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Common substitutional isovalent semiconductor alloys usually form disordered metastable phases with positive excess formation enthalpies ({\Delta}H). In contrast, monolayer alloys of transition metal dichalcogenides (TMDs) MX2 (M = Mo, W; X…

Materials Science · Physics 2017-10-17 Ji-Hui Yang , Boris I. Yakobson

Contact resistance of semiconducting transition metal dichalcogenides has been shown to decrease in lateral heterojunctions formed with their metallic phases but its origins remain elusive. Here we combine first principles and quantum…

Mesoscale and Nanoscale Physics · Physics 2020-03-04 Adam Pfeifle , Marcelo A. Kuroda

Metallic transition metal dichalcogenides (TMDs), consisting of H-NbSe$_2$, H-NbS$_2$, H-TaSe$_2$ and H-TaS$_2$, remain superconducting down to a thickness of a single layer. In these materials, thickness affects a variety of properties,…

Using first-principles atomistic simulations, we study the response of atomically-thin layers of transition metal dichalcogenides (TMDs) - a new class of two-dimensional inorganic materials with unique electronic properties - to electron…

Two-dimensional layered materials, such as transition metal dichalcogenides (TMDCs), are promising materials for future electronics owing to their unique electronic properties. With the presence of a band gap, atomically thin gate defined…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Xiang-Xiang Song , Di Liu , Vahid Mosallanejad , Jie You , Tian-Yi Han , Dian-Teng Chen , Hai-Ou Li , Gang Cao , Ming Xiao , Guang-Can Guo , Guo-Ping Guo

Nanolayered post-transition metal monochalcogenides (PTMMCs) stand out as promising advanced two-dimensional (2D) materials. Beyond inheriting the general advantages associated with traditional 2D materials, they exhibit unique properties,…

Materials Science · Physics 2024-03-06 Mingyu Yu , Maria Hilse , Qihua Zhang , Yongchen Liu , Zhengtianye Wang , Stephanie Law

We study the effect of point-defect chalcogen vacancies on the optical properties of monolayer transition metal dichalcogenides using ab initio GW and Bethe-Salpeter equation calculations. We find that chalcogen vacancies introduce…

Materials Science · Physics 2018-10-24 Sivan Refaely-Abramson , Diana Y. Qiu , Steven G. Louie , Jeffrey B. Neaton

Transition metal dichalcogenides (TMDs) represent an entire new class of semiconducting 2D materials with exciting properties. Defects in 2D TMDs can crucially affect their physical and chemical properties. However, characterization of the…

Transition metal dichalcogenide (TMD) monolayers attract great attention due to their specific structural, electronic and mechanical properties. The formation of their lateral heterostructures allows a new degree of flexibility in…

Materials Science · Physics 2020-09-29 Sadegh Imani Yengejeh , William Wen , Yun Wang

Transition metal dichalcogenides (TMDs) attract significant attention due to their exceptional optical, excitonic, mechanical, and electronic properties. Nanostructured multilayer TMDs were recently shown to be highly promising for…

Atomically thin group-VIB transition metal dichalcogenides (TMDs) have recently emerged as a new class of two-dimensional (2D) semiconductors with extraordinary properties including the direct band gap in the visible frequency range, the…

Mesoscale and Nanoscale Physics · Physics 2015-12-08 Gui-Bin Liu , Di Xiao , Yugui Yao , Xiaodong Xu , Wang Yao

In the field of 2D materials, transition metal dichalcogenides (TMDs) are gaining attention for electronic applications. Our study delves into the H-phase monolayer VS$_2$ of the TMD family, analyzing its electronic structure and how strain…

Materials Science · Physics 2024-01-18 Oguzhan Orhan , Şener Özönder , Soner Ozgen

Alloying offers a way to tune many of the properties of the transition metal dichalcogenide (TMD) monolayers. While these systems in many cases have been thoroughly investigated previously, the fundamental understanding of critical…

Materials Science · Physics 2023-04-17 Christopher Linderälv , J. Magnus Rahm , Paul Erhart

Moire superlattices of transition metal dichalcogenide (TMD) bilayers have been shown to host correlated electronic states, which arises from the interplay of emergent moire potential and long-range Coulomb interactions. Here we…

Strongly Correlated Electrons · Physics 2021-04-28 Yang Zhang , Tongtong Liu , Liang Fu

The discovery of archetypal two-dimensional (2D) materials provides enormous opportunities in both fundamental breakthroughs and device applications, as evident by the research booming in graphene, atomically thin transition-metal…

Mesoscale and Nanoscale Physics · Physics 2018-11-27 Chenqiang Hua , Feng Sheng , Qifeng Hu , Zhu-An Xu , Yunhao Lu , Yi Zheng

So far, several transition metal dichalcogenides (TMDCs) based two-dimensional (2D) topological insulators (TIs) have been discovered, all of them based on a tetragonal lattice. However, in 2D crystals, the hexagonal rather than the…

Materials Science · Physics 2016-02-17 Yandong Ma , Liangzhi Kou , Xiao Li , Ying Dai , Thomas Heine

We present a comprehensive first-principles study of the structural and elastic properties of 2H-MX$_2$ transition metal dichalcogenides (TMDs) (M = W, Mo, Ta, Nb; X = S, Se). Using density functional theory with various van der Waals…

Materials Science · Physics 2025-05-12 S. Azadi , A. Azhar , R. V. Belosludov , T. D. Kühne , M. S. Bahramy

Two dimensional transition metal dichalcogenides (TMDC) have very interesting properties for optoelectronic devices. In this work we theoretically investigate and predict that superlattices comprised of MoS$_{2}$ and WSe$_{2}$ multilayers…

Materials Science · Physics 2013-10-29 Yong-Hong Zhao , Feng Yang , Jian Wang , Hong Guo , Wei Ji

Understanding quasiparticle band structures of transition metal dichalcogenides (TMDs) is critical for technological advances of these materials for atomic layer electronics and photonics. Although theoretical calculations to date have…

Mesoscale and Nanoscale Physics · Physics 2015-10-30 Chendong Zhang , Yuxuan Chen , Amber Johnson , Ming-Yang Li , Lain-Jong Li , Patrick C. Mende , Randall M. Feenstra , Chih-Kang Shih

Even the best quality 2D materials have non-negligible concentrations of vacancies and impurities. It is critical to understand and quantify how defects change intrinsic properties, and use this knowledge to generate functionality. This…

Other Condensed Matter · Physics 2020-10-22 Pedro Miguel M. C. de Melo , Zeila Zanolli , Matthieu Jean Verstraete