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Low-energy Hamiltonians with a linear crossing in their energy dispersion (dubbed Dirac Hamiltonians) have recently been the subject of intense investigations. The linear dispersion is often the result of an approximation in the energy…

Quantum Physics · Physics 2024-12-09 Mohammad-Sadegh Vaezi , Davoud Nasr Esfahani

Nonadiabatic dynamics methods are an essential tool for investigating photochemical processes. In the context of employing first principles electronic structure techniques, such simulations can be carried out in a practical manner using…

Chemical Physics · Physics 2024-05-08 Jonathan R. Mannouch , Aaron Kelly

The exact nuclear time-dependent potential energy surface arises from the exact decomposition of electronic and nuclear motion, recently presented in [A. Abedi, N. T. Maitra, and E. K. U. Gross, Phys. Rev. Lett. 105, 123002 (2010)]. Such…

Chemical Physics · Physics 2015-06-16 Federica Agostini , Ali Abedi , Yasumitsu Suzuki , E. K. U. Gross

We show that, during adiabatic evolution, any changes in entanglement can be attributed to a succession of avoided energy level crossings at which eigenvalues swap their eigenvectors. These swaps mediate the generation and redistribution of…

Quantum Physics · Physics 2025-08-14 Einar Gabbassov , Achim Kempf

Dynamical transitions, such as a change from bound to unbound motion, often occur as post-adiabatic crossings of a time-dependent separatrix. Whether or not any given orbit will include such a crossing transition typically depends…

Classical Physics · Physics 2018-11-28 Timo Eichmann , Eike P. Thesing , James R. Anglin

Accurate description of nonadiabatic dynamics of molecules at metal surfaces involving electron transfer has been a longstanding challenge for theory. Here, we tackle this problem by first constructing high-dimensional neural network…

Materials Science · Physics 2024-01-05 Gang Meng , James Gardner , Wenjie Dou , Reinhard J. Maurer , Bin Jiang

Adiabatic quantum computation is based on the adiabatic evolution of quantum systems. We analyse a particular class of qauntum adiabatic evolutions where either the initial or final Hamiltonian is a one-dimensional projector Hamiltonian on…

Quantum Physics · Physics 2015-05-13 Avatar Tulsi

In many quantum technologies adiabatic processes are used for coherent quantum state operations, offering inherent robustness to errors in the control parameters. The main limitation is the long operation time resulting from the requirement…

Quantum Physics · Physics 2019-04-12 A. Vepsäläinen , S. Danilin , G. S. Paraoanu

We review techniques for simulating fully quantum nonadiabatic dynamics using the frozen-width moving Gaussian basis functions to represent the nuclear wavefunction. A choice of these basis functions is primarily motivated by the idea of…

Chemical Physics · Physics 2018-09-05 Loïc Joubert-Doriol , Artur F. Izmaylov

A nonlinear Landau-Zener model was proposed recently to describe, among a number of applications, the nonadiabatic transition of a Bose-Einstein condensate between Bloch bands. Numerical analysis revealed a striking phenomenon that…

Quantum Physics · Physics 2009-11-07 Jie Liu , Li-Bin Fu , Bi-Yiao Ou , Shi-Gang Chen , Qian Niu

Stimulated Raman Adiabatic Passage, a very efficient technique for manipulating a quantum system based on the adiabatic theorem, is analyzed in the case where the manipulated physical system is interacting with a spin bath. Exploitation of…

Quantum Physics · Physics 2023-11-21 Benedetto Militello , Anna Napoli

Fine control of the dynamics of a quantum system is the key element to perform quantum information processing and coherent manipulations for atomic and molecular systems. In this paper we propose a control protocol using a tangent-pulse…

Quantum Physics · Physics 2018-06-27 Guang Yang , Wei Li , Li-Xiang Cen

Quantum pumping, in its different forms, is attracting attention from different fields, from fundamental quantum mechanics, to nanotechnology, to superconductivity. We investigate the crossover of quantum pumping from the adiabatic to the…

We investigate the LiF spectrum up to $7800$ cm$^{-1}$ above the first dissociation limit. The ab initio calculations of the adiabatic potentials and other molecular functions are performed in a wide range of interatomic separations,…

Atomic Physics · Physics 2025-12-03 V. G. Ushakov , A. Yu. Ermilov , E. S. Medvedev

We present a system composed of two flux qubits and a transmission-line resonator. Instead of using the rotating wave approximation (RWA), we analyse the system by the adiabatical approximation methods under two opposite extreme conditions.…

Quantum Physics · Physics 2015-06-04 Ping Yang , Zhi-Ming Zhang

We present an explicit and simple approximation for the superadiabatic excess (over ideal gas) free power functional, admitting the study of the nonequilibrium dynamics of overdamped Brownian many-body systems. The functional depends on the…

Soft Condensed Matter · Physics 2018-02-26 Daniel de las Heras , Matthias Schmidt

An extension of the CCS-method [Chem. Phys. 2004, 304, p. 103-120] for simulating non-adiabatic dynamics with quantum effects of the nuclei is put forward. The time-dependent Schr\"{o}dinger equation for the motion of the nuclei is solved…

Chemical Physics · Physics 2016-07-27 Alexander Humeniuk , Roland Mitrić

Transport of overdamped Brownian particles in a two-dimensional asymmetric tube is investigated in the presence of nonadiabatic periodic driving forces. By using Brownian dynamics simulations we can find that the phenomena in nonadiabatic…

Soft Condensed Matter · Physics 2015-05-18 Bao-quan Ai

Nonadiabatic effects appear due to avoided crossings or conical intersections that are either intrinsic properties in field-free space or induced by a classical laser field in a molecule. It was demonstrated that avoided crossings in…

Chemical Physics · Physics 2019-11-12 András Csehi , Markus Kowalewski , Gábor J. Halász , Ágnes Vibók

This paper investigates the applicability of a recently-proposed nonlinear sparse Bayesian learning (NSBL) algorithm to identify and estimate the complex aerodynamics of limit cycle oscillations. NSBL provides a semi-analytical framework…

Computational Engineering, Finance, and Science · Computer Science 2022-10-24 Rimple Sandhu , Brandon Robinson , Mohammad Khalil , Chris L. Pettit , Dominique Poirel , Abhijit Sarkar
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