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Related papers: SCAN-based hybrid and double-hybrid density functi…

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Hybrid density functional (HDF) approximations usually deliver higher accuracy than local and semilocal approximations to the exchange-correlation functional, but this comes with drastically increased computational cost. Practical…

Materials Science · Physics 2022-10-12 Yuyang Ji , Peize Lin , Xinguo Ren , Lixin He

The newly developed "strongly constrained and appropriately normed" (SCAN) meta-generalized-gradient approximation (meta-GGA) can generally improve over the non-empirical Perdew-Burke-Ernzerhof (PBE) GGA not only for strong chemical…

Materials Science · Physics 2016-10-19 Haowei Peng , Zeng-Hui Yang , Jianwei Sun , John P. Perdew

This study investigates the impact of exchange-correlation functional choices on the predictive accuracy of multiscale models for charge transport in organic semiconductors (OSCs). A hybrid functional approach is applied to analyze…

Materials Science · Physics 2025-03-31 Zhongquan Chen , Pim van der Hoorn , Bjoern Baumeier

The recent major modification, r$^2$SCAN, of the SCAN (strongly constrained and appropriately normed) meta-GGA exchange-correlation functional is shown to give substantially better spin-crossover electronic energies (high spin minus low…

Chemical Physics · Physics 2021-01-27 Daniel Mejia-Rodriguez , S. B. Trickey

To solve difficulties related to the use of nuclear density functional theory applied in its beyond mean-field version, we introduce a semi-contact 3-body effective interaction. We show that this interaction is a good candidate to replace…

Nuclear Theory · Physics 2015-06-23 Denis Lacroix , Karim Bennaceur

A systematic investigation of even-even superheavy elements in the region of proton numbers $100 \leq Z \leq 130$ and in the region of neutron numbers from the proton-drip line up to neutron number $N=196$ is presented. For this study we…

Nuclear Theory · Physics 2016-04-27 S. E. Agbemava , A. V. Afanasjev , T. Nakatsukasa , P. Ring

Density-functional theory for superfluid systems is developed in the framework of the functional renormalization group based on the effective action formalism. We introduce the effective action for the particle-number and nonlocal pairing…

Nuclear Theory · Physics 2021-05-11 Takeru Yokota , Haruki Kasuya , Kenichi Yoshida , Teiji Kunihiro

This work presents a new class of hybrid density functional theory (DFT) approximations, incorporating nonlocal exact exchange in predefined states such as core atomic orbitals (AOs). These projected hybrid density functionals are a…

Chemical Physics · Physics 2023-05-16 Benjamin G. Janesko

We present an approach to parameterize DFT+$U$+$V$ from hybrid-functional calculations using Wannier-function projections. The method constructs a common localized Wannier basis for both semilocal DFT and hybrid-functional calculations,…

Strongly Correlated Electrons · Physics 2026-02-25 Dmitry M. Korotin , Anna A. Anisimova , Vladimir I. Anisimov

Unlike covalent two-dimensional (2D) materials like graphene, 2D metals have non-layered structures due to their non-directional, metallic bonding. While experiments on 2D metals are still scarce and challenging, density-functional theory…

Materials Science · Physics 2023-01-06 Kameyab Raza Abidi , Pekka Koskinen

Ground and excited states of a confined negative Hydrogen ion has been pursued under Kohn-Sham density functional approach by invoking a physically motivated work-function-based exchange potential. The exchange-only results are of near…

Atomic Physics · Physics 2022-05-23 Sangita Majumdar , Neetik Mukherjee , Amlan K. Roy

Self-consistent-field (SCF) approximations formulated using Hartree-Fock (HF) or Kohn-Sham Density Functional Theory (KS-DFT) both have the potential to yield multiple solutions. However, the formal relationship between multiple solutions…

Chemical Physics · Physics 2021-01-06 Rhiannon A. Zarotiadis , Hugh G. A. Burton , Alex J. W. Thom

The prominence of density functional theory (DFT) in the field of electronic structure computation stems from its ability to usefully balance accuracy and computational effort. At the base of this ability is a functional of the electron…

Nonparametric estimation of the mean and covariance functions is ubiquitous in functional data analysis and local linear smoothing techniques are most frequently used. Zhang and Wang (2016) explored different types of asymptotic properties…

Statistics Theory · Mathematics 2025-01-28 Shaojun Guo , Dong Li , Xinghao Qiao , Yizhu Wang

The construction of meta generalized gradient approximations based on the density matrix expansion (DME) is considered as one of the most accurate technique to design semilocal exchange energy functionals in two-dimensional density…

Materials Science · Physics 2018-05-09 Abhilash Patra , Subrata Jana , Prasanjit Samal

By adopting a divide-and-conquer strategy, subsystem-DFT (sDFT) can dramatically reduce the computational cost of large-scale electronic structure calculations. The key ingredients of sDFT are the nonadditive kinetic energy and…

Materials Science · Physics 2021-08-25 Wenhui Mi , Xuecheng Shao , Alessandro Genova , Davide Ceresoli , Michele Pavanello

The recent development of the accurate and efficient semilocal density functionals on the third rung of Jacob's ladder of density functional theory such as the revised regularized strongly constrained and appropriately normed (r2SCAN)…

Computational Physics · Physics 2023-09-25 Haoliang Liu , Xue Bai , Jingliang Ning , Yuxuan Hou , Zifeng Song , Akilan Ramasamy , Ruiqi Zhang , Yefei Li , Jianwei Sun , Bing Xiao

Kernel-based hypothesis tests offer a flexible, non-parametric tool to detect high-order interactions in multivariate data, beyond pairwise relationships. Yet the scalability of such tests is limited by the computationally demanding…

Methodology · Statistics 2025-06-09 Zhaolu Liu , Robert L. Peach , Mauricio Barahona

Density functionals with a range-separated treatment of the exchange energy are known to improve upon their semilocal forerunners and fixed-fraction hybrids. The conversion of a given semilocal functional into its short-range analog is not…

Chemical Physics · Physics 2019-09-09 Dimitri N. Laikov

The Hubbard model provides a test bed to investigate the complex behaviour arising from electron-electron interaction in strongly-correlated systems and naturally emerges as the foundation model for lattice density functional theory (DFT).…

Strongly Correlated Electrons · Physics 2025-01-29 Eoghan Cronin , Rajarshi Tiwari , Stefano Sanvito
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