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The structure of an Al(111)3x3-Si surface was examined by combining data from positron diffraction and core-level photoemission spectroscopy. Analysis of the diffraction rocking curves indicated that the overlayer had a flat honeycomb…

Photoelectron diffraction (PED) is a powerful and essential experimental technique for resolving the structure of surfaces with sub-angstrom resolution. In the high energy regime, researchers in angle-resolved photoemission spectroscopy…

There is only a handful of scanning techniques that can provide surface topography at nanometre resolution. At the same time, there are no methods that are capable of non-invasive imaging of the three-dimensional surface topography of a…

Instrumentation and Detectors · Physics 2017-03-07 Tatiana Latychevskaia , Wei-Hao Hsu , Wei-Tse Chang , Chun-Yueh Lin , Ing-Shouh Hwang

We have calculated numerically electron exchange, correlation energies and dynamical polarization function for newly discovered silicene, germanene and black phosphorus (BP), consisting of puckered layers of elemental phosphorus atoms,…

Mesoscale and Nanoscale Physics · Physics 2016-05-30 Andrii Iurov , Godfrey Gumbs , Danhong Huang

We propose previously unknown allotropes of phosphorus carbide (PC) in the stable shape of an atomically thin layer. Different stable geometries, which result from the competition between sp2 bonding found in graphitic C and sp3 bonding…

Materials Science · Physics 2016-05-25 Jie Guan , Dan Liu , Zhen Zhu , David Tomanek

The competition between the electron-hole Coulomb attraction and the three-dimensional dielectric screening dictates the optical properties of layered semiconductors. In low-dimensional materials, the equilibrium dielectric environment can…

Black phosphorus (BP) stands out from other 2D materials by the wide amplitude of the band-gap energy (Delta(Eg)) that sweeps an optical window from Visible (VIS) to Infrared (IR) wavelengths, depending on the layer thickness. This…

Since its discovery, the environmental instability of exfoliated black phosphorus (2D bP) has emerged as a challenge that hampers its wide application in chemistry, physics, and materials science. Many studies have been carried out to…

Excitation of hybrid modes constituted by different material-supported polaritons is a common way to enhance the near-field radiative energy transport, which has fascinating promise in applications of thermal photonics. Here, we investigate…

We studied the electronic structure and optic absorption of phosphorene (monolayer of black phosphorus) under strain. Strain was found to be a powerful tool for the band structure engineering. The in-plane strain in armchair or zigzag…

Mesoscale and Nanoscale Physics · Physics 2016-04-20 Houjian Duan , Mou Yang , Ruiqiang Wang

A surface layer ("skin") that is functionally and structurally different from the bulk was found in single crystals of BiFeO3. Impedance analysis indicates that a previously reported anomaly at T* ~ 275 \pm 5 ^/circC corresponds to a phase…

Materials Science · Physics 2015-05-20 X. Marti , P. Ferrer , J. Herrero-Albillos , J. Narvaez , V. Holy , N. Barrett , M. Alexe , G. Catalan

The two-dimensional semiconductor phosphorene has attracted extensive research interests for potential applications in optoelectronics, spintronics, catalysis, sensors, and energy conversion. To harness phosphorene's potential requires a…

Materials Science · Physics 2021-07-13 Biswas Rijal , Anne Marie Z. Tan , Christoph Freysoldt , Richard G. Hennig

An outstanding challenge of theoretical electronic structure is the description of van der Waals (vdW) interactions in molecules and solids. Renewed interest in resolving this is in part motivated by the technological promise of layered…

Materials Science · Physics 2016-01-20 Luke Shulenburger , Andrew D. Baczewski , Zhen Zhu , Jie Guan , David Tomanek

We study the mechanical and electronic properties of heterobilayers composed of black phosphorus (BP) on hexagonal boron nitride (hBN) and of blue phosphorus (\Pblue) on hBN by means of ab-intio density functional theory. Emphasis is put on…

Materials Science · Physics 2020-07-15 Baptiste Bienvenu , Hakim Amara , François Ducastelle , Lorenzo Sponza

Edge atomic configuration often plays an important role in dictating the properties of finite-sized two-dimensional (2D) materials. By performing ab initio calculations, we identify a highly stable zigzag edge of phosphorene, which is the…

Materials Science · Physics 2017-03-29 Junfeng Gao , Xiangjun Liu , Gang Zhang , Yong-Wei Zhang

Two-dimensional electron gases (2DEG) have been an important source of experimental discovery and conceptual development in condensed matter physics for decades. When combined with the unique electronic properties of two-dimensional (2D)…

Mesoscale and Nanoscale Physics · Physics 2014-11-25 Likai Li , Guo Jun Ye , Vy Tran , Ruixiang Fei , Guorui Chen , Huichao Wang , Jian Wang , Kenji Watanabe , Takashi Taniguchi , Li Yang , Xian Hui Chen , Yuanbo Zhang

Vertical integration of two-dimensional materials has recently emerged as an exciting method for the design of novel electronic and optoelectronic devices. Using density functional theory, we investigatethe structural and electronic…

Materials Science · Physics 2015-06-25 Yongqing Cai , Gang Zhang , Yong-Wei Zhang

We report first principles theoretical investigations of possible metal contacts to monolayer black phosphorus (BP). By analyzing lattice geometry, five metal surfaces are found to have minimal lattice mismatch with BP: Cu(111), Zn(0001),…

Mesoscale and Nanoscale Physics · Physics 2015-02-03 Kui Gong , Lei Zhang , Wei Ji , Hong Guo

We have identified an unusually stable helical coil allotrope of phosphorus. Our ab initio Density Functional Theory calculations indicate that the uncoiled, isolated straight 1D chain is equally stable as a monolayer of black phosphorus…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 Dan Liu , Jie Guan , Jingwei Jiang , David Tomanek

The effect of the number of stacking layers and the type of stacking on the electronic and optical properties of bilayer and trilayer black phosphorus are investigated by using first principles calcula- tions within the framework of density…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Deniz Cakir , Cem Sevik , Francois M. Peeters