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Motivated by the discovery of superconductivity in beta-pyrochlore oxides, we study property of rattling motion coupled with conduction electrons. We derive the general expression of the Green's function of fully anharmonic lattice…

Strongly Correlated Electrons · Physics 2009-11-13 Masateru Takechi , Kazuo Ueda

We present an embedding scheme for periodic systems that facilitates the treatment of the physically important part (here the unit cell) with advanced electronic-structure methods, that are computationally too expensive for periodic…

Materials Science · Physics 2016-04-08 Wael Chibani , Xinguo Ren , Matthias Scheffler , Patrick Rinke

I review the way the many-body Green functions are used to renormalize the perturbation theory of correlated fermions. The Green functions are introduced to implement systematically dynamical corrections to the static mean-field theory. The…

Strongly Correlated Electrons · Physics 2021-09-21 Václav Janiš

We present a new hybrid method to solve the relativistic Hartree-Fock-Roothan equations where the one- and two-electron radial integrals are evaluated numerically by defining the basis functions on a grid. This procedure reduces the…

Atomic Physics · Physics 2009-10-31 Rajat K. Chaudhuri , Prafulla K. Panda , B. P. Das

The single particle Green's function provides valuable information on the momentum and energy-resolved spectral properties for a strongly correlated system. In large-scale numerical calculations using quantum Monte Carlo (QMC), dynamical…

Strongly Correlated Electrons · Physics 2024-10-01 Maksymilian Kliczkowski , Lauren Keyes , Sayantan Roy , Thereza Paiva , Mohit Randeria , Nandini Trivedi , Maciej M. Maska

We present a formalism for strongly correlated electrons systems which consists in a local approximation of the dynamical three-leg interaction vertex. This vertex is self-consistently computed with a quantum impurity model with dynamical…

Strongly Correlated Electrons · Physics 2016-04-01 Thomas Ayral , Olivier Parcollet

The analytic energy gradients with respect to nuclear motion are derived for natural orbital functional (NOF) theory. The resulting equations do not require to resort to linear-response theory, so the computation of NOF energy gradients is…

Chemical Physics · Physics 2017-09-13 Ion Mitxelena , Mario Piris

In this article we use linear algebra to improve the computational time for the obtaining of Green's functions of linear differential equations with reflection (DER). This is achieved by decomposing both the `reduced' equation (the ODE…

Classical Analysis and ODEs · Mathematics 2017-07-05 F. Adrián F. Tojo

The thermodynamics of low dimensional spin-1/2 Heisenberg ferromagnets (HFM) in an external magnetic field is investigated within a second-order two-time Green function formalism in the wide temperature and field range. A crucial point of…

Strongly Correlated Electrons · Physics 2009-11-13 T. N. Antsygina , M. I. Poltavskaya , I. I. Poltavsky , K. A. Chishko

The energy minimization involved in density functional calculations of electronic systems can be carried out using an exponential transformation that preserves the orthonormality of the orbitals. The energy of the system is then represented…

Computational Physics · Physics 2022-11-09 Aleksei V. Ivanov , Elvar Ö. Jónsson , Tejs Vegge , Hannes Jónsson

In the past decade, natural orbital functional (NOF) approximations have emerged as prominent tools for characterizing electron correlation. Despite their effectiveness, these approaches, which rely on natural orbitals and their associated…

Chemical Physics · Physics 2024-04-19 Ion Mitxelena , Mario Piris

Natural orbital functional theory is considered for systems with one or more unpaired electrons. An extension of the Piris natural orbital functional (PNOF) based on electron pairing approach is presented, specifically, we extend the…

Many-body functionals of the Green's function can provide fundamental advances in electronic-structure calculations, due to their ability to accurately predict both spectral and thermodynamic properties, such as angle-resolved photoemission…

Strongly Correlated Electrons · Physics 2025-08-26 Tommaso Chiarotti , Matteo Quinzi , Andrea Pintus , Mario Caserta , Andrea Ferretti , Nicola Marzari

Polymer self-consistent field theory techniques are used to derive quantum density functional theory without the use of the theorems of density functional theory. Instead, a free energy is obtained from a partition function that is…

Chemical Physics · Physics 2022-11-29 Russell B. Thompson

A general theory for the melting of two dimensional solids explaining the universal and non-universal properties is an open problem up to date. Although the celebrated KTHNY theory have been able to predict the critical properties of the…

Statistical Mechanics · Physics 2024-03-13 Alejandro Mendoza-Coto , Valéria Mattiello , Rômulo Cenci , Nicolò Defenu , Lucas Nicolao

In this paper, the second in a series of two, we complete the derivation of the lowest-order wave function of a dimensional perturbation theory (DPT) treatment for the N-body quantum-confined system. Taking advantage of the symmetry of the…

Quantum Physics · Physics 2007-05-23 M. Dunn , D. K. Watson , J. G. Loeser

The 2D space-fractional Schrodinger equation in the time-independent and time-dependent cases for the scattering problem in the fractional quantum mechanics is studied. We define and give the mathematical expression of the Green's functions…

Mathematical Physics · Physics 2013-01-15 Dong Jianping

We report successful implementation of the time-dependent second-order many-body perturbation theory using optimized orthonormal orbital functions called time-dependent optimized second-order many-body perturbation theory [TD-OMP2] to reach…

Chemical Physics · Physics 2020-08-26 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

Starting from the hamiltonian for the Heisenberg ferromagnet which comprise randomly distributed nonmagnetic ions as impurities in a Bravais lattice, we express the spin operators by means of the Dyson-Maleev transformation in terms of the…

Statistical Mechanics · Physics 2022-08-16 Z. J. Weiss , A. R. Massih

In this paper we are interested in obtaining the exact expression and the study of the constant sign of the Green's function related to a second order perturbed periodic problem coupled with integral boundary conditions at the extremes of…

Classical Analysis and ODEs · Mathematics 2022-01-25 Alberto Cabada , Lucía López-Somoza , Mouhcine Yousfi
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