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In this paper, we suppose a possible extension of Gibbs ensemble theory so that it can provide a reasonable description to phase transitions and spontaneous symmetry breaking. The extension is founded on three hypotheses, and can be…

Statistical Mechanics · Physics 2008-11-26 Ming-wen Xiao

A four states phase diagram for protein folding as a function of temperature and solvent quality is derived from an improved 2-d lattice model taking into account the temperature dependence of the hydrophobic effect. The phase diagram…

Statistical Mechanics · Physics 2009-11-11 Olivier Collet

Variational calculations of excited electronic states are carried out by finding saddle points on the surface that describes how the energy of the system varies as a function of the electronic degrees of freedom. This approach has several…

Chemical Physics · Physics 2023-02-15 Yorick L. A. Schmerwitz , Gianluca Levi , Hannes Jónsson

In generic classical and quantum many-body systems, where typically energy and particle number are the only conserved quantities, stationary states are described by thermal equilibrium. In contrast, integrable systems showcase an infinite…

Quantum Gases · Physics 2026-01-13 Alvise Bastianello , Alexey Tikan , Francois Copie , Stephane Randoux , Pierre Suret

This article studies the interrelation between the determining modes property in the two-dimensional (2D) Navier-Stokes equations (NSE) of incompressible fluids and the reconstruction property of two filtering algorithms for continuous data…

Analysis of PDEs · Mathematics 2025-12-11 Elizabeth Carlson , Aseel Farhat , Vincent R. Martinez , Collin Victor

Using well-known mathematical foundations of the elasticity theory, a mathematical model for two solutes transport in a poroelastic material (soft tissue is a typical example) is suggested. It is assumed that molecules of essentially…

Mathematical Physics · Physics 2024-03-04 Roman Cherniha , Joanna Stachowska-Pietka , Jacek Waniewski

A coarse-grained off-lattice model that is not biased in any way to the native state is proposed to fold proteins. To predict the native structure in a reasonable time, the model has included the essential effects of water in an effective…

Statistical Mechanics · Physics 2009-11-11 Nan-yow Chen , Zheng-Yao Su , Chung-Yu Mou

We use a free energy functional theory to elucidate general properties of heterogeneously ordering, fast folding proteins, and we test our conclusions with lattice simulations. We find that both structural and energetic heterogeneity can…

Disordered Systems and Neural Networks · Physics 2009-10-31 Steven S. Plotkin , Jose N. Onuchic

The prediction of the biologically active native conformation of a protein is one of the fundamental challenges of structural biology. This problem remains yet unsolved mainly due to three factors: the partial knowledge of the effective…

Biomolecules · Quantitative Biology 2007-05-23 Jose Luis Alonso , Gregory A. Chass , Imre G. Csizmadia , Pablo Echenique , Alfonso Tarancon

We study a class of exactly solvable models for strongly correlated electrons, defined on a set of N cells, and with infinite on-site repulsion on part of the sites of each cell. For 2N or more electrons the exact ground state is known. We…

Condensed Matter · Physics 2009-10-28 Andreas Giesekus , Uwe Brandt

Characterization of protein energy landscape and conformational ensembles is important for understanding mechanisms of protein folding and function. We studied ensembles of bound and unbound conformations of six proteins to explore their…

Biological Physics · Physics 2012-11-06 Anatoly M. Ruvinsky , Tatsiana Kirys , Alexander V. Tuzikov , Ilya A. Vakser

A simple model of a circularly closed dsDNA in a poor solvent is considered as an example of a semi-flexible polymer with self-attraction. To find the ground states, the conformational energy is computed as a sum of the bending and…

Biological Physics · Physics 2013-04-25 E. L. Starostin

We study the global influence of curvature on the free energy landscape of two-dimensional binary mixtures confined on closed surfaces. Starting from a generic effective free energy, constructed on the basis of symmetry considerations and…

Soft Condensed Matter · Physics 2019-09-11 Piermarco Fonda , Melissa Rinaldin , Daniela J. Kraft , Luca Giomi

A general theoretical framework is developed using free energy functional methods to understand the effects of heterogeneity in the folding of a well-designed protein. Native energetic heterogeneity arising from non-uniformity in native…

Disordered Systems and Neural Networks · Physics 2007-05-23 Steven S. Plotkin , Jose N. Onuchic

A thermodynamic model of formation of multi-component solid solutions as a thermodynamic mixture of their binary components, is proposed. There are obtained expressions for the effective temperature of the equilibrium state of the solid…

Materials Science · Physics 2023-12-05 Sergei Naydenov , Igor Pritula

When a quantum system is placed in thermal environments, we often assume that the system relaxes to the Gibbs state in which decoherence takes place in the system energy eigenbasis. However, when the coupling between the system and the…

Quantum Physics · Physics 2019-12-03 Ketan Goyal , Ryoichi Kawai

RNA function crucially depends on its structure. Thermodynamic models currently used for secondary structure prediction rely on computing the partition function of folding ensembles, and can thus estimate minimum free-energy structures and…

Biomolecules · Quantitative Biology 2022-07-26 Nicola Calonaci , Alisha Jones , Francesca Cuturello , Michael Sattler , Giovanni Bussi

A possible way to extract information about the reversible dissociation of a molecular adhesion bond from force fluctuations observed in force ramp experiments is discussed. For small loading rates the system undergoes a limited number of…

Statistical Mechanics · Physics 2015-06-18 Gregor Diezemann

A central goal of protein-folding theory is to predict the stochastic dynamics of transition paths --- the rare trajectories that transit between the folded and unfolded ensembles --- using only thermodynamic information, such as a…

Biomolecules · Quantitative Biology 2018-08-09 William M. Jacobs , Eugene I. Shakhnovich

The structure of the state-vector space for the two-mode parabose system is investigated and a complete set of state-vectors is constructed. The basis vectors are orthonormal in order $p=2$. In order $p=2$, conserved-charge parabose…

High Energy Physics - Theory · Physics 2008-11-26 Sicong Jing , Charles A. Nelson