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We observe long-range homonuclear diatomic $nD$ Rydberg molecules photoassociated out of an ultracold gas of $^{87}$Rb atoms for 34$\le n \le$40. The measured ground-state binding energies of $^{87}$Rb$(nD-5S_{1/2})$ molecular states are…

Atomic Physics · Physics 2014-04-29 David A. Anderson , Stephanie A. Miller , Georg Raithel

Divalent atoms have emerged as powerful alternatives to alkalis in ultracold atom platforms, offering unique advantages arising from their two-electron structure. Among these species, ytterbium (Yb) is especially promising, yet its anionic…

We present a novel binding mechanism where a neutral Rydberg atom and an atomic ion form a molecular bound state at large internuclear distance. The binding mechanism is based on Stark shifts and level crossings which are induced in the…

Atomic Physics · Physics 2021-12-28 Markus Deiß , Shinsuke Haze , Johannes Hecker Denschlag

We report the creation of ultralong-range Sr$_2$ molecules comprising one ground-state $5s^2$ $^1S_0$ atom and one atom in a $5sns$ $^3S_1$ Rydberg state for $n$ ranging from 29 to 36. Molecules are created in a trapped ultracold atomic gas…

We propose an experiment to demonstrate a novel blockade mechanism caused by long-range anisotropic interactions in an ultracold dipolar gas composed of the recently observed "butterfly" Rydberg molecules. At the blockade radius, the strong…

Atomic Physics · Physics 2017-09-21 Matthew T. Eiles , Hyunwoo Lee , Jesus Perez-Rios , Chris H. Greene

Long-range metastable molecules consisting of two cesium atoms in high Rydberg states have been observed in an ultracold gas. A sequential three-photon two-color photoassociation scheme was employed to form these molecules in states which…

Atomic Physics · Physics 2016-11-17 Heiner Saßmannshausen , Johannes Deiglmayr

Ultracold Rb atoms were used to demonstrate non-degenerate four-wave mixing through a Rydberg state. Continuous 5S-5P-nD two-photon excitation to the Rydberg state was combined with an nD-6P tuned laser in a phase matched geometry. The…

Atomic Physics · Physics 2012-07-13 E. Brekke , J. O. Day , T. G. Walker

We experimentally investigate the mix-dimensional scattering occurring when the collisional partners live in different dimensions. We employ a binary mixture of ultracold atoms and exploit a species-selective 1D optical lattice to confine…

Quantum Gases · Physics 2010-04-16 G. Lamporesi , J. Catani , G. Barontini , Y. Nishida , M. Inguscio , F. Minardi

Rydberg molecules, often exemplified by long-range "trilobite" molecules, are a subject of much recent interest at high principal quantum number $n$. States that use the same bonding mechanism can exist at much lower $n$ and less-extreme…

Atomic Physics · Physics 2017-05-01 R. A. Carollo , J. L. Carini , E. E. Eyler , P. L. Gould , W. C. Stwalley

We observe mixing between two-electron singlet and triplet states in a double quantum dot, caused by interactions with nuclear spins in the host semiconductor. This mixing is suppressed by applying a small magnetic field, or by increasing…

We investigate triatomic molecules that consist of two ground state atoms and a highly excited Rydberg atom, bound at large internuclear distances of thousands of \AA ngstroms. In the molecular state the Rydberg electron is in a…

Atomic Physics · Physics 2019-02-27 Christian Fey , Frederic Hummel , Peter Schmelcher

We present a combined experimental and theoretical study of the effects of Rydberg interactions on Autler-Townes spectra of ultracold gases of atomic strontium. Realizing two-photon Rydberg excitation via a long-lived triplet state allows…

We report the observation of cold Cs Rydberg atom molecules bound at internuclear separations of R~3-9 um. The bound states result from avoided crossings between Rydberg atom pair interaction potentials in an applied electric field. The…

We present a general theoretical treatment and calculations of the fine and hyperfine structures in the spectra of high-$n$ molecular Rydberg states in static uniform electric fields. The treatment combines (i) multichannel quantum-defect…

Atomic Physics · Physics 2026-04-22 Ioana Doran , Leon Jeckel , Maximilian Beyer , Christian Jungen , Frédéric Merkt

The coupling of an isolated quantum state to a continuum is typically associated with decoherence and decreased lifetime. Here, we demonstrate that Rydberg macrodimers, weakly bound pairs of Rydberg atoms, can overcome this dissipative…

We propose an approach to detect individual Rydberg molecules with each molecule consisting of two atoms in different Rydberg states. The scheme exploits the movement of atoms in the presence of an external force that exerts only on atoms…

Quantum Physics · Physics 2017-12-22 Mingxia Huo

We have studied the associative ionization of a Rydberg atom and a ground state atom in an ultracold Rydberg gas. The measured scattering cross section is three orders of magnitude larger than the geometrical size of the produced molecule.…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Torsten Manthey , Tobias M. Weber , Herwig Ott

We report on the observation of highly excited ($\nu \sim 100)$ vibrational states of a trilobite ultralong-range Rydberg molecule in $^{87}$Rb. These states manifest spectroscopically in a regularly spaced series of peaks red-detuned from…

We present combined measurements of the spatially-resolved optical spectrum and the total excited-atom number in an ultracold gas of three-level atoms under electromagnetically induced transparency conditions involving high-lying Rydberg…

We observe a series of conical intersections in the potential energy curves governing both the collision between a Rydberg atom and a ground-state atom and the structure of Rydberg molecules. By employing the electronic energy of the…

Atomic Physics · Physics 2021-07-14 Frederic Hummel , Matthew T. Eiles , Peter Schmelcher