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We report an implementation of self-consistent Green's function many-body theory within a second-order approximation (GF2) for application with molecular systems. This is done by iterative solution of the Dyson equation expressed in matrix…

Chemical Physics · Physics 2016-11-15 Jordan J. Phillips , Dominika Zgid

The second-order Green's function method (GF2) was shown recently to be an accurate self-consistent approach for electronic structure of correlated systems since the self-energy accounts for both the weak and some of the strong correlation.…

Chemical Physics · Physics 2016-03-31 Daniel Neuhauser , Roi Baer , Dominika Zgid

The second-order Matsubara Green's function method (GF2) is a robust temperature dependent quantum chemistry approach, extending beyond the random-phase approximation. However, till now the scope of GF2 applications was quite limited as…

Chemical Physics · Physics 2017-09-20 Daniel Neuhauser , Roi Baer , Dominika Zgid

We present an approach to renormalized second-order Green's function perturbation theory (GF2) which avoids all dependency on continuous variables, grids or explicit Green's functions, and is instead formulated entirely in terms of static…

Chemical Physics · Physics 2020-06-26 Oliver J. Backhouse , Max Nusspickel , George H. Booth

Including finite-temperature effects from the electronic degrees of freedom in electronic structure calculations of semiconductors and metals is desired; however, in practice it remains exceedingly difficult when using zero-temperature…

Chemical Physics · Physics 2016-11-24 Alicia Rae Welden , Alexander A. Rusakov , Dominika Zgid

We present an implementation of a fully self-consistent finite temperature second order Green's function perturbation theory (GF2) within the diagrammatic Monte Carlo framework. In contrast to the previous implementations of stochastic GF2…

Chemical Physics · Physics 2020-09-22 Blair Winograd , Emanuel Gull , Dominika Zgid

The magnon Hedin's equations are derived via the Schwinger functional derivative technique, and the resulting self-consistent Green's function method is used to calculate ground state spin patterns and magnetic structure factors for…

Strongly Correlated Electrons · Physics 2022-11-30 Zhen Zhao , Claudio Verdozzi , Ferdi Aryasetiawan

We examine fractional charge and spin errors in self-consistent Green's function theory within a second-order approximation (GF2). For GF2 it is known that the summation of diagrams resulting from the self-consistent solution of the Dyson…

Computational Physics · Physics 2016-11-15 Jordan J. Phillips , Alexei A. Kananenka , Dominika Zgid

The self-energy method for quantum impurity models expresses the correlation part of the self-energy in terms of the ratio of two Green's functions and allows for a more accurate calculation of equilibrium spectral functions than is…

Strongly Correlated Electrons · Physics 2021-11-24 H. T. M. Nghiem , T. A. Costi

Previous work in the literature has studied gravitational radiation in black-hole collisions at the speed of light. In particular, it had been proved that the perturbative field equations may all be reduced to equations in only two…

Astrophysics · Physics 2018-10-17 Giampiero Esposito

We derive the second-order approximation (PT2) to the ensemble correlation energy functional by applying the G\"{o}rling-Levy perturbation theory on the ensemble density-functional theory (EDFT). Its performance is checked by calculating…

Computational Physics · Physics 2021-11-17 Zeng-hui Yang

We develop a time dependent second order Green's function theory (GF2) for calculating neutral excited states in molecules. The equation of motion for the lesser Green's function (GF) is derived within the adiabatic approximation to the…

Chemical Physics · Physics 2022-01-19 Wenjie Dou , Joonho Lee , David R. Reichman , Roi Baer , Eran Rabani

We present a self-consistent approach for computing the correlated quasiparticle spectrum of charged excitations in iterative $\mathcal{O}[N^5]$ computational time. This is based on the auxiliary second-order Green's function approach [O.…

Chemical Physics · Physics 2020-10-05 Oliver J. Backhouse , George H. Booth

One-particle Green's function methods can model molecular and solid spectra at zero or non-zero temperatures. One-particle Green's functions directly provide electronic energies and one-particle properties, such as dipole moment. However,…

Chemical Physics · Physics 2021-08-24 Pavel Pokhilko , Sergei Iskakov , Chia-Nan Yeh , Dominika Zgid

Previous work in the literature has studied gravitational radiation in black-hole collisions at the speed of light. In particular, it had been proved that the perturbative field equations may all be reduced to equations in only two…

General Relativity and Quantum Cosmology · Physics 2018-10-18 Giampiero Esposito

Using generalizations of natural orbitals, spin-averaged natural orbitals, and two-particle charge correlators for solids, we investigate electronic structure of antiferromagnetic transition-metal oxides with a fully self-consistent,…

Strongly Correlated Electrons · Physics 2024-02-07 Pavel Pokhilko , Dominika Zgid

The Green-function technique, termed the irreducible Green functions (IGF) method, that is a certain reformulation of the equation-of motion method for double-time temperature dependent Green functions is presented. This method was…

Strongly Correlated Electrons · Physics 2007-05-23 A. L. Kuzemsky

We report an exhaustive study of the performance of different variants of Green function methods for the spherium model in which two electrons are confined to the surface of a sphere and interact via a genuine long-range Coulomb operator.…

Chemical Physics · Physics 2018-07-23 Pierre-François Loos , Pina Romaniello , J. A. Berger

Due to non-linear structure, iterative Green's function methods can result in multiple different solutions even for simple molecular systems. In contrast to the wave-function methods, a detailed and careful analysis of such molecular…

Chemical Physics · Physics 2021-08-24 Pavel Pokhilko , Dominika Zgid

It is well known that second order linear ordinary differential equations with slowly varying coefficients admit slowly varying phase functions. This observation is the basis of the Liouville-Green method and many other techniques for the…

Numerical Analysis · Mathematics 2022-12-19 James Bremer
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