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We have investigated the atomically-resolved substrate and homoepitaxial thin film surfaces of SrTiO3(001) using low-temperature scanning tunneling microscopy/spectroscopy (STM/STS) combined with pulsed laser deposition (PLD). It was found…

Materials Science · Physics 2015-05-18 Takeo Ohsawa , Katsuya Iwaya , Ryota Shimizu , Tomihiro Hashizume , Taro Hitosugi

The topographic and electronic structure of cleaved SrTiO3(001) surfaces were studied, employing samples that either had or had not been coated with Ti on their outer surfaces prior to fracture. In both cases, SrO- and TiO2-terminated…

Materials Science · Physics 2015-09-16 Wattaka Sitaputra , Marek Skowronski , Randall M. Feenstra

We have systematically investigated the annealing effect on the structure and composition of the polar surface of SrTiO3 (111), starting with an ex-situ chemical etch. The relative surface concentration between Ti and Sr strongly depends on…

Materials Science · Physics 2016-03-14 Mohammad Saghayezhian , Lina Chen , Gaomin Wang , Hangwen Guo , E. W. Plummer , Jiandi Zhang

The surface structure of SrTiO3(001) thin films homoepitaxially grown by PLD in step-flow mode was characterized using low temperature STM. It was found that one-dimensional (1D) TiOx-based nanostructures were formed on the thin film…

Materials Science · Physics 2015-05-18 Katsuya Iwaya , Takeo Ohsawa , Ryota Shimizu , Tomihiro Hashizume , Taro Hitosugi

The surface structure of the SrTiO$_3$(110) polar surface is studied by scanning tunneling microscopy and X-ray photoelectron spectroscopy. Monophased reconstructions in (5$\times$1), (4$\times$1), (2$\times$8), and (6$\times$8) are…

Materials Science · Physics 2015-05-20 Zhiming Wang , Fang Yang , Zhiqiang Zhang , Yuanyuan Tang , Jiagui Feng , Kehui Wu , Qinlin Guo , Jiandong Guo

The availability of low-index rutile TiO2 single crystal substrates with atomically flat surfaces is essential for enabling epitaxial growth of rutile transition metal oxide films. The high surface energy of the rutile (001) surface often…

Materials Science · Physics 2016-03-23 Yang Wang , Shinbuhm Lee , Paolo Vilmercati , Ho Nyung Lee , Hanno H. Weitering , Paul C. Snijders

The surface termination of (100)-oriented LaAlO3 (LAO) single crystals was examined by atomic force microscopy and optimized to produce a single-terminated atomically flat surface by annealing. Then the atomically flat STO film was achieved…

Materials Science · Physics 2012-05-09 Z. Q. Liu , Z. Huang , W. M. Lü , K. Gopinadhan , X. Wang , A. Annadi , T. Venkatesan , Ariando

SrTiO3 plays a central role in oxide electronics. It is the substrate of choice for functional oxide heterostructures based on perovskite-structure thin-film stacks, and its surface or interface with a polar oxide such as LaAlO3 can become…

Materials Science · Physics 2016-10-12 J. M. D. Coey , M Venkatesan , P Stamenov

KTaO3 single crystals with different orientations are used as substrates for the epitaxial growth of thin films and/or as hosts for two-dimensional electron gases. Due to the polar nature of the KTaO3(001) surface, one can expect…

Comparison between single- and the poly-crystalline structures provides essential information on the role of long-range translational symmetry and grain boundaries. In particular, by comparing single- and poly-crystalline transition metal…

Crystal surfaces are sensitive to the surrounding environment, where atoms left with broken bonds reconstruct to minimize surface energy. In many cases, the surface can exhibit chemical properties unique from the bulk. These differences are…

Materials Science · Physics 2016-12-21 Weizong Xu , Preston C. Bowes , Everett D. Grimley , Douglas L. Irving , James M. LeBeau

The surfaces of perovskite oxides affect their functional properties, and while a bulk-truncated (1$\times$1) termination is generally assumed, its existence and stability is controversial. Here, such a surface is created by cleaving the…

We report that a deionized water etching and thermal annealing technique can be effective for preparing atomically-flat and singly-terminated surfaces of single crystalline SrTiO3 substrates. After a two-step thermal-annealing and…

Materials Science · Physics 2013-09-09 J. G. Connell , B. J. Isaac , D. R. Strachan , S. S. A. Seo

Rearrangement of atoms due to broken translational symmetries at the surface of SrTiO$_3$ is scarcely debatable in the present day scenario. Actual concern demands to unveil the true structure and precise mechanism responsible for atomic…

Materials Science · Physics 2018-11-08 Adeel Y Abid , Ning Li , Ayaz Arif , Peng Gao

In this study, we report on investigations of the electronic structure of SrTiO$_3$ annealed at temperature ranging between 550 and 840$^\circ$C in an ultrahigh vacuum. Annealing induced oxygen vacancies (O$_{vac}$) impart considerable…

Materials Science · Physics 2014-08-18 Prabir Pal , Pramod Kumar , Aswin V. , Anjana Dogra , Amish G. Joshi

We investigated how SrOx segregates on a Nb doped SrTiO3 (100) surface by in air annealing. Using atomic force and photoemission electron microscopes, we can directly visualize the morphology and the electronic phase changes with SrOx…

Scanning tunneling spectroscopy suggests the formation of a two dimensional electron gas (2DEG) on the TiO2 terminated surface of undoped SrTiO3 single crystals annealed at temperature lower than 400 {\deg}C in ultra high vacuum conditions.…

Understanding and manipulating properties emerging at a surface or an interface require a thorough knowledge of structure-property relationships. We report a study of a prototype oxide system, La2/3Sr1/3MnO3 grown on SrTiO3(001), by…

Strongly Correlated Electrons · Physics 2019-04-11 Lina Chen , Zhen Wang , Gaomin Wang , Hangwen Guo , Mohammad Saghayezhian , Zhaoliang Liao , Yimei Zhu , E. W. Plummer , Jiandi Zhang

The c(6x2) is a reconstruction of the SrTiO3(001) surface that is formed between 1050-1100oC in oxidizing annealing conditions. This work proposes a model for the atomic structure for the c(6x2) obtained through a combination of results…

Polar crystals composed of charged ionic planes cannot exist in nature without acquiring surface changes to balance an ever-growing dipole. The necessary changes can manifest structurally or electronically. An electronic asymetry has long…

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