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For classical systems driven out of equilibrium, Crooks derived a relation (the Crooks-Jarzynski relation), whose special cases include a relation (the Crooks relation) equivalent to the Kawasaki non-linear response relation. We derive a…

Statistical Mechanics · Physics 2014-05-26 Hiroshi Matsuoka

We present fluctuation theorems and moment generating function equalities for generalized thermodynamic observables and quantum dynamics described by completely positive trace preserving (CPTP) maps, with and without feedback control. Our…

Quantum Physics · Physics 2013-10-01 Tameem Albash , Daniel A. Lidar , Milad Marvian , Paolo Zanardi

Generalized measurements of an observable performed on a quantum system during a force protocol are investigated and conditions that guarantee the validity of the Jarzynski equality and the Crooks relation are formulated. In agreement with…

Statistical Mechanics · Physics 2014-03-14 Gentaro Watanabe , B. Prasanna Venkatesh , Peter Talkner , Michele Campisi , Peter Hänggi

A fluctuation theorem is proved for the macroscopic currents of a system in a nonequilibrium steady state, by using Schnakenberg network theory. The theorem can be applied, in particular, in reaction systems where the affinities or…

Statistical Mechanics · Physics 2015-06-25 David Andrieux , Pierre Gaspard

We study the motion of an overdamped colloidal particle in a time-dependent non-harmonic potential. We demonstrate the first law-like balance between applied work, exchanged heat, and internal energy on the level of a single trajectory. The…

Statistical Mechanics · Physics 2007-05-23 V. Blickle , T. Speck , L. Helden , U. Seifert , C. Bechinger

We extend Jarzynski's work relation and the second law of thermodynamics to a heat conducting system which is operated by an external agent. These extensions contain a new non equilibrium contribution expressed as the violation of the…

Statistical Mechanics · Physics 2012-09-25 Naoko Nakagawa

Non-equilibrium path integral methods for computing quantum free energy differences are applied to a quantum particle trapped in a harmonic well of uniformly changing strength with the purpose of establishing the convergence properties of…

Statistical Mechanics · Physics 2009-11-13 Ramses van Zon , Lisandro Hernandez de la Pena , Gilles H. Peslherbe , Jeremy Schofield

We show that steady-state probabilities of a nonequilibrium Markovian system can be reconstructed from a weighted ensemble average of finite-time loop-erased paths. Each path $\Gamma$ is weighted by $e^{-S(\Gamma)}$, where $S(\Gamma)$ can…

Statistical Mechanics · Physics 2024-10-15 Ugur Cetiner

The free-energy difference $\Delta F$ between two high-dimensional systems is notoriously difficult to compute, but very important for many applications, such as drug discovery. We demonstrate that an unconventional definition of work…

Soft Condensed Matter · Physics 2024-10-24 Adrianne Zhong , Benjamin Kuznets-Speck , Michael R. DeWeese

The asymptotic behaviour of the work probability distribution in driven non-equilibrium systems is determined using the method of optimal fluctuations. For systems described by Langevin dynamics the corresponding Euler-Lagrange equation…

Statistical Mechanics · Physics 2013-05-29 A. Engel

The well known Bohr-van Leeuwen Theorem states that the orbital diamagnetism of classical charged particles is identically zero in equilibrium. However, results based on real space-time approach using the classical Langevin equation…

Statistical Mechanics · Physics 2015-05-14 Arnab Saha , Sourabh Lahiri , A. M. Jayannavar

Firstly the fluctuation theorems (FT) for expended work in a driven nonequilibrium system, isolated or thermostatted, together with the ensuing Jarzynski work-energy (W-E) relationships, will be discussed and reobtained. Secondly, the…

Statistical Mechanics · Physics 2016-10-31 Carolyne M. Van Vliet

We introduce a straightforward, single-ensemble, path sampling approach to calculate free energy differences based on Jarzynski's relation. For a two-dimensional ``toy'' test system, the new (minimally optimized) method performs roughly one…

Computational Physics · Physics 2009-11-10 F. Marty Ytreberg , Daniel M. Zuckerman

In this work, we numerically verify the Jarzynski equality and Crook fluctuation theorem for a Brownian particle diffusing in a heterogeneous thermal bath and hence having a non-Gaussian position distribution. We use the…

Statistical Mechanics · Physics 2026-03-05 A. Saravanan , I. Iyyappan

We study the thermodynamics of quantum projective measurements by using the set up for the Jarzynski equality. We prove the fluctuations of energy change induced by measurements satisfy the Jarzynski equality, revealing that the quantum…

Statistical Mechanics · Physics 2015-08-31 Juyeon Yi , Yong Woon Kim

Many studies of quantum-size heat engines assume that the dynamics of an internal system is unitary and that the extracted work is equal to the energy loss of the internal system. Both assumptions, however, should be under scrutiny. In the…

Statistical Mechanics · Physics 2017-04-05 Yohei Morikuni , Hiroyasu Tajima , Naomichi Hatano

We present a general quantum fluctuation theorem for the entropy production of an open quantum system coupled to multiple environments, not necessarily at equilibrium. Such a general theorem, when restricted to the weak-coupling and…

Quantum Physics · Physics 2022-06-29 Gabriele De Chiara , Alberto Imparato

In a recent paper, Deffner and Saxena (2015 Phys. Rev. Lett. 114 150601) showed that quantum Jarzynski equality generalizes to PT- symmetric quantum mechanics with unbroken symmetry. later Zeng and Yong (2017 Journal of Phys. Commun. 1…

Statistical Mechanics · Physics 2018-08-28 Saurov Hazarika

In stochastic thermodynamics work is a random variable whose average is bounded by the change in the free energy of the system. In most treatments, however, the work reservoir that absorbs this change is either tacitly assumed or modelled…

Quantum Physics · Physics 2021-03-10 Patryk Lipka-Bartosik , Paweł Mazurek , Michał Horodecki

We derive the differential equation describing the time evolution of the work probability distribution function of a stochastic system which is driven out of equilibrium by the manipulation of a parameter. We consider both systems described…

Statistical Mechanics · Physics 2007-05-23 A. Imparato , L. Peliti