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Strain engineering of perovskite oxide thin films has proven to be an extremely powerful method for enhancing and inducing ferroelectric behavior. In ferroelectric thin films and superlattices, the polarization is intricately linked to…

We use first principles density functional theory calculations to investigate the effect of biaxial strain in the low-temperature structural and ferroelectric properties of [111]-oriented SrTiO$_3$. We find that [111] biaxial strain,…

Materials Science · Physics 2019-03-27 Sebastian E. Reyes-Lillo , Karin M. Rabe , Jeffrey B. Neaton

The polarization and strain response of ferroelectric materials at fields below the macroscopic coercive field is of a paramount importance for the operation of many electronic devices. The response of real ferroelectric and related…

Materials Science · Physics 2021-06-08 Lukas M. Riemer , Li Jin , Hana Uršič , Mojca Otonicar , Tadej Rojac , Dragan Damjanovic

Micrometric domains of precise ferroelectric polarization have been written into a 20 nm thick epitaxial thin film of BaTiO3(001) (BTO) on a Nb doped SrTiO3 (STO) substrate using PiezoForce Microscopy (PFM). The domain dependent electronic…

Materials Science · Physics 2018-06-06 N. Barrett , J. Rault , I. Krug , B. Vilquin , G. Niu , B. Gautier , D. Albertini , O. Renault

An electro-optic modulator offers the function of modulating the propagation of light in a material with electric field and enables seamless connection between electronics-based computing and photonics-based communication. The search for…

Materials Science · Physics 2022-05-11 Yang Liu , Guodong Ren , Tengfei Cao , Rohan Mishra , Jayakanth Ravichandran

SrTiO$_3$ is an incipient ferroelectric on the verge of a polar instability, which is avoided at low temperatures by quantum fluctuations. Within this unusual quantum paraelectric phase, superconductivity persists despite extremely dilute…

Superconductivity · Physics 2019-09-12 Ryan Russell , Noah Ratcliff , Kaveh Ahadi , Lianyang Dong , Susanne Stemmer , John W. Harter

Design of novel artificial materials based on ferroelectric perovskites relies on the basic principles of electrostatic coupling and in-plane lattice matching. These rules state that the out-of-plane component of the electric displacement…

Materials Science · Physics 2016-01-20 Claudio Cazorla , Massimiliano Stengel

In this paper we study the size effects of the ferroelectric nanotube phase diagrams and polar properties allowing for effective surface tension and depolarization field influence. The approximate analytical expression for the…

Materials Science · Physics 2007-05-23 A. N. Morozovska , M. D. Glinchuk , E. A. Eliseev

Piezoelectricity is inherent only in noncentrosymmetric materials, but a piezoelectric response can also be obtained in centrosymmetric crystals if subjected to inhomogeneous deformation. This phenomenon, known as flexoelectricity, affects…

Materials Science · Physics 2007-10-22 P. Zubko , G. Catalan , A. Buckley , P. R. L. Welche , J. F. Scott

The mechanocaloric effect is the temperature change of a material upon application or removal of an external stress. Beyond its fundamental interest, this caloric response represents a promising and ecofriendly alternative to current…

Materials Science · Physics 2021-12-01 Diana E. Murillo-Navarro , Mónica Graf , Jorge Íñiguez

Since its original prediction 25 years ago, room-temperature out-of-plane ferroelectricity in compressively strained SrTiO3 remains an ongoing pursuit. In this work, we investigate the structural, electrical and electromechanical properties…

This paper provides a brief introduction to the phenomenological aspects of the polarization in ferrroelectric materials, and then an analysis of a few selected topics related to the modelling of ferroelectrics. The description of…

Emerging Technologies · Computer Science 2023-11-08 David Esseni , Francesco Driussi , Daniel Lizzit , Marco Massarotto , Mattia Segatto

We explore the interplay between ferroelectricity and metallicity, which are generally considered to be contra-indicated properties, in the prototypical ferroelectric barium titanate, BaTiO$_3$. Using first-principles density functional…

Materials Science · Physics 2025-07-22 Veronica F. Michel , Tobias Esswein , Nicola A. Spaldin

Understanding ferroelectricity is of both fundamental and technological importance to further stimulate the development of new materials designs and manipulations. Here, we perform an in-depth first-principle study on the well-known…

Materials Science · Physics 2022-07-12 Simon Mellaerts , Jin Won Seo , Valeri Afanas'ev , Michel Houssa , Jean-Pierre Locquet

The $\phi(\kpp)\sim \kpp$ relation is called polarization structure. By density functional calculations, we study the polarization structure in ferroelectric perovskite PbTiO$_3$, revealing (1) the $\kpp$ point that contributes most to the…

Materials Science · Physics 2009-01-08 Yanpeng Yao , Huaxiang Fu

We report modifications of the ferroelectric and electrocaloric properties of BaTiO$_3$ by defects. For this purpose, we have combined \textit{ab initio}-based molecular dynamics simulations with a simple model for defects. We find that…

Materials Science · Physics 2016-10-03 Anna Grünebohm , Takeshi Nishimatsu

PbTiO$_3$ is a ferroelectric perovskite semiconductor with favourable electronic and optical properties, making it suitable for a wide range of applications, including photo-catalysis and (opto)electronic devices. Despite its relevance, an…

Materials Science · Physics 2025-12-03 Pietro Pacchioni , Lorenzo Varrassi , Cesare Franchini

The instability of ferroelectric ordering in ultra-thin films is one of the most important fundamental issues pertaining realization of a number of electronic devices with enhanced functionality, such as ferroelectric and multiferroic…

The tunneling electroresistance (TER) for ferroelectric tunnel junctions (FTJs) with BaTiO_{3} (BTO) and PbTiO}_{3} (PTO) barriers is calculated by combining the microscopic electronic structure of the barrier material with a macroscopic…

Materials Science · Physics 2010-12-17 N. F. Hinsche , M. Fechner , P. Bose , S. Ostanin , J. Henk , I. Mertig , P. Zahn

Stable and switchable polarization of ferroelectric materials opens a possibility to electrically control their functional behavior. A particularly promising approach is to employ ferroelectric tunnel junctions where the polarization…