Related papers: Regularized Boltzmann entropy determines macroscop…
The thermodynamic limit in statistical thermodynamics of many-particle systems is an important but often overlooked issue in the various applied studies of condensed matter physics. To settle this issue, we review tersely the past and…
Let H and K be Hilbert spaces and T be a coarse-graining from B(H) to B(K). Assume that density matrices D_1 and D_2 acting on H are given. In the paper the consequences of the existence of a coarse-graining S from B(K) to B(H) satisfying…
In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…
The cornerstone of Boltzmann-Gibbs ($BG$) statistical mechanics is the Boltzmann-Gibbs-Jaynes-Shannon entropy $S_{BG} \equiv -k\int dx f(x)\ln f(x)$, where $k$ is a positive constant and $f(x)$ a probability density function. This theory…
The Boltzmann-Gibbs-von Neumann entropy of a large part (of linear size L) of some (much larger) d-dimensional quantum systems follows the so-called area law (as for black holes), i.e., it is proportional to $L^{d-1}$. Here we show, for…
In a recent paper [Franzosi, Physica A {\bf 494}, 302 (2018)], we have suggested to use of the surface entropy, namely the logarithm of the area of a hypersurface of constant energy in the phase space, as an expression for the thermodynamic…
We show, in two different ways, that the Tsallis' partition function and its derivatives are related to thermodynamic quantities such as entropy, internal energy, etc., in the same way as in Boltzmann-Gibbs' formalism, with the Lagrange…
In this paper, we aim to address an important issue about the pseudopotential lattice Boltzmann (LB) model, which has attracted much attention as a mesoscopic model for simulating interfacial dynamics of complex fluids, but suffers from the…
Despite substantial progress in non-equilibrium physics, steady-state (s.s.) probabilities remain intractable to analysis. For a Markov process, s.s. probabilities can be expressed in terms of transition rates using the Matrix-Tree theorem…
Stochastic thermodynamics is the field of study relating fluctuations in stochastic systems to thermodynamic quantities. The total entropy production (EP), is central to the thermodynamic classification of systems. Non-equilibrium systems…
A pedagogical approach for deriving the statistical mechanical partition function, in a manner that emphasizes the key role of entropy in connecting the microscopic states to thermodynamics, is introduced. The connections between the…
Ab initio thermodynamics is a widespread, computationally efficient approach to predict the stable configuration of a surface in contact with a surrounding (gas or liquid) environment. In a prevalent realization of this approach, this…
We study a particle immersed in a heat bath, in the presence of an external force which decays at least as rapidly as $1/x$, for example a particle interacting with a surface through a Lennard-Jones or a logarithmic potential. As time…
The Hamiltonian evolution of an isolated classical system is reversible, yet the second law of thermodynamics states that its entropy can only increase. This has confounded attempts to identify a `Microscopic Dynamical Entropy' (MDE), by…
Starting at the mesoscopic level with a general formulation of stochastic thermodynamics in terms of Markov jump processes, we identify the scaling conditions that ensure the emergence of a (typically nonlinear) deterministic dynamics and…
A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…
The notion of the thermodynamic entropy in the context of quantum mechanics is a controversial topic. While there were proposals to refer von Neumann entropy as the thermodynamic entropy, it has it's own limitations. The observational…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
We reveal a correspondence between temperature and integrability-breaking in classical and quantum many-body systems through the lens of geometry and adiabatic transformations. Decreasing the temperature, obtained in a standard way through…
The cornerstones of Boltzmann-Gibbs and nonextensive statistical mechanics respectively are the entropies $S_{BG} \equiv -k \sum_{i=1}^W p_i \ln p_i $ and $S_{q}\equiv k (1-\sum_{i=1}^Wp_i^{q})/(q-1) (q\in{\mathbb R} ; S_1=S_{BG})$. Through…