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We study the formation of epitaxial graphene on Ru(0001) using fast x-ray photoelectron spectroscopy during the growth process. The assignment of different C 1s and Ru 3d core level components and their evolution during the growth process…

Intercalation of different species under graphene on metals is an effective way to tailor electronic properties of these systems. Here we present the successful intercalation of metallic (Cu) and gaseous (oxygen) specimens underneath…

Materials Science · Physics 2019-08-12 Yuriy Dedkov , Elena Voloshina

Epitaxial graphene, grown on SiC(0001) surface, has been widely studied both experimentally and theoretically. It was found that first epitaxial graphene layer in such structures is a buffer layer i.e. there are no characteristic Dirac…

Materials Science · Physics 2015-03-13 Jakub Soltys , Jacek Piechota , Michal Lopuszynski , Stanislaw Krukowski

The effect of Mn intercalation on the atomic, electronic and magnetic structure of the graphene/Cu(111) interface is studied using state-of-the-art density functional theory calculations. Different structural models of the…

Materials Science · Physics 2021-12-23 Qilin Guo , Yuriy Dedkov , Elena Voloshina

We present a method for decoupling epitaxial graphene grown on SiC(0001) by intercalation of a layer of fluorine at the interface. The fluorine atoms do not enter into a covalent bond with graphene, but rather saturate the substrate Si…

The electronic structure of graphene on Cu(111) and Cu(100) single crystals is investigated using low energy electron microscopy, low energy electron diffraction and angle resolved photoemission spectroscopy. On both substrates the graphene…

We perform a density functional theory study of the effects of oxygen adsorption on the structural and electronic properties of Gr/Co(0001) and Gr/Co/Ir(111) interfaces. In both interfaces, the graphene-Co distance increases with increasing…

Materials Science · Physics 2022-08-05 Dario A. Leon , Andrea Ferretti , Daniele Varsano , Elisa Molinari , Claudia Cardoso

We have investigated the electronic structure of graphene supported on Re(0001) before and after the intercalation of one monolayer of Ag by means of angle-resolved photoemission spectroscopy measurements and density functional theory…

Materials Science · Physics 2014-01-20 M. Papagno , P. Moras , P. M. Sheverdyaeva , J. Doppler , A. Garhofer , F. Mittendorfer , J. Redinger , C. Carbone

The combination of the surface science techniques (STM, XPS, ARPES) and density-functional theory calculations was used to study the decoupling of graphene from Ni(111) by oxygen intercalation. The formation of the antiferromagnetic (AFM)…

Materials Science · Physics 2017-05-26 Yuriy Dedkov , Wolfgang Klesse , Andreas Becker , Florian Späth , Christian Papp , Elena Voloshina

We present a structural analysis of the graphene/Ru(0001) system obtained by surface x-ray diffraction. The data were fit using Fourier-series expanded displacement fields from an ideal bulk structure, plus the application of symmetry…

We use anhydrous ferric chloride (FeCl3) to intercalate graphite flakes consisting of 2 to 4 graphene layers and to dope graphene monolayers. The intercalant, staging, stability and doping of the resulting intercalation compounds (ICs) are…

Materials Science · Physics 2011-06-07 W. J. Zhao , P. H. Tan , J. Liu , A. C. Ferrari

Electrons in graphene behave like Dirac fermions, permitting phenomena from high energy physics to be studied in a solid state setting. A key question is whether or not these Fermions are critically influenced by Coulomb correlations. We…

Strongly Correlated Electrons · Physics 2015-05-20 James P. Reed , Bruno Uchoa , Young Il Joe , Yu Gan , Diego Casa , Eduardo Fradkin , Peter Abbamonte

Electrons in isolated graphene layers are a two-dimensional gas of massless Dirac Fermions. In realistic devices, however, the electronic properties are modified by elastic deformations, interlayer coupling and substrate interaction. Here…

Understanding the nature of the interaction at the graphene/metal interfaces is the basis for graphene-based electron- and spin-transport devices. Here we investigate the hybridization between graphene- and metal-derived electronic states…

Materials Science · Physics 2014-07-17 H. Vita , S. Boettcher , K. Horn , E. N. Voloshina , R. E. Ovcharenko , Th. Kampen , A. Thissen , Yu. S. Dedkov

An elegant approach on the synthesis of graphene on the strong ferromagnetic (FM) material Mn$_5$Ge$_3$ is proposed via intercalation of Mn in the graphene-Ge(111) interface. According to the DFT calculations, graphene in this strongly…

Materials Science · Physics 2019-08-12 Elena Voloshina , Yuriy Dedkov

It is highly desirable to integrate graphene into existing semiconductor technology, where the combined system is thermodynamically stable yet maintain a Dirac cone at the Fermi level. Firstprinciples calculations reveal that a certain…

Mesoscale and Nanoscale Physics · Physics 2012-11-16 Yuanchang Li , Pengcheng Chen , Gang Zhou , Jia Li , Jian Wu , Bing-Lin Gu , S. B. Zhang , Wenhui Duan

Graphene is a fascinating 2D material that is being widely investigated for use in electronic devices due to its unique electronic and materials properties. Also, because of its high thermal stability and inertness, it is considered a…

Mesoscale and Nanoscale Physics · Physics 2017-10-25 Tianbai Li , Jory A. Yarmoff

Free-standing exfoliated monolayer graphene is an ultra-thin flexible membrane, which exhibits out of plane deformation or corrugation. In this paper, a technique is described to measure the band structure of such free-standing graphene by…

We investigate the structural and electronic properties of Li-intercalated monolayer graphene on SiC(0001) using combined angle-resolved photoemission spectroscopy and first-principles density functional theory. Li intercalates at room…

We report measurements of the cyclotron mass in graphene for carrier concentrations n varying over three orders of magnitude. In contrast to the single-particle picture, the real spectrum of graphene is profoundly nonlinear so that the…

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