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We have systematically studied a variety of vanadium dioxide (VO2) crystalline forms, including bulk single crystals and oriented thin films, using infrared (IR) near-field spectroscopic imaging techniques. By measuring the IR spectroscopic…

The coexisting rhombohedral-like (R', MA) and tetragonal-like (T', MC) monoclinic phases in compressively strained bismuth ferrite thin films exhibit exceptional piezoelectric and magnetic properties. While previous studies have largely…

Recent experimental results demonstrate that in thin films ferroelectricity persists down to film thickness of a few unit cells. This finding opens an avenue for novel electronic devices based on ultathin ferroelectrics, but also raises…

Materials Science · Physics 2015-06-25 Chun-Gang Duan , Renat F. Sabirianov , Wai-Ning Mei , Sitaram S. Jaswal , Evgeny Y. Tsymbal

NdFeO3 modified polycrystalline ceramics with composition (NdFeO3)0.1-(Ba0.7Sr0.3TiO3)0.9 (NFBST) ceramics have been synthesized via solid-state reaction route. The Rietveld refinement of the XRD data confirmed the existence of a tetragonal…

Materials Science · Physics 2019-06-26 Anumeet Kaur , Lakhwant Singh

Perovskite ferroelectric oxides are usually considered to be brittle materials, however, recent work [Dong et al., Science 366, 475 (2019)] demonstrated the super-elasticity in the freestanding BaTiO3 thin films. This property may originate…

Materials Science · Physics 2020-04-15 Changqing Guo , Guohua Dong , Ziyao Zhou , Ming Liu , Houbing Huang , Jiawang Hong , Xueyun Wang

The novel strain-driven morphotropic phase boundary (MPB) in highly-strained BiFeO3 thin film is featured by ordered mixed phase nanodomains (MPNs). Through scanning probe microscopy and synchrotron X-ray diffraction, eight structural…

Materials Science · Physics 2012-03-01 Lu You , Zuhuang Chen , Xi Zou , Hui Ding , Weigang Chen , Lang Chen , Guoliang Yuan , Junling Wang

The structural and magnetic properties of ultrathin FeO(111) films on Pt(111) with thicknesses from 1 to 16 monolayers (ML) were studied using the nuclear inelastic scattering (NIS) of synchrotron radiation. Distinct evolution of…

Compressed Pr0.5Ca0.5MnO3 films (250nm) deposited on LaAlO3 have been studied by Electron Spin Resonance technique under high frequency and high magnetic field. We show evidences for the presence of a ferromagnetic phase (FM) embedded in…

Strongly Correlated Electrons · Physics 2009-11-10 S. de Brion , G. Storch , G. Chouteau , A. Janossy , W. Prellier , E. Rauwel Buzin

The temperature dependence of the relaxation dynamics in the bilayer thin film heterostructure composed of multiferroic BiFeO$_{3}$ (BFO) and superconducting YBa$_{2}$Cu$_{3}$O$_{7}$ (YBCO) grown on a (001) SrTiO$_{3}$ substrate is studied…

Perovskite oxides hetero-structures are host to a large number of interesting phenomena such as ferroelectricity and 2D-superconductivity. Ferroelectric perovskite oxides have been of significant interest due to their possible use in…

We demonstrate that SrRuO3 and CaRuO3 thin films undergo a room temperature structural phase transition driven by the substrate imposed epitaxial biaxial strain. As tensile strain increases, ARuO3 (A=Ca, Sr) films transform from the…

Materials Science · Physics 2009-11-13 Arturas Vailionis , Wolter Siemons , Gertjan Koster

We study how the ferroelastic domain structure sets in in an epitaxial film of a material with second order proper ferroelastic transition. The domain structures considered are similar to either $a_{1}/a_{2}/a_{1}/a_{2}$ or $c/a/c/a$…

Statistical Mechanics · Physics 2009-11-07 A. M. Bratkovsky , A. P. Levanyuk

Fatigue failure in ferroelectrics has been intensively investigated in the past few decades. Most of the mechanisms discussed for ferroelectric fatigue have been built on the "hypothesis of variation in charged defects", which however are…

Materials Science · Physics 2014-12-09 Qingqing Ke , Amit Kumar , Xiaojie Lou , Yuan Ping Feng , Kaiyang Zeng , Yongqing Cai , John Wang

Weakly coupled ferroelectric/dielectric superlattice thin film heterostructures exhibit complex nanoscale polarization configurations that arise from a balance of competing electrostatic, elastic, and domain-wall contributions to the free…

The experimental data on the thermal properties of the nanostructured perovskite ferroelectrics are presented and analysed. The ability of the modified 3w method for specific heat measurements is discussed and illustrated by the thermal…

Materials Science · Physics 2007-05-23 B. Strukov , S. Davitadze , V. Lemanov , S. Shulman , Y. Uesu , S. Asanuma

We report a Raman scattering investigation of columnar BiFeO3-CoFe2O4 (BFO-CFO) epitaxial thin film nanostructures, where BFO pillars are embedded in a CFO matrix. The feasibility of a strain analysis is illustrated through an investigation…

Materials Science · Physics 2011-08-16 O. Chaix-Pluchery , C. Cochard , P. Jadhav , J. Kreisel , N. Dix , F. Sanchez , J. Fontcuberta

The spectacular metal-to-insulator transition of V2O3 can be progressively suppressed in thin film samples. Evidence for phase separation was observed using microbridges as a mesoscopic probe of transport properties where the same film…

Materials Science · Physics 2009-11-13 C. Grygiel , A. Pautrat , W. C. Sheets , W. Prellier , B. Mercey , L. Mechin

Epitaxial strain can be used to modify the properties of ferroelectric thin films. From the experimental viewpoint, the challenge is to fine-tune the magnitude of the strain. We illustrate how, by using a suitable combination of composition…

Materials Science · Physics 2015-05-20 Gijsbert Rispens , Jeroen A. Heuver , Beatriz Noheda

The dynamics of the charge ordered (CO) state under non-equilibrium conditions created by strong dc-electric field (~106 V/cm) and photo-illumination with short (~ 6 ns) laser pulses is investigated in Bi1-xCaxMnO3 (x > 0.5) epitaxial…

Strongly Correlated Electrons · Physics 2007-05-23 S. Chaudhuri , R. C. Budhani

BiFeO3 thin films are deposited on FTO coated glass substrates using a simple sol-gel deposition technique, limiting thickness about 70 nm and Ag/BiFeO3/FTO RRAM devices are prepared. The devices showed low-voltage bipolar switching with…

Materials Science · Physics 2018-06-13 Chandni Kumari , Ishan Varun , Shree Prakash Tiwari , Ambesh Dixit