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In this paper, we consider the optimum coordinate of the penta-graphene. Penta-graphene is a new stable carbon allotrope which is stronger than graphene. Here, we compare the band gap of penta-graphene with various density functional theory…

Materials Science · Physics 2016-02-17 H. Einollahzadeh , R. S. Dariani , S. M. Fazeli

The advent of graphene has renewed the interest in other 2D carbon-based materials. Bhattacharya and Jana have proposed a new carbon allotrope, composed of different polygonal carbon rings containing 4, 5, 6, and 10 atoms, named…

Materials Science · Physics 2023-05-24 Caique C. Oliveira , Matheus Medina , Douglas S. Galvao , Pedro A. S. Autreto

By performing firt-principles electronic calculations we propose new a phase of group-V allotropes of antimonene, arsenene and phosphorene in the pentaoctite structure. By calculating the phonon spectra, we show that all these phases are…

Materials Science · Physics 2020-08-31 Erika Nascimento Lima , Andreia Luisa da Rosa , Thomas Frauenheim

We present a tight-binding parametrization for penta-graphene that correctly describes its electronic band structure and linear optical response. The set of parameters is validated by comparing to ab-initio density functional theory…

Materials Science · Physics 2020-12-25 Sergio Bravo , J. D. Correa , Leonor Chico , M. Pacheco

We study how phonon structure manifests itself in the electronic density of states of graphene. A procedure for extracting the value of the electron-phonon renormalization $\lambda$ is developed. In addition, we identify direct phonon…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 E. J. Nicol , J. P. Carbotte

A methodology for constructing a quasi-one-dimensional coupled-resonator phononic metamaterial is presented. This is achieved through the design of artificial phononic analogs of two molecular structures: trans-polyacetylene and…

Penta-graphene (PG) has been identified as a novel 2D material with an intrinsic bandgap, which makes it especially promising for electronics applications. In this work, we use first-principles lattice dynamics and iterative solution of the…

Materials Science · Physics 2016-06-29 Xufei Wu , Vikas Varshney , Jonghoon Lee , Teng Zhang , Jennifer L. Wohlwend , Ajit K. Roy , Tengfei Luo

Using the GW approximation, we study the electronic structure of the recently synthesized hydrogenated graphene, named graphane. For both conformations, the minimum band gap is found to be direct at the $\Gamma$ point, and it has a value of…

Materials Science · Physics 2015-05-13 S. Lebegue , M. Klintenberg , O. Eriksson , M. I. Katsnelson

We show how the magneto-phonon resonance, particularly pronounced in sp2 carbon allotropes, can be used as a tool to probe the band structure of multilayer graphene specimens. Even when electronic excitations cannot be directly observed,…

Mesoscale and Nanoscale Physics · Physics 2012-09-11 C. Faugeras , P Kossacki , A. A. L. Nicolet , M. Orlita , M Potemski , A. Mahmood , D. M. Basko

Penta-graphene is a quasi-two-dimensional carbon allotrope consisting of a pentagonal lattice in which both sp2 and sp3-like carbons are present. Unlike graphene, penta-graphene exhibits a non-zero bandgap, which opens the possibility of…

Using the density-functional-based tight-binding method we performed a systematic comparative study of stability, structural and electronic properties for 12 various types of graphene allotropes, which are likely candidates for engineering…

Materials Science · Physics 2015-05-20 A. N. Enyashin , A. L. Ivanovskii

This work presents a systematic review of the feature-rich essential properties in graphene-related systems using the first-principles method. The geometric and electronic properties are greatly diversified by the number of layers, the…

Chemical Physics · Physics 2017-02-14 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Chiun-Yan Lin , Ming-Fa Lin

Electronic and structural properties of a 3D carbon allotrope made of Hopf-linked graphenes, which we call a Hopfene - a type of topological crystal, are examined by semi-empirical molecular-orbital and density-functional-theoretical…

Materials Science · Physics 2019-12-30 Isao Tomita , Shinichi Saito

Using systematic evolutionary structure searching we propose a new carbon allotrope, phagraphene, standing for penta-hexa-hepta-graphene, because the structure is composed of 5-6-7 carbon rings. This two-dimensional (2D) carbon structure is…

Materials Science · Physics 2015-09-02 Zhenhai Wang , Xiang-Feng Zhou , Xiaoming Zhang , Qiang Zhu , Huafeng Dong , Mingwen Zhao , Artem R. Oganov

Recently, a new carbon 3D carbon allotrope named pentadiamond was proposed. Pentadiamond is composed of carbon atoms in mixed sp$^2$ and sp$^3$-like hybridization. In this work, we have carried out a detailed investigation of the electronic…

Materials Science · Physics 2021-02-03 Raphael M. Tromer , Levy C. Felix , Cristiano F. Woellner , Douglas S. Galvao

We induced periodic biaxial tensile strain in polycrystalline graphene by wrapping it over a substrate with repeating pillar-like structures with a periodicity of 600 nm. Using Raman spectroscopy, we determined to have introduced biaxial…

Materials Science · Physics 2015-11-09 Marjan Aslani , C. Michael Garner , Suhas Kumar , Dennis Nordlund , Piero Pianetta , Yoshio Nishi

Using density functional theory calculations we investigate the electronic structure of graphene doped by deposition of foreign atoms. We demonstrate that, as the charge transfer to the graphene layer increases, the band structure of the…

Materials Science · Physics 2009-11-13 Matteo Calandra , Francesco Mauri

The novel graphene allotropes $\alpha$-, $\beta$-, and $\gamma$-graphyne derive from graphene by insertion of acetylenic groups. The three graphynes are the only members of the graphyne family with the same hexagonal symmetry as graphene…

Mesoscale and Nanoscale Physics · Physics 2013-08-28 Valentin N. Popov , Philippe Lambin

Hydrogenation has proven to be an effective tool to open the bandgap of graphene. In the present density functional study we demonstrate that single-side-hydrogenated graphene is a semiconductor with an indirect bandgap of 1.89 eV, in…

Materials Science · Physics 2011-03-01 Bhalchandra S. Pujari , Sergey Gusarov , Michael Brett , Andriy Kovalenko

Quantum confinement endows two-dimensional (2D) layered materials with exceptional physics and novel properties compared to their bulk counterparts. Although certain two- and few-layer configurations of graphene have been realized and…

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