Related papers: Hydrogen isotope exchanges between water and metha…
Deuterium fractionation, as studied through mono-deuterated methanol, is frequently used as a diagnostic tool to trace the physical conditions and chemical evolution of interstellar sources. This study investigates methanol deuteration in…
Accurate quantification of the column density of di-deuterated methanol is a key missing puzzle piece in the otherwise thoroughly constrained family of D-bearing methanol in the deeply embedded low-mass protostellar system and astrochemical…
Prestellar cores represent early sites of low-mass ($M$ $\leq$ few M$_\odot$) star and planet formation and provide insight into initial chemical conditions of complex organic molecules (COMs). Deuterated COMs trace the degree of molecular…
We carry out Monte-Carlo simulation to study deuterium enrichment of interstellar grain mantles under various physical conditions. Based on the physical properties, various types of clouds are considered. We find that in diffuse cloud…
Recent observations indicate that organic molecules are prevalent towards starless and prestellar cores. Deuteration of these molecules has not been well-studied during the starless phase. Published observations of singly-deuterated…
Observations show that the global deuterium-to-hydrogen ratio (D/H) in the local interstellar medium (ISM) is about 90% of the primordial ratio predicted by big bang nucleosynthesis. The high (D/H)$_{ISM}$ implies that only a small fraction…
The HDO/H2O ratio is a powerful diagnostic to understand the evolution of water from the first stages of star formation to the formation of planets and comets. Our aim is to determine precisely the abundance distribution of HDO towards the…
High levels of deuterium fractionation in gas-phase molecules are usually associated with cold regions, such as prestellar cores. Significant fractionation ratios are also observed in hot environments such as hot cores or hot corinos, where…
We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…
Water is detected in environments representing every stage of star and solar system formation, but its chemical evolution throughout these stages remains poorly constrained. Deuterium ratios offer a means of probing chemical links between…
Methyl formate, HCOOCH$_3$, and many of its isotopologues have been detected in astrophysical regions with considerable abundances. However, the recipe for the formation of this molecule and its isotopologues is not yet known. In this work,…
We report the first detection of doubly-deuterated methanol (CHD2OH), as well as firm detections of the two singly-deuterated isotopomers of methanol (CH2DOH and CH3OD), towards the solar-type protostar IRAS16293-2422. From the present…
We investigate the delivery of regular and deuterated forms of water from prestellar cores to circumstellar disks. We adopt a semi-analytical axisymmetric two-dimensional collapsing core model with post-processing gas-ice astrochemical…
We present column density measurements of the HD molecule in the interstellar gas toward 17 Galactic stars. The values for the seven most heavily reddened sightlines, with E(B-V) = 0.38-0.72, are derived from observations with the Far…
Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…
Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of…
Using the IRAM 30m telescope, we mapped the methanol emission in the pre-stellar core L1544 and observed singly deuterated methanol (CH$_2$DOH and CH$_3$OD) towards the dust peak of L1544. Non-LTE radiative transfer modelling was performed…
Methanol is formed via surface reactions on icy dust grains. Methanol is also detected in the gas-phase at temperatures below its thermal desorption temperature and at levels higher than can be explained by pure gas-phase chemistry. The…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
Methanol and complex organic molecules have been found in cold starless cores, where a standard warm-up scenario would not work because of the absence of heat sources. A recent chemical model attributed the presence of methanol and large…