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Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

Materials Science · Physics 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

Bismuth vanadate - bismuth molybdate solid-solution was prepared to elaborate ceramics with different amounts of cation vacancies. Dense ceramics with similar microstructures were obtained and the evolution of their melting point, specific…

Temperature-dependent dielectric permittivity of lead-free (LixNa1-x)NbO3 for nominal x = 0.04-0.20, prepared by solid state reaction followed by sintering, was studied to resolve often debated issue pertaining to exactness of morphotropic…

Materials Science · Physics 2014-01-15 S. Mitra , A. R. Kulkarni , Om. Prakash

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

Perovskite solid solutions PbHfO3-PbSnO3 offer valuable opportunities for studying the formation mechsnisms of incommensurate phases, owing to the presence of an intermediate (between cubic and incommensurate) phase, which is stabilized in…

The polycrystalline Sm2MgMnO6 (SMMO) was synthesized at 1173K by means of sol-gel technique. Rietveld refine-ment of X-ray diffraction (XRD) pattern confirmed the formation of a single phase monoclinic structure with space group P21/n. The…

Materials Science · Physics 2017-07-03 Moumin Rudra , Ritwik Maity , T. P. Sinha

Measurements of the electrical and thermal conductivities, thermopower and paramagnetic susceptibility have been performed on single crystal samples of Bi1/2Sr1/2MnO3 and complemented with the X-ray powder diffraction data. A pronounced…

Strongly Correlated Electrons · Physics 2009-11-07 J. Hejtmanek , K. Knizek , Z. Jirak , M. Hervieu , C. Martin , M. Nevriva , P. Beran

We show results of broadband dielectric measurements on the charge ordered, proposed to be mul- tiferroic material LuFe2O4. The temperature and frequency dependence of the complex permittivity as investigated for temperatures above and…

Strongly Correlated Electrons · Physics 2013-05-30 Daniel Niermann , Florian Waschkowski , Joost de Groot , Manuel Angst , Joachim Hemberger

Using Landau-Ginzburg-Devonshire approach, we predict the intrinsic instability of the ferroelectric-ferroelastic domain walls in the multiferroic BiFeO3 emerging from the interplay between the gradient terms of the antiferrodistortive and…

Materials Science · Physics 2019-01-03 Eugene A. Eliseev , Anna N. Morozovska , Christopher T. Nelson , Sergei V. Kalinin

Structural, vibrational and dielectric properties of (Pb1-xBix)(Ti1-xMnx)O3 (PBTM) (0 x 0.50) polycrystalline ceramics have been examined as a function of temperature. Synchrotron-based powder x-ray diffraction was employed to confirm phase…

Reflection and transmission as a function of temperature (5--300 K) have been measured on single crystals of the multiferroic compound FeTe$_{2}$O$_{5}$Br utilizing light spanning the far infrared to the visible portions of the…

Strongly Correlated Electrons · Physics 2015-06-12 K. H. Miller , X. S. Xu , H. Berger , V. Craciun , X. Xi , C. Martin , G. L. Carr , D. B. Tanner

The dielectric response of hard (Fe-doped) and soft (Nb-doped) rhombohedral Pb(Zr0.58Ti0.42)1-xMexO3 (PZT; Me= Fe or Nb) ceramics was studied at subswitching conditions over a wide range of temperatures (50 C to 450 C) and frequencies (10…

Materials Science · Physics 2015-05-14 M. I. Morozov , D. Damjanovic

Iron manganese trioxide (Fe0.25Mn0.75)2O3 nanocrystals were synthesized by the sol-gel method. The 80 K Mossbauer spectrum was well-fitted using two doublets representing the 8b and 24d crystallographic sites of the (FexMn1-x)2O3 phase and…

Lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT) ceramic exhibits excellent dielectric, ferroelectric and piezoelectric properties at the Morphotropic Phase Boundary (MPB). Previously, we demonstrated that the use of the anionic surfactant…

In this manuscript, we report room temperature structural, microstructural, optical, dielectric, and magnetic properties of CuO and Cu0.995La0.005 ceramics, synthesized by solid-state reaction method. La doping in CuO leads to the evolution…

Materials Science · Physics 2022-01-03 Kumar Brajesh , Sudhir Ranjan , Rajeev Gupta , Ambesh Dixit , Ashish Garg

We investigate the relaxation and conduction mechanism of Ba0.90Sr0.10TiO3 (BST) ceramic, synthesized by the solid state reaction method. The dielectric and relaxation properties are analyzed in the temperature range of 380-450{\deg}C with…

Materials Science · Physics 2019-03-27 H. Zaitouni , L. Hajji , E. Choukri , D. Mezzane , Z. Abkhar , L. Essaleh , A. Alimoussa , M. El Marssi , I. A. Luk'yanchuk

We present neutron diffraction measurements in high magnetic fields (0 to 14.5 T) and at low temperatures (2.5, 2.3, 0.77 and 0.068 K) on single crystals of the tetragonal heavy fermion antiferromagnet Ce2RhIn8. For B//[110] the field…

Strongly Correlated Electrons · Physics 2015-06-24 E. G. Moshopoulou , K. Prokes , E. Garcia-Matres , P. G. Pagliuso , J. L. Sarrao , J. D. Thompson

The perovskite (1-x)YMnO$_3$-xBiFeO$_3$ binary system is very promising because of its multiferroic end members. Nanocrystalline phases have been recently obtained by mechanosynthesis across the system, and the perovskite structural…

Dielectric properties of BTZ-BCT ceramics were probed in the frequency range from 10 Hz to 100 THz in a broad temperature range (10-900 K). Polar soft phonon observed in infrared spectra softens with cooling, however below 500 K its…

Materials Science · Physics 2016-12-13 S. Kamba , E. Simon , V. Skoromets , V. Bovtun , M. Kempa , J. Pokorny , M. Savinov , J. Koruza , B. Malic

We report the synthesis of Y-substituted Mg-Zn ferrites using conventional standard ceramic technique. XRD patterns confirm the single phase cubic spinel structure up to x = 0.03 and appearance of a secondary phase of YFeO3for higher Y…

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