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We present an approach for eliminating the gauge freedom for derivative couplings in nonadiabatic dynamics in the presence of geometric phase effects. This approach relies on a bottom-up construction of a parametric quantum Hamiltonian in…

Chemical Physics · Physics 2023-04-18 Alex Krotz , Roel Tempelaar

Efficient descriptions of open quantum systems can be obtained by performing an adiabatic elimination of the fast degrees of freedom and formulating effective operators for the slow degrees of freedom in reduced dimensions. Here, we perform…

The parametric deformations of quasienergies and eigenvectors of unitary operators are applied to the design of quantum adiabatic algorithms. The conventional, standard adiabatic quantum computation proceeds along eigenenergies of…

Quantum Physics · Physics 2015-05-14 Atushi Tanaka , Kae Nemoto

The system undergoes adiabatic evolution when its population in the instantaneous eigenbasis of its time-dependent Hamiltonian changes only negligibly. Realization of such dynamics requires slow-enough changes of the parameters of the…

Quantum Physics · Physics 2015-06-23 Bogdan Damski

We propose a scheme which can produce desired nonadiabatic passages for the stimulated Raman transition in three-level systems. The state transfer in the protocol is realized by following the evolution of the dynamical basis itself and no…

Quantum Physics · Physics 2019-11-27 Hong Cao , Shao-Wu Yao , Li-Xiang Cen

We develop a method for executing robust and selective transfer of populations between a single level and pre-selected superpositions of energy eigenstates. Viewed in the frequency domain, our method amounts to executing a series of…

Quantum Physics · Physics 2009-11-13 Evgeny A. Shapiro , Valery Milner , Moshe Shapiro

The method of the envelope Hamiltonian [K. Toyota, U. Saalmann, and J. M. Rost, New J. Phys. {\bf 17}, 073005~(2015)] is applied to further study a detachment dynamics of a model negative ion in one-dimension in high-frequency regime. This…

Atomic Physics · Physics 2016-10-19 Koudai Toyota

Estimating energy gaps, i.e. the energy difference between two different states, in quantum systems is crucial for understanding their properties. Conventionally, spectral gap estimation relies on independently computing the ground-state…

Quantum Physics · Physics 2025-12-23 Davide Cugini , Francesco Ghisoni , Angela Rosy Morgillo , Francesco Scala

In adiabatic quantum computing the aim is to track an eigenstate as the Hamiltonian changes. In the usual setup this is achieved using the natural time-dependent Hamiltonian evolution of the system and the main technical tool is the…

Quantum Physics · Physics 2026-05-29 Joseph Cunningham , Jérémie Roland

Experimental observations of multi-quantum relaxation of highly vibrationally excited NO scattering from Au(111) are a benchmark for the breakdown of Born-Oppenheimer approximation in molecule-surface systems. This remarkable vibrational…

Chemical Physics · Physics 2019-10-23 Rongrong Yin , Yaolong Zhang , Bin Jiang

Suppressing unwanted transitions out of the instantaneous ground state is a major challenge in unitary adiabatic quantum computation. A recent approach consists in building counterdiabatic potentials approximated using variational…

Quantum Physics · Physics 2022-03-14 Gianluca Passarelli , Rosario Fazio , Procolo Lucignano

We propose a procedure to analyze the relation between the exact factorization of the electron-nuclear wave function and the Born-Oppenheimer approximation. We define the adiabatic limit as the limit of infinite nuclear mass. To this end,…

Chemical Physics · Physics 2016-08-24 F. G. Eich , Federica Agostini

We develop an Over Barrier Model for computing charge exchange between ions and one-active-electron atoms at low impact energies. The main feature of the model is the treatment of the barrier crossing process by the electron within a…

Atomic Physics · Physics 2007-05-23 F. Sattin

Coherent dynamics of atomic matter waves in a standing-wave laser field is studied. In the dressed-state picture, wave packets of ballistic two-level atoms propagate simultaneously in two optical potentials. The probability to make a…

Atomic Physics · Physics 2012-05-29 S. V. Prants

The crossover between two customary limits of phonon-assisted tunneling, the adiabatic and antiadiabatic regimes, is studied systematically in the framework of a minimal model for molecular devices: a resonant level coupled by displacement…

Mesoscale and Nanoscale Physics · Physics 2013-03-29 Eitan Eidelstein , Dotan Goberman , Avraham Schiller

We present an exact solution for one-dimensional overdamped dynamics near a hard wall, allowing us to connect steady-state distributions under confinement with the extreme value statistics of unconfined stochastic processes. This mapping…

Statistical Mechanics · Physics 2024-11-05 Thibaut Arnoulx de Pirey

The evolution of a system induced by counter-diabatic driving mimics the adiabatic dynamics without the requirement of slow driving. Engineering it involves diagonalizing the instantaneous Hamiltonian of the system and results in the need…

Quantum Physics · Physics 2013-09-05 Adolfo del Campo

We review some recent results obtained for the time evolution of wave packets for systems of equations of pseudo-differential type, including Schr{\"o}dinger ones, and discuss their application to the approximation of the associated unitary…

Analysis of PDEs · Mathematics 2020-11-04 Clotilde Kammerer , Caroline Lasser , Didier Robert

The viability of adiabatic quantum computation depends on the slow evolution of the Hamiltonian. The adiabatic switching theorem provides an asymptotic series for error estimates in $1/T$, based on the lowest non-zero derivative of the…

Quantum Physics · Physics 2025-12-25 Thomas D. Cohen , Andrew Li , Hyunwoo Oh , Maneesha Sushama Pradeep

We consider a system described by a controlled bilinear Schr{\"o}dinger equation with three external inputs. We provide a constructive method to approximately steer the system from a given energy level to a superposition of energy levels…

Optimization and Control · Mathematics 2015-02-25 Paolo Mason , Francesca Chittaro
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