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While the phenomenon of metal substrate adatom incorporation into molecular overlayers is generally believed to occur in several systems, the experimental evidence for this relies on the interpretation of scanning tunnelling microscopy…

Understanding exotic solids is a difficult task as interactions are often hidden by the symmetry of the system. Here, we study the electronic properties of a noncentrosymmetric solid, BiPd, which is a rare material exhibiting both…

Black phosphorus (bP) is the second known elemental allotrope with a layered crystal structure that can be mechanically exfoliated down to atomic layer thickness. We have fabricated bP naked quantum wells in a back-gated field effect…

Mesoscale and Nanoscale Physics · Physics 2015-09-04 V. Tayari , N. Hemsworth , I. Fakih , A. Favron , E. Gaufrès , G. Gervais , R. Martel , T. Szkopek

Few layer phosphorene(FLP) devices are extensively studied due to its unique electronic properties and potential applications on nano-electronics . Here we present magnetotransport studies which reveal electron-electron interactions as the…

Mesoscale and Nanoscale Physics · Physics 2016-08-02 Yanmeng Shi , Nathaniel Gillgren , Timothy Espiritu , Son Tran , Jiawei Yang , Kenji Watanabe , Takahashi Taniguchi , Chun Ning Lau

The growth and ordering of molecules on surfaces is an intriguing research topic as insights gained here can be of significant relevance for organic electronic devices. While often simple, rigid molecules are employed as model systems, we…

Chemical Physics · Physics 2024-10-02 Baris Oecal , Philipp Weitkamp , Klaus Meerholz , Selina Olthof

Optical and electronic properties of black phosphorus strongly depend on the number of layers and type of stacking. Using first-principles calculations within the framework of density functional theory, we investigate the electronic…

Mesoscale and Nanoscale Physics · Physics 2017-09-07 Cem Sevik , John R. Wallbank , Oguz Gulseren , Francois M. Peeters , Deniz Cakır

When a two-dimensional material, adhered onto a compliant substrate, is subjected to compression it can undertake a buckling instability yielding to a periodic rippling. Interestingly, when black phosphorus flakes are compressed along the…

Applied Physics · Physics 2019-07-18 Luis Vaquero-Garzon , Riccardo Frisenda , Andres Castellanos-Gomez

Few layer black phosphorus is a new two-dimensional material which is of great interest for applications, mainly in electronics. However, its lack of stability severely limits our ability to synthesise and process this material. Here we…

Phosphorene is a new family member of two-dimensional materials. We observed strong and highly layer-dependent photoluminescence in few-layer phosphorene (2 to 5 layers). The results confirmed the theoretical prediction that few-layer…

Mesoscale and Nanoscale Physics · Physics 2014-09-05 Shuang Zhang , Jiong Yang , Renjing Xu , Fan Wang , Weifeng Li , Muhammad Ghufran , Yong-wei Zhang , Zongfu Yu , Gang Zhang , Qinghua Qin , Yuerui Lu

Black phosphorus (BP) is an emerging two-dimensional semiconducting material with great potential for nanoelectronic and nanophotonic applications, especially owing to its unique anisotropic electrical and optical properties. Many…

Two-dimensional (2D) crystals' edge structures not only influence their overall properties but also dictate their formation due to edge-mediated synthesis and etching processes. Edges must be carefully examined because they often display…

Mesoscale and Nanoscale Physics · Physics 2022-08-03 Sol Lee , Yangjin Lee , Li Ping Ding , Kihyun Lee , Feng Ding , Kwanpyo Kim

Phosphorene, a monolayer of black phosphorus, is promising for nanoelectronic applications not only because it is a natural p-type semiconductor but also it possesses a layer-number dependent direct bandgap (in the range of 0.3 eV~1.5 eV).…

Mesoscale and Nanoscale Physics · Physics 2014-03-26 Jun Dai , Xiao Cheng Zeng

Black phosphorus (BP) is a two-dimensional layered material composed of phosphorus atoms. Recently, it was demonstrated that external perturbations such as an electric field close the band gap in few-layer BP, and can even induce a band…

Mesoscale and Nanoscale Physics · Physics 2019-03-11 Jiho Jang , Seongjin Ahn , Hongki Min

Hyperbolic polaritons exhibit large photonic density of states and can be collimated in certain propagation directions. The majority of hyperbolic polaritons are sustained in man-made metamaterials. However, natural-occurring hyperbolic…

Mesoscale and Nanoscale Physics · Physics 2021-09-28 Fanjie Wang , Chong Wang , Andrey Chaves , Chaoyu Song , Guowei Zhang , Shenyang Huang , Yuchen Lei , Qiaoxia Xing , Lei Mu , Yuangang Xie , Hugen Yan

Folded regions are commonly encountered in a number of hexagonal boron nitride (h-BN) based bulk and nanostructured materials. Two types of structural modifications occur in folded h-BN layers: local curvature at the folded edges and…

Materials Science · Physics 2022-11-21 Anthony Impellizzeri , Michele Amato , Chris P. Ewels , Alberto Zobelli

The current state of the art in structural biology is led by NMR, X-ray crystallography and TEM investigations. These powerful tools however all rely on averaging over a large ensemble of molecules. Here, we present an alternative concept…

Atomic and Molecular Clusters · Physics 2015-12-15 Tatiana Latychevskaia , Jean-Nicolas Longchamp , Conrad Escher , Hans-Werner Fink

The puckered surface of black phosphorus represents an ideal substrate for an unconventional arrangement of physisorbed species and the resulting specific two-dimensional chemistry of this system. This opens the way to investigate the…

Controlling the bandgap through local-strain engineering is an exciting avenue for tailoring optoelectronic materials. Two-dimensional crystals are particularly suited for this purpose because they can withstand unprecedented…

While preserving many of the unusual features of single-layer graphene, few-layer graphene (FLG) provides a richness and flexibility of electronic structure that render this set of materials of great interest for both fundamental studies…

Mesoscale and Nanoscale Physics · Physics 2009-08-04 Kin Fai Mak , Matthew Y. Sfeir , James A. Misewich , Tony F. Heinz

The objective of this work is to study the effects of charge redistribution, applied layer-normal electric fields, applied strain, and layer engineering on the band alignment of Black Phosphorus (BP)/Molybdenum disulphide (MoS2)…

Materials Science · Physics 2022-12-28 Nupur Navlakha , Priyamvada Jadaun , Leonard F. Register , Sanjay K. Banerjee