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In this work we use first-principles density-functional theory (DFT) calculations combined with the maximally localized Wannier function tight binding Hamiltonian (MLWF-TB) and Bethe-Salpeter equation (BSE) formalism to investigate…

The modification of electronic band structures and the subsequent tuning of electrical, optical, and thermal material properties is a central theme in the engineering and fundamental understanding of solid-state systems. In this scenario,…

Materials Science · Physics 2022-09-12 Valerio Di Giulio , P. A. D. Gonçalves , F. Javier García de Abajo

In this study we present a theoretical investigation of structural, electronic and mechanical properties of pentagonal monolayers of carbon (p-graphene), boron nitride (p-B$_{2}$N$_{4}$ and p-B$_{4}$N$_{2}$) and silver azide (p-AgN$_{3}$)…

Materials Science · Physics 2015-10-06 M. Yagmurcukardes , H. Sahin , J. Kang , E. Torun , F. M. Peeters , R. T. Senger

Recently, a new type of two-dimensional layered material, i.e. C3N, has been fabricated by polymerization of 2,3-diaminophenazine and used to fabricate a field-effect transistor device with an on/off current ratio reaching 5.5E10 (Adv.…

Materials Science · Physics 2017-03-28 Haidi Wang , Hong Wu , Jinlong Yang

We have investigated the effects of number of layers on the structural, vibrational, electronic and optical properties of $\alpha$-PbO using first principles calculations. Our theoretical calculations have shown that four Raman active modes…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Ali Bakhtatou , Fatih Ersan

Black phosphorus (BP) analogous tin(II) sulfide (SnS) has recently emerged as an attractive building block for electronic devices due to its highly anisotropic response. Two-dimensional (2D) SnS has shown to exhibit in-plane anisotropy in…

Systematic engineering of atomic-scale low-dimensional defects in two-dimensional nanomaterials is a promising way to modulate the electronic properties of these nanomaterials. Defects at interfaces such as grain boundaries and line defects…

Materials Science · Physics 2016-01-22 Woosun Jang , Kisung Kang , Aloysius Soon

We examine the structure of compact metal nanoparticles (NPs) forming polyhedral sections of face centered (fcc) and body centered (bcc) cubic lattices, which are confined by facets characterized by highly dense {100}, {110}, and {111}…

Atomic and Molecular Clusters · Physics 2022-03-21 Klaus E. Hermann

The evolution of electronic structure of graphene nanoribbons (GNRs) as a function of the number of layers stacked together is investigated using \textit{ab initio} density functional theory (DFT) including interlayer van der Waals…

Materials Science · Physics 2011-10-28 Neerav Kharche , Yu Zhou , Kevin P. O'Brien , Swastik Kar , Saroj K. Nayak

We report on various nanocarbons formed from a unique structural pattern containing two pentagons, three hexagons and two heptagons, resulting from local rearrange- ments around a divacancy in pristine graphene or nanotubes. This defect can…

Materials Science · Physics 2015-06-03 Jean-Marc Leyssale , G érard L. Vignoles , Antoine Villesuzanne

We explore the possibility and potential benefit of rolling a Si2BN sheet into single-walled nanotubes (NTs). Using density functional theory (DFT), we consider both structural stability and the impact on the nature of chemical bonding and…

Mesoscale and Nanoscale Physics · Physics 2022-03-16 Deobrat Singh , Vivekanand Shukla , Nabil Khossossi , Per Hyldgaard , Rajeev Ahuja

In the latest experimental advances, Ni-, Co- and Cu-HAB MOFs were synthesized in 2D forms, with high electrical conductivities and capacitances as well. Motivated by these experimental advances, we employed first-principles simulations to…

Computational Physics · Physics 2018-11-05 Bohayra Mortazavi , Masoud Shahrokhi , Meysam Makaremi , Gianaurelio Cuniberti , Timon Rabczuk

Using different experimental techniques combined with density functional based theoretical methods we have explored the formation of interface-stabilized manganese oxide structures grown on Pd(100) at (sub)monolayer coverage. Amongst the…

Materials Science · Physics 2015-05-13 C. Franchini , R. Podloucky , F. Allegretti , F. Li , G. Parteder , S. Surnev , F. P. Netzer

Recently, two-dimensional nanostructures consisting of alternating graphene and boron nitride (BN) domains have been synthesized. These systems possess interesting electronic and mechanical properties, with potential applications in…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Yan Li , Riccardo Mazzarello

The graphene and phosphorene nanostructures have a big potential application in a large area of actuals research in physics. However, their methods of synthesis still do not allow the production of perfect materials with an intact molecular…

Mesoscale and Nanoscale Physics · Physics 2018-02-23 Jan Smotlacha , Richard Pincak

Two dimensional materials as electrodes have shown unique advantages such as the infinite planar lengths, broad electrochemical window, and much exposed active sites. In this work, by means of density functional theory computations, we…

Applied Physics · Physics 2019-12-25 Dawei Zhoua , Xin Tangb , Chunying Pua

Two-dimensional materials supporting deep-subwavelength plasmonic modes can also exhibit strong magneto-optical responses. Here, we theoretically investigate magnetoplasmons (MPs) in monolayer black phosphorus (BP) structures under moderate…

Based on extensive evolutionary algorithm driven structural search, we propose a new diphosphorus trisulfide (P2S3) 2D crystal, which is dynamically, thermally and chemically stable as confirmed by the computed phonon spectrum and ab initio…

Materials Science · Physics 2017-03-03 Hang Xiao , Xiaoyang Shi , Feng Hao , Xiangbiao Liao , Yayun Zhang , Xi Chen

Using full-potential density functional calculations we have investigated the structural and electronic properties of graphene and some of its structural analogues, viz., monolayer (ML) of SiC, GeC, BN, AlN, GaN, ZnO, ZnS and ZnSe. While…

Mesoscale and Nanoscale Physics · Physics 2013-05-30 Gautam Mukhopadhyay , Harihar Behera

Nanoporous graphene (NPG), consisting of ordered arrays of nanopores separated by graphene nanoribbons was recently realized using a bottom-up synthesis method (Science 360(2018), 199). In this work we accordingly explored the mechanical…

Mesoscale and Nanoscale Physics · Physics 2019-03-12 Bohayra Mortazavi , Mohamed E. Madjet , Masoud Shahrokhi , Said Ahzi , Xiaoying Zhuang , Timon Rabczuk
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