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Single layer (SL) phosphorus (phosphorene) has drawn considerable research attention recently as a two-dimensional (2D) material for application promises. It is a semiconductor showing superior transport and optical properties. Few-layer or…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Jin-Peng Xu , Jun-Qiu Zhang , Hao Tian , Hu Xu , Wingkin Ho , Maohai Xie

We report about the energy and momentum resolved optical response of black phosphorus (BP) in its bulk form. Along the armchair direction of the puckered layers we find a highly dispersive mode that is trongly suppressed in the…

Mesoscale and Nanoscale Physics · Physics 2015-03-10 R. Schuster , J. Trinckauf , M. Knupfer , B. Büchner

Silicon can be heavily doped with phosphorus in a single atomic layer (a $\delta$ layer), significantly altering the electronic structure of the conduction bands within the material. Recent progress has also made it possible to further dope…

Materials Science · Physics 2026-02-26 Quinn T. Campbell , Andrew D. Baczewski , Shashank Misra , Evan M. Anderson

Black phosphorus is a quasi-two-dimensional layered semiconductor with a narrow direct band gap of 0.3 eV. A giant surface Stark effect can be produced by the potassium doping of black phosphorus, leading to a semiconductor to semimetal…

Materials Science · Physics 2021-07-21 G. Kremer , M. Rumo , C. Yue , A. Pulkkinen , C. W. Nicholson , T. Jaouen , F. O. von Rohr , P. Werner , C. Monney

Phosphorus diffusion on a Si(100) surface was studied using scanning tunneling microscopy (STM) at temperatures of 77 and 300 K. The phosphorus source utilized was the PBr$_3$ molecule, which fully dissociates on the surface at 77 K. We…

Materials Science · Physics 2025-10-20 T. V. Pavlova , V. M. Shevlyuga

We study collective plasmon excitations and screening of disordered single- and bilayer black phosphorus beyond the low energy continuum approximation. The dynamical polarizability of phosphorene is computed using a tight-binding model that…

Mesoscale and Nanoscale Physics · Physics 2015-09-30 Fengping Jin , Rafael Roldán , Mikhail I. Katsnelson , Shengjun Yuan

Screening in reduced dimensions has strong consequences on the electronic properties in van der Waals semiconductors, impacting the quasiparticle band gap and exciton binding energy. Screening in these materials is typically treated…

Black phosphorus is a material with an intrinsic anisotropy in electronic and optical properties due to its puckered honeycomb lattice. Optical absorption is different for incident light with linear polarization in the armchair and zigzag…

Mesoscale and Nanoscale Physics · Physics 2022-04-20 Leandro Seixas

Recently fabricated two dimensional (2D) phosphorene crystal structures have demonstrated great potential in applications of electronics. Mechanical strain was demonstrated to be able to significantly modify the electronic properties of…

Materials Science · Physics 2014-07-02 Qun Wei , Xihong Peng

In this work, we reported uniform layer-by-layer sublimation of black phosphorus under heating below 600 K. The uniformity and crystallinity of BP samples after thermal thinning were confirmed by Raman spectra and 2D Raman imaging. A…

Materials Science · Physics 2017-08-02 Weijun Luo , Rui Yang , Jialun Liu , Yunlong Zhao , Wenjuan Zhu , Guangrui , Xia

In this work we study the intercalation of monolayer phosphorene with nitrogen, lithium and calcium for exploring prospects of spintronic applications. The electronic and the magnetic properties of the intercalated structure are…

Materials Science · Physics 2021-02-03 S. Koley , S. Basu

Using the first-principles GW-Bethe-Salpeter equation method, here we study the excited-state properties, including quasi-particle band structures and optical spectra, of phosphorene, a two-dimensional (2D) atomic layer of black phosphorus.…

Materials Science · Physics 2015-07-28 Vellayappan Dheivanayagam S/O Ganesan , Chun Zhang , Yuan Ping Feng , Lei Shen

Epitaxial graphene grown on metallic substrates presents, in several cases, a long-range periodic structure due to a lattice mismatch between the graphene and the substrate. For instance, graphene grown on Ir(111), displays a corrugated…

Few-layer black phosphorus (BP), also known as phosphorene, is poised to be the most attractive graphene analogue owing to its high mobility approaching that of graphene, and its thickness- tunable band gap that can be as large as that of…

Materials Science · Physics 2015-03-13 Joon-Seok Kim , Yingnan Liu , Weinan Zhu , Seohee Kim , Di Wu , Li Tao , Ananth Dodabalapur , Keji Lai , Deji Akinwande

As a way to further improve the electronic properties of group V layered semiconductors, we propose to form in-layer 2D heterostructures of black phosphorus and grey arsenic. We use \textit{ab initio} density functional theory to optimize…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Zhen Zhu , Jie Guan , David Tomanek

The allotropes of a new layered material, phosphorus carbide (PC), have been predicted recently and a few of these predicted structures have already been successfully fabricated. Herein, by using first-principles calculations we…

Monolayer phosphorene provides a unique two-dimensional (2D) platform to investigate the fundamental dynamics of excitons and trions (charged excitons) in reduced dimensions. However, owing to its high instability, unambiguous…

Materials Science · Physics 2015-04-30 Jiong Yang , Renjing Xu , Jiajie Pei , Ye Win Myint , Fan Wang , Zhu Wang , Shuang Zhang , Zongfu Yu , Yuerui Lu

The atomic and electronic structure of positively charged P vacancies on InP(110) surfaces is determined by combining scanning tunneling microscopy, photoelectron spectroscopy, and density-functional theory calculations. The vacancy…

Materials Science · Physics 2009-10-31 Ph. Ebert , K. Urban , L. Aballe , C. H. Chen , K. Horn , G. Schwarz , J. Neugebauer , M. Scheffler

Few-layer black phosphorus was recently rediscovered as a narrow-bandgap atomically thin semiconductor and has already attracted unprecedented attention due to its interesting properties. One feature of this material that sets it apart from…

Mesoscale and Nanoscale Physics · Physics 2017-04-04 Artem Mishchenko , Yang Cao , Geliang Yu , Colin R. Woods , Roman V. Gorbachev , Kostya S. Novoselov , Andre K. Geim , Leonid S. Levitov

Tuning band gaps in two-dimensional (2D) materials is of great interest in the fundamental and practical aspects of contemporary material sciences. Recently, black phosphorus (BP) consisting of stacked layers of phosphorene was…

Materials Science · Physics 2017-09-13 Sun-Woo Kim , Hyun Jung , Hyun-Jung Kim , Jin-Ho Choi , Su-Huai Wei , Jun-Hyung Cho