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We present a computer simulation study of the crystalline phases of hard ellipsoids of revolution. A previous study [Phys. Rev. E, \textbf{75}, 020402 (2007)] showed that for aspect ratios $a/b\ge 3$ the previously suggested stretched-fcc…

Statistical Mechanics · Physics 2015-05-13 M. Radu , P. Pfleiderer , T. Schilling

We show that hard spheres confined between two parallel hard plates pack denser with periodic adaptive prismatic structures which are composed of alternating prisms of spheres. The internal structure of the prisms adapts to the slit height…

The binodals and the non-ergodicity lines of a binary mixture of hard sphere-like particles with large size ratio are computed for studying the interplay between dynamic arrest and phase separation in depletion-driven colloidal mixtures.…

Soft Condensed Matter · Physics 2009-11-13 Ph. Germain , S. Amokrane

The fundamental measure approach to classical density functional theory has been shown to be a powerful tool to predict various thermodynamic properties of hard-sphere systems. We employ this approach to determine not only one-particle…

Soft Condensed Matter · Physics 2015-11-02 Andreas Härtel , Matthias Kohl , Michael Schmiedeberg

Although there are theoretical predictions [\textit{Eur.~Phys.~J.~E} \textbf{41} (2018) 110] for the rich phase behaviour of colloidal cubes mixed with non-adsorbing polymers, a thorough verification of this phase behaviour is still…

Soft Condensed Matter · Physics 2020-06-04 Frans Dekker , Alvaro Gonzalez Garcia , Albert P. Philipse , Remco Tuinier

We study the phase behaviour of a two-dimensionally confined hard sphere colloidal system in the presence of a periodic light field of two interfering laser beams using Monte Carlo simulations. For a given packing fraction of the particles,…

Condensed Matter · Physics 2007-05-23 Pinaki Chaudhuri , Ajay K. Sood , H. R. Krishnamurthy

Triply-periodic networks are among the most complex and functionally valuable self-assembled morphologies, yet they form in nearly every class of biological and synthetic soft matter building blocks. In contrast to simpler assembly motifs…

Soft Condensed Matter · Physics 2022-06-01 Abhiram Reddy , Michael S. Dimitriyev , Gregory M. Grason

In this paper we complete the study of the phase diagram and conformational states of a stiff homopolymer. It is known that folding of a sufficiently stiff chain results in formation of a torus. We find that the phase diagram obtained from…

Soft Condensed Matter · Physics 2009-10-31 Yu. A. Kuznetsov , E. G. Timoshenko

We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades…

We use specialized Monte Carlo simulation methods and moment free energy calculations to provide conclusive evidence that dense polydisperse spheres at equilibrium demix into coexisting fcc phases, with more phases appearing as the spread…

Statistical Mechanics · Physics 2013-05-29 Peter Sollich , Nigel B. Wilding

A line of hard spheres confined by a transverse harmonic potential, with hard walls at its ends, exhibits a variety of buckled structures as it is compressed longitudinally. Here we show that these may be conveniently observed in a rotating…

Soft Condensed Matter · Physics 2019-09-24 Jens Winkelmann , Adil Mughal , Denis Weaire , Stefan Hutzler

We investigate the structure and dynamics of a hard colloid-star polymer mixture in the range of its arrested phase separation, where an incipient demixing transition is interfering with a nearby vitrification line, focusing on the protein…

Soft Condensed Matter · Physics 2026-01-13 Konstantin N. Moser , Christos N. Likos , Vittoria Sposini

Unlike atoms, colloidal particles are not identical, but can only be synthesised within a finite size tolerance. Colloids are therefore polydisperse, i.e. mixtures of infinitely many components with sizes drawn from a continuous…

Soft Condensed Matter · Physics 2009-11-07 R. M. L. Evans , C. B. Holmes

We present a scaled particle density functional study of two-dimensional binary mixtures of hard convex particles with one or both species being ellipses. In particular, we divide our study into two parts. The first part is devoted to the…

Soft Condensed Matter · Physics 2022-06-07 Yuri Martinez-Raton

We consider homogeneous crystallisation rates in confocal microscopy experiments on colloidal nearly hard spheres at the single particle level. These we compare with Brownian dynamics simuations by carefully modelling the softness in the…

Soft Condensed Matter · Physics 2017-12-27 Jade Taffs , Stephen R. Williams , Hajime Tanaka , C. Patrick Royall

We determine the full kinetic phase diagram for nucleation and growth of crystal phases in a suspension of charged colloids. We calculate nucleation barrier heights for face-centered cubic (fcc) and body-centered cubic (bcc) crystal phases…

Soft Condensed Matter · Physics 2022-08-31 Willem Gispen , Marjolein Dijkstra

The self-assembly of binary nanoparticle superlattices from colloidal mixtures is a promising method for the fabrication of complex colloidal co-crystal structures. However, binary mixtures often form amorphous or metastable phases instead…

Soft Condensed Matter · Physics 2022-05-11 R. Allen LaCour , Timothy C. Moore , Sharon C. Glotzer

We report theoretical and numerical evaluations of the phase diagram for a model of patchy particles. Specifically we study hard-spheres whose surface is decorated by a small number f of identical sites ("sticky spots'') interacting via a…

Soft Condensed Matter · Physics 2009-11-13 Emanuela Bianchi , Piero Tartaglia , Emanuela Zaccarelli , Francesco Sciortino

A hexagonal structure of solid molecular hydrogen with $P6_122$ symmetry is calculated to be more stable below about 200 GPa than the monoclinic $C2/c$ structure identified previously as the best candidate for phase III. We find that the…

Materials Science · Physics 2016-11-01 Bartomeu Monserrat , Richard J. Needs , Eugene Gregoryanz , Chris J. Pickard

In continuation of our work in [A.P. Gantapara et al., Phys. Rev. Lett. 111, 015501 (2013)], we investigate here the thermodynamic phase behavior of a family of truncated hard cubes, for which the shape evolves smoothly from a cube via a…

Soft Condensed Matter · Physics 2015-06-23 Anjan P. Gantapara , Joost de Graaf , René van Roij , Marjolein Dijkstra
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