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While mid-infrared optical frequency combs have been widely utilized in areas such as trace gas sensing, chemical kinetics, and combustion science, the relatively low power per comb tooth has limited acquisition times and sensitivities. We…

Optics · Physics 2023-09-28 Adam T. Heiniger , Matthew J. Cich , David A. Long

We demonstrate coherent dual frequency-comb spectroscopy for detecting variations in greenhouse gases. High signal-to-noise spectra are acquired spanning 5990 to 6260 cm^-1 (1600 to 1670 nm) covering ~700 absorption features from CO2, CH4,…

Non-thermal molecular plasmas play a crucial role in numerous industrial processes and hold significant potential for driving essential chemical transformations. Accurate information about the molecular composition of the plasmas and the…

The optical frequency comb has made a significant impact in precision spectroscopy and on our ability to probe atomic, molecular and, recently, nuclear transitions to further our understanding of their fundamental properties and how their…

Optics · Physics 2026-02-17 John J. McCauley , DylanP. Tooley , R. Jason Jones

Ultraviolet spectroscopy provides unique insights into the structure of matter with applications ranging from fundamental tests to photochemistry in the earth's atmosphere and astronomical observations from space telescopes. At longer…

Optics · Physics 2024-03-08 Bingxin Xu , Zaijun Chen , Theodor W. Hänsch , Nathalie Picqué

A new method for highly selective remote sensing of atmospheric trace polar molecular gases is described. Based on infrared/terahertz double resonance spectroscopic techniques, the molecule- specific coincidence between the lines of a CO2…

Atomic Physics · Physics 2012-05-15 Dane J. Phillips , Elizabeth A. Tanner , Frank C. De Lucia , Henry O. Everitt

Absorption spectroscopy is a widely used technique that permits the detection and characterization of gas species at low concentrations. We propose a sensing strategy combining the advantages of frequency modulation spectroscopy with the…

Quantum Physics · Physics 2023-03-30 Alexandre Belsley

With the advent of laser frequency combs, coherent light sources that offer equally-spaced sharp lines over a broad spectral bandwidth have become available. One decade after revolutionizing optical frequency metrology, frequency combs hold…

The occurrence of complex organic molecules (COMs) in the gas phase at low temperature in the dense phases of the ISM suggests that a non-thermal desorption mechanism is at work because otherwise, COMs should condense within a short…

Astrophysics of Galaxies · Physics 2019-07-17 E. Dartois , M. Chabot , T. Id Barkach , H. Rothard , B. Augé , A. N. Agnihotri , A. Domaracka , P. Boduch

Mid-infrared microscopy is an important tool for biological analyses, allowing a direct probe of molecular bonds in their low energy landscape. In addition to the label-free extraction of spectroscopic information, the application of…

Vibrational spectroscopy, comprised of infrared absorption and Raman scattering spectroscopy, is widely used for label-free optical sensing and imaging in various scientific and industrial fields. The group theory states that the two…

Chemical Physics · Physics 2019-10-09 Kazuki Hashimoto , Venkata Ramaiah Badarla , Akira Kawai , Takuro Ideguchi

Context. The number of identified complex organic molecules (COMs) in inter- and circumstellar gas-phase environments is steadily increasing. Recent laboratory studies show that many such species form on icy dust grains. At present only…

Solar and Stellar Astrophysics · Physics 2018-03-21 J. Terwisscha van Scheltinga , N. F. W. Ligterink , A. C. A. Boogert , E. F. van Dishoeck , H. Linnartz

Gas samples relevant to health and environment typically contain a plethora of molecular species that span a huge concentration dynamic range. High-concentration molecules impose a strong absorption background that hinders robust…

Optics · Physics 2024-06-07 Qizhong Liang , Apoorva Bisht , Andrew Scheck , Peter G. Schunemann , Jun Ye

Optical spectroscopy and imaging of microscopic samples have opened up a wide range of applications throughout the physical, chemical, and biological sciences. High chemical specificity may be achieved by directly interrogating the…

We describe an instrument which can be used to analyze complex chemical mixtures at high resolution and high sensitivity. Molecules are collisionally cooled with helium gas at cryogenic temperatures (~ 4-7 K), and subsequently detected…

Instrumentation and Detectors · Physics 2019-05-22 Jessica P. Porterfield , Lincoln Satterthwaite , Sandra Eibenberger , David Patterson , Michael C. McCarthy

The sensitivity of molecular fingerprinting is dramatically improved when placing the absorbing sample in a high-finesse optical cavity, thanks to the large increase of the effective path-length. As demonstrated recently, when the…

Interferometric scattering microscopy has been a very promising technology for highly sensitive label-free imaging of a broad spectrum of biological nanoparticles from proteins to viruses in a high-throughput manner. Although it can reveal…

Optics · Physics 2021-08-11 Celalettin Yurdakul , Haonan Zong , Yeran Bai , Ji-Xin Cheng , M. Selim Unlu

Broadband precision spectroscopy is indispensable for providing high fidelity molecular parameters for spectroscopic databases. We have recently shown that mechanical Fourier transform spectrometers based on optical frequency combs can…

Instrumentation and Detectors · Physics 2018-05-09 Lucile Rutkowski , Piotr Maslowski , Alexandra C. Johansson , Amir Khodabakhsh , Aleksandra Foltynowicz

In this paper, we introduce an all-fibered dual-comb spectrometer based on a new design of highly nonlinear fiber to efficiently convert frequency combs from 1.55 micron to 2 micron We show that our spectrometer can be used to measure…

Infrared spectroscopy in the spectral fingerprint region from 6-12 um accesses the largest molecular absorption cross-sections, permitting sensitive, quantitative and species-specific measurements. Here, we show how dual-comb…

Optics · Physics 2023-06-26 O. Kara , L. Maidment , T. Gardiner , P. G. Schunemann , D. T. Reid