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Probabilistic (or Bayesian) modeling and learning offers interesting possibilities for systematic representation of uncertainty using probability theory. However, probabilistic learning often leads to computationally challenging problems.…

Computation · Statistics 2018-03-14 Andreas Svensson , Thomas B. Schön , Fredrik Lindsten

Raman spectroscopy is a powerful experimental technique for characterizing molecules and materials that is used in many laboratories. First-principles theoretical calculations of Raman spectra are important because they elucidate the…

Materials Science · Physics 2025-06-25 David A. Egger , Manuel Grumet , Tomáš Bučko

Nonlinear optical microscopy allows rapid high-resolution microscopy with image contrast generated from intrinsic properties of the sample. Established modalities such as multiphoton excited fluorescence and second/third-harmonic generation…

Raman spectroscopy is an effective, low-cost, non-intrusive technique often used for chemical identification. Typical approaches are based on matching observations to a reference database, which requires careful preprocessing, or supervised…

Machine Learning · Computer Science 2022-10-12 Bo Li , Mikkel N. Schmidt , Tommy S. Alstrøm

We propose a statistical model for narrowing line shapes in spectroscopy that are well approximated as linear combinations of Lorentzian or Voigt functions. We introduce a log-Gaussian Cox process to represent the peak locations thereby…

Applications · Statistics 2025-07-01 Teemu Härkönen , Emma Hannula , Matthew T. Moores , Erik M. Vartiainen , Lassi Roininen

Raman scattering spectroscopy is widely used as an analytical technique in various fields, but its measurement process tends to be slow due to the low scattering cross-section. In the last decade, various broadband coherent Raman scattering…

Optics · Physics 2025-05-06 Takuma Nakamura , Kazuki Hashimoto , Takuro Ideguchi

The identification of parameters in mathematical models using noisy observations is a common task in uncertainty quantification. We employ the framework of Bayesian inversion: we combine monitoring and observational data with prior…

Computation · Statistics 2018-05-11 Jonas Latz , Iason Papaioannou , Elisabeth Ullmann

In this paper, we present a Bayesian approach for spectral unmixing of multispectral Lidar (MSL) data associated with surface reflection from targeted surfaces composed of several known materials. The problem addressed is the estimation of…

Methodology · Statistics 2015-10-28 Yoann Altmann , Andrew Wallace , Steve McLaughlin

Raman scattering, an inelastic scattering mechanism, provides information about molecular excitation energies and can be used to identify chemical compounds. Albeit being a powerful analysis tool, especially for label-free biomedical…

Bayesian spectral deconvolution provides a data-driven framework for mathematical model selection and parameter estimation from spectral data. Although highly versatile, it becomes computationally expensive as the number of model…

Computation · Statistics 2026-04-07 Tomohiro Nabika , Yui Hayashi , Masato Okada

We propose a Bayesian statistical model for analyzing coherent anti-Stokes Raman scattering (CARS) spectra. Our quantitative analysis includes statistical estimation of constituent line-shape parameters, underlying Raman signal,…

Applications · Statistics 2020-05-15 Teemu Härkönen , Lassi Roininen , Matthew T. Moores , Erik M. Vartiainen

In performing a Bayesian analysis, two difficult problems often emerge. First, in estimating the parameters of some model for the data, the resulting posterior distribution may be multi-modal or exhibit pronounced (curving) degeneracies.…

Instrumentation and Methods for Astrophysics · Physics 2013-12-20 F. Feroz , J. Skilling

This paper presents a Bayesian algorithm for linear spectral unmixing of hyperspectral images that accounts for anomalies present in the data. The model proposed assumes that the pixel reflectances are linear mixtures of unknown endmembers,…

Methodology · Statistics 2015-10-06 Yoann Altmann , Steve McLaughlin , Alfred Hero

A Bayesian analysis of the probability of a signal in the presence of background is developed, and criteria are proposed for claiming evidence for, or the discovery of a signal. The method is general and in particular applicable to sparsely…

Data Analysis, Statistics and Probability · Physics 2009-11-13 Allen Caldwell , Kevin Kröninger

We propose an approach utilizing gamma-distributed random variables, coupled with log-Gaussian modeling, to generate synthetic datasets suitable for training neural networks. This addresses the challenge of limited real observations in…

Applications · Statistics 2025-07-01 Teemu Härkönen , Erik M. Vartiainen , Lasse Lensu , Matthew T. Moores , Lassi Roininen

Calculation of Raman scattering from molecular dynamics (MD) simulations requires accurate modeling of the evolution of the electronic polarizability of the system along its MD trajectory. For large systems, this necessitates the use of…

Materials Science · Physics 2024-06-12 Atanu Paul , Maya Rubenstein , Anthony Ruffino , Stefan Masiuk , Jonathan Spanier , Ilya Grinberg

Raman spectroscopy is a powerful analytical tool with applications ranging from quality control to cutting edge biomedical research. One particular area which has seen tremendous advances in the past decade is the development of powerful…

Signal Processing · Electrical Eng. & Systems 2020-06-19 M. Hamed Mozaffari , Li-Lin Tay

In this paper, we propose a novel method for separately estimating spectral distributions from images captured by a typical RGB camera. The proposed method allows us to separately estimate a spectral distribution of illumination,…

Image and Video Processing · Electrical Eng. & Systems 2021-06-04 Yuma Kinoshita , Hitoshi Kiya

This paper introduces methodology for performing Bayesian inference sequentially on a sequence of posteriors on spaces of different dimensions. We show how this may be achieved through the use of sequential Monte Carlo (SMC) samplers (Del…

Computation · Statistics 2020-06-02 Richard G Everitt , Richard Culliford , Felipe Medina-Aguayo , Daniel J Wilson

Surface enhanced Raman spectroscopy, is a technique of fundamental importance to analytical science and technology where the amplified Raman spectrum of analytes is used for chemical fingerprinting. Here, we showcase an engineered…

Applied Physics · Physics 2021-06-08 K N Prajapati , Anoop A Nair , S Ravi P Silva , J Mitra