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We extend the definition of non-adiabatic entropy production given for Markovian systems in [M. Esposito and C. Van den Broeck, Phys. Rev. Lett. 104 090601, (2010)], to arbitrary non-Markov ergodic dynamics. We also introduce a notion of…

Statistical Mechanics · Physics 2012-09-14 Reinaldo García-García

The particle in an expanding/contracting 1-dimension box is revisited in action-angle like variables with direct thermodynamic interpretation. An angle dependent potential is proposed accurately describing the mechanical behavior while also…

Classical Physics · Physics 2026-04-01 Adrian Faigon

We provide a quantum statistical basis for (a)a characterisation of a complete set of thermodynamic variables and (b) the differentiability of the entropy function of these variables

Mathematical Physics · Physics 2019-03-27 Geoffrey L. Sewell

In a previous work (M. Campisi. Stud. Hist. Phil. M. P. 36 (2005) 275-290) we have addressed the mechanical foundations of equilibrium thermodynamics on the basis of the Generalized Helmholtz Theorem. It was found that the volume entropy…

Statistical Mechanics · Physics 2008-03-09 Michele Campisi

In this work we study the evolution of Boltzmann's entropy in the context of free expansion of a one dimensional interacting gas inside a box. Boltzmann's entropy is defined for single microstates and is given by the phase-space volume…

Statistical Mechanics · Physics 2023-03-29 Subhadip Chakraborti , Abhishek Dhar , Anupam Kundu

In economics, construction of perfect models in a way that would be comparable to the standards customary in physical sciences is generally not feasible. In particular, the observed value for an economic equilibrium may deviate…

Probability · Mathematics 2026-01-05 Esa Nummelin , Elja Arjas

Algorithmic entropy can be seen as a special case of entropy as studied in statistical mechanics. This viewpoint allows us to apply many techniques developed for use in thermodynamics to the subject of algorithmic information theory. In…

Mathematical Physics · Physics 2013-02-27 John C. Baez , Mike Stay

We consider the meta-equilibrium state of a composite system made up of independent subsystems satisfying the additive form of external constraints, as recently discussed by Abe [Phys. Rev. E {\bf 63}, 061105 (2001)]. We derive the additive…

Statistical Mechanics · Physics 2009-11-10 Ramandeep S. Johal

It is well-known in thermodynamics that the creation of correlations costs work. It seems then a truism that if a thermodynamic transformation A->B is impossible, so will be any transformation that in sending A to B also correlates among…

Quantum Physics · Physics 2015-10-13 Matteo Lostaglio , Markus P. Mueller , Michele Pastena

We develop the argument that the Gibbs-von Neumann entropy is the appropriate statistical mechanical generalisation of the thermodynamic entropy, for macroscopic and microscopic systems, whether in thermal equilibrium or not, as a…

Quantum Physics · Physics 2008-01-23 O. J. E. Maroney

It was first suggested by David Z. Albert that the existence of a real, physical non-unitary process (i.e., "collapse") at the quantum level would yield a complete explanation for the Second Law of Thermodynamics (i.e., the increase in…

Quantum Physics · Physics 2018-07-24 R. E. Kastner

The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics…

Quantum Physics · Physics 2015-05-18 X. L. Huang , B. Cui , X. X. Yi

We review a series of experimental studies of the thermodynamics of nonequilibrium processes at the microscale. In particular, in these experiments we studied the fluctuations of the thermodynamic properties of a single optically-trapped…

Statistical Mechanics · Physics 2016-06-22 L. Dinis , I. A. Martínez , É. Roldán , J. M. R. Parrondo , R. A. Rica

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati

In the context of stochastic thermodynamics, a minimal model for non equilibrium steady states has been recently proposed: the Brownian Gyrator (BG). It describes the stochastic overdamped motion of a particle in a two dimensional harmonic…

Statistical Mechanics · Physics 2020-10-07 Andrea Baldassarri , Andrea Puglisi , Luca Sesta

The thermodynamic aspects of the polymorphic phase transition from {\alpha}-indomethacin to {\gamma}-indomethacin are the fundamental key to find the most bioavailable phase of indomethacin. In the present work, varying the temperature and…

Chemical Physics · Physics 2019-02-22 K. P. S. de Brito , T. C. Ramalho , T. R. Cardoso , E. F. F. da Cunha

We develop a Landauer-B\"uttiker theory of entropy evolution in time-dependent strongly coupled electron systems. This formalism naturally avoids the problem of system-bath distinction caused by the strong hybridization of central system…

Mesoscale and Nanoscale Physics · Physics 2018-03-12 Anton Bruch , Caio Lewenkopf , Felix von Oppen

Recently, Marzlin and Sanders (2004) demonstrated an inconsistency when the adiabatic approximation was applied to specific, "inverse" time-evolving systems. Following that, Tong et al. (2005) showed that the widely used traditional…

Quantum Physics · Physics 2009-11-11 T. Vértesi , R. Englman

Let $\Theta$ be a finite alphabet. We consider a bundle of measure preserving transformations $(T_{\theta})_{\theta \in \Theta}$ acting on a probability space $(X,\mu)$, which are chosen randomly according to an ergodic stochastic process…

Dynamical Systems · Mathematics 2022-09-01 Elias Zimmermann

Instead of the work \cite{1} which in according to the Lovelock theorem it could not applicable for all types of 4D curved spacetimes of Einstein Gauss Bonnet (EGB) gravity, authors of the work \cite{2} applied break of diffeomorphism…

High Energy Physics - Theory · Physics 2022-12-08 Hossein Ghaffarnejad , Elham Ghasami , Emad Yaraie , Mohammad Farsam