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Optimal control theory is usually formulated as an indirect method requiring the solution of a two-point boundary value problem. Practically, the solution is obtained by iterative forward and backward propagation of quantum wavepackets.…

Quantum Physics · Physics 2020-10-09 Alejandro R. Ramos Ramos , Oliver Kühn

Quantum optimal control theory is a powerful tool for engineering quantum systems subject to external fields such as the ones created by intense lasers. The formulation relies on a suitable definition for a target functional, that…

Quantum Physics · Physics 2015-05-20 David Kammerlander , Alberto Castro , Miguel A. L. Marques

This work investigates the optimal control of the variable-exponent subdiffusion, which extends the work [Gunzburger and Wang, {\it SIAM J. Control Optim.} 2019] to the variable-exponent case to account for the multiscale and crossover…

Optimization and Control · Mathematics 2025-06-03 Yiqun Li , Mengmeng Liu , Wenlin Qiu , Xiangcheng Zheng

Quantum optimal control represents a powerful technique to enhance the performance of quantum experiments by engineering the controllable parameters of the Hamiltonian. However, the computational overhead for the necessary optimization of…

The problem of quantum state preparation is one of the main challenges in achieving the quantum advantage. Furthermore, classically, for multi-level problems, our ability to solve the corresponding quantum optimal control problems is rather…

We investigate theoretically a scheme for spectroscopy of electrons emitted by an on-demand single particle source. The total system, with an electron turnstile source and a single level quantum dot spectrometer, is implemented with edge…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 F. Battista , P. Samuelsson

We demonstrate coherent control over the photoelectron circular dichroism in randomly oriented chiral molecules, based on quantum interference between multiple photoionization pathways. To significantly enhance the chiral signature, we use…

Quantum Physics · Physics 2019-01-16 R. Esteban Goetz , Christiane P. Koch , Loren Greenman

The basic properties of atoms, molecules and solids are governed by electron dynamics which take place on extremely short time scales. To measure and control these dynamics therefore requires ultrafast sources of radiation combined with…

Atomic Physics · Physics 2008-02-27 J. Mauritsson , P. Johnsson , E. Gustafsson , M. Swoboda , T. Ruchon , A. LHuillier , K. J. Schafer

We present theory and calculations for coherent high-fidelity quantum control of many-particle states in semiconductor quantum wells. We show that coupling a two-electron double quantum dot to a terahertz optical source enables targeted…

Mesoscale and Nanoscale Physics · Physics 2013-02-04 E. Rasanen , T. Blasi , M. F. Borunda , E. J. Heller

We report on a combined experimental and theoretical study of XUV ionization of atomic argon in the presence of a near-infrared laser field. The resulting energy- and angle- resolved photoemission spectra have been described in the…

We present a time-dependent density-functional method able to describe the photoelectron spectrum of atoms and molecules when excited by laser pulses. This computationally feasible scheme is based on a geometrical partitioning that…

Atomic Physics · Physics 2012-06-28 U. De Giovannini , D. Varsano , M. A. L. Marques , H. Appel , E. K. U. Gross , A. Rubio

The possibility to induce predetermined coherent quantum dynamics by controlling only the dissipative environmental parameters (such as temperature and pressure) is studied using the combined optimal control and environment engineering…

Quantum Physics · Physics 2015-08-20 Dmitry V. Zhdanov , Tamar Seideman

Existing algorithms for the optimal control of quantum observables are based on locally optimal steps in the space of control fields, or as in the case of genetic algorithms, operate on the basis of heuristics that do not explicitly take…

Quantum Physics · Physics 2007-08-27 Raj Chakrabarti , Rebing Wu , Herschel Rabitz

We derive the fundamental equations of an optimal control theory for systems containing both quantum electrons and classical ions. The system is modeled with Ehrenfest dynamics, a non-adiabatic variant of molecular dynamics. The general…

Chemical Physics · Physics 2015-06-16 Alberto Castro , E. K. U. Gross

We present a new open-source Python package, krotov, implementing the quantum optimal control method of that name. It allows to determine time-dependent external fields for a wide range of quantum control problems, including state-to-state…

The ability to characterise a Hamiltonian with high precision is crucial for the implementation of quantum technologies. In addition to the well-developed approaches utilising optimal probe states and optimal measurements, the method of…

Quantum Physics · Physics 2022-12-14 Shushen Qin , Marcus Cramer , Christiane P. Koch , Alessio Serafini

We investigate the angular distribution of electrons that are emitted in the ionization of hydrogen-like ions by twisted photons. Analysis is performed based on the first-order perturbation theory and the non-relativistic Schr\"odinger…

A New theoretical formalism for the optimal quantum control has been presented. The approach stems from the consideration of describing the time-dependent quantum system in terms of the real physical observables, viz., the probability…

Chemical Physics · Physics 2015-06-26 Bijoy K. Dey

We demonstrate that the angular distribution of electrons knocked out from an atom by a fast charge particle is determined not only by dipole but also by quadrupole transitions, the contribution of which can be considerably enhanced as…

Atomic Physics · Physics 2010-12-30 M. Ya. Amusia , L. V. Chernysheva , E. Z. Liverts

Photoelectron spectroscopy is a powerful method that provides insight into the quantum mechanical properties of a wide range of systems. The ionized electron wavefunction carries information on the structure of the bound orbital, the ionic…