for understanding their magneto-optoelectronic properties. By combining a theoretical model for three spin interactions in…

Materials Science · Physics 2015-02-20 W. J. Baker , T. L. Keevers , C. Boehme , D. R. McCamey

We have studied the role of spin-dependent processes on conductivity in polyfluorene (PFO) thin films by conducting continuous wave (c.w.) electrically detected magnetic resonance (EDMR) spectroscopy at temperatures between 10 K and 293 K…

Materials Science · Physics 2016-12-14 Richards Miller , K. J. van Schooten , H. Malissa , G. Joshi , S. Jamali , J. M. Lupton , C. Boehme

We explore the magnetoresistance (MC) effect in an organic semiconductor device based on the magnetic field related bipolaron formation. By establishing a group of dynamic equations, we present the transition among spin-parallel,…

Materials Science · Physics 2015-06-04 W. Qin , S. Yin , K. Gao , S. J. Xie

Polymer nanofibers are one-dimensional organic hydrocarbon systems containing conducting polymers where the non-linear local excitations such as solitons, polarons and bipolarons formed by the electron-phonon interaction were predicted.…

Mesoscale and Nanoscale Physics · Physics 2012-10-18 A. Choi , K. H. Kim , S. J. Hong , M. Goh , K. Akagi , R. B. Kaner , N. N. Kirova , S. A. Brazovskii , A. T. Johnson , D. A. Bonnell , E. J. Mele , Y. W. Park
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