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The nonequilibrium free energy theorems show how distributions of work along nonequilibrium paths are related to free energy differences between the equilibrium states at the end points of these paths. In this paper we develop a natural way…

Statistical Mechanics · Physics 2011-11-09 Stephen R. Williams , Debra J. Searles , Denis J. Evans

Fluctuations of the work performed on a driven quantum system can be characterized by the so-called fluctuation theorems. The Jarzynski relation and the Crooks theorem are famous examples of exact equalities characterizing non-equilibrium…

Quantum Physics · Physics 2018-04-12 Alexey E. Rastegin

Exchange energy statistics between two bodies at different thermal equilibrium obey the Jarzynski-W\'ojcik fluctuation theorem. The corresponding energy scale factor is the difference of the inverse temperatures associated to the bodies at…

The transient quantum fluctuation theorems of Crooks and Jarzynski restrict and relate the statistics of work performed in forward and backward forcing protocols. So far these theorems have been obtained under the assumption that the work…

Statistical Mechanics · Physics 2014-02-07 B. Prasanna Venkatesh , Gentaro Watanabe , Peter Talkner

Nonequilibrium work-Hamiltonian connection for a microstate plays a central role in diverse branches of statistical thermodynamics (fluctuation theorems, quantum thermodynamics, stochastic thermodynamics, etc.). We show that the change in…

Statistical Mechanics · Physics 2017-02-03 P. D. Gujrati

This is a brief review of recently derived relations describing the behaviour of systems far from equilibrium. They include the Fluctuation Theorem, Jarzynski's and Crooks' equalities, and an extended form of the Second Principle for…

Statistical Mechanics · Physics 2009-11-11 Jorge Kurchan

Understanding and manipulating work fluctuations in microscale and nanoscale systems are of both fundamental and practical interest. For example, aspects of work fluctuations will be an important factor in designing nanoscale heat engines.…

Statistical Mechanics · Physics 2014-11-26 Gaoyang Xiao , Jiangbin Gong

Jarzynski's equality sets a strong bound on the probability of violating the second law of thermodynamics by extracting work beyond the free energy difference. We derive finite-time refinements to this bound for driven systems in contact…

Statistical Mechanics · Physics 2023-04-19 Harry J. D. Miller , Martí Perarnau-Llobet

We derive integral quantum fluctuation theorems and quantum Jarzynski equalities for a feedback-controlled system and a memory which registers outcomes of the measurement. The obtained equalities involve the information content, which…

Statistical Mechanics · Physics 2014-01-30 Ken Funo , Yu Watanabe , Masahito Ueda

The probability densities of work that can be exerted on a quantum system initially staying in thermal equilibrium are constrained by the fluctuation relations of Jarzynski and Crooks, when the work is determined by two projective energy…

Quantum Physics · Physics 2019-03-20 Kosuke Ito , Peter Talkner , B. Prasanna Venkatesh , Gentaro Watanabe

Characterizing fluctuations of work in coherent quantum systems is notoriously problematic. Here we reveal the ultimate source of the problem by proving that ($\mathfrak{A}$) energy conservation and ($\mathfrak{B}$) the Jarzynski…

Quantum Physics · Physics 2024-05-08 Karen V. Hovhannisyan , Alberto Imparato

We give a pedagogical introduction to a selection of recently discussed topics in nonequilibrium statistical mechanics, concentrating mostly on formal structures and on general principles. Part I contains an overview of the formalism of…

Mathematical Physics · Physics 2009-11-05 C. Maes , K. Netocny , B. Shergelashvili

The crucial condition in the derivation of the Jarzynski equality (JE) from the fluctuation theorem is that the time integral of the phase space contraction factor can be exactly expressed as the entropy production resulting from the heat…

Statistical Mechanics · Physics 2015-06-25 Z. C. Tu , Zicong Zhou

Stochastic dynamics in the energy representation is employed as a method to study non-equilibrium Brownian-like systems. It is shown that the equation of motion for the energy of such systems can be taken in the form of the Langevin…

Statistical Mechanics · Physics 2015-05-18 Bohdan I. Lev , Alexei D. Kiselev

The Jarzynski identity can describe small-scale nonequilibrium systems through stochastic thermodynamics. The identity considers fluctuating trajectories in a phase space. The complexity geometry frames the discussions on quantum…

High Energy Physics - Theory · Physics 2022-06-08 Chen Bai , Wen-Hao Li , Xian-Hui Ge

We discuss the stochastic thermodynamics of systems that are described by a time-dependent density field, for example simple liquids and colloidal suspensions. For a time-dependent change of external parameters, we show that the Jarzynski…

Statistical Mechanics · Physics 2014-03-18 T. Leonard , B. Lander , U. Seifert , T. Speck

We study nonequilibrium work relations for a space-dependent field with stochastic dynamics (Model A). Jarzynski's equality is obtained through symmetries of the dynamical action in the path integral representation. We derive a set of exact…

Statistical Mechanics · Physics 2011-02-18 Kirone Mallick , Moshe Moshe , Henri Orland

Using the Feynman-Kac formula, a work fluctuation theorem for a Brownian particle in a nonconfining potential, e.g., a potential well with finite depth, is derived. The theorem yields aninequality that puts a lower bound on the average work…

Statistical Mechanics · Physics 2021-02-12 Christoph Streißnig , Holger Kantz

Recent progress on micro- and nanometer scale manipulation has opened the possibility to probe systems small enough that thermal fluctuations of energy and coordinate variables can be significant compared with their mean behavior. We…

Mesoscale and Nanoscale Physics · Physics 2012-11-02 O. -P. Saira , Y. Yoon , T. Tanttu , M. Möttönen , D. V. Averin , J. P. Pekola

A promising method for calculating free energy differences Delta F is to generate non-equilibrium data via ``fast-growth'' simulations or experiments -- and then use Jarzynski's equality. However, a difficulty with using Jarzynski's…

Computational Physics · Physics 2007-05-23 F. Marty Ytreberg , Daniel M. Zuckerman