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One of the fundamental problems of quantum statistical physics is how an ideally isolated quantum system can ever reach thermal equilibrium behavior despite the unitary time evolution of quantum-mechanical systems. Here, we study, via…

Quantum Physics · Physics 2025-06-24 Marvin Lenk , Sayak Biswas , Anna Posazhennikova , Johann Kroha

The thermodynamic entropy of an isolated system is given by its von Neumann entropy. Over the last few years, there is an intense activity to understand thermodynamic entropy from the principles of quantum mechanics. More specifically, is…

Quantum Physics · Physics 2016-07-19 S. Santhosh Kumar , S. Shankaranarayanan

We review the general aspects of the concept of temperature in equilibrium and non-equilibrium statistical mechanics. Although temperature is an old and well-established notion, it still presents controversial facets. After a short…

Statistical Mechanics · Physics 2017-11-13 A. Puglisi , A. Sarracino , A. Vulpiani

A general Werner-type state is studied from two viewpoints: (i) an application of dynamical interaction of the objective system with its environment, represented by a unital positive operator-valued measure (POVM), which ensures increase of…

Statistical Mechanics · Physics 2010-01-22 Sumiyoshi Abe , A. R. Usha Devi , A. K. Rajagopal

The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…

Statistical Mechanics · Physics 2020-07-01 S. N. Saadatmand , Tim Gould , E. G. Cavalcanti , J. A. Vaccaro

The deterministic and time-reversal symmetric dynamics of isolated quantum systems is at odds with irreversible equilibration observed in generic thermodynamic systems. Standard approaches at a reconciliation employ subjective restrictions…

Quantum Physics · Physics 2025-11-07 Aritro Mukherjee

We review with a tutorial scope the information theory foundations of quantum statistical physics. Only a small proportion of the variables that characterize a system at the microscopic scale can be controlled, for both practical and…

Statistical Mechanics · Physics 2007-05-23 R. Balian

We consider conditions under which an isolated quantum system approaches a microcanonical equilibrium state. A key component is the eigenstate thermalisation hypothesis, which proposes that all energy eigenstates appear thermal. We…

Quantum Physics · Physics 2021-09-01 Joe Dunlop , Oliver Cohen , Anthony J. Short

Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level…

Statistical Mechanics · Physics 2015-06-15 George L. Barnes , Michael E. Kellman

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

Quantum Physics · Physics 2025-01-16 Florian Meier , Tom Rivlin , Tiago Debarba , Jake Xuereb , Marcus Huber , Maximilian P. E. Lock

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…

Quantum Physics · Physics 2019-05-01 Mirjam Weilenmann , Lea Krämer Gabriel , Philippe Faist , Renato Renner

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

There is an intense debate in the recent literature about the correct generalization of Maxwell's velocity distribution in special relativity. The most frequently discussed candidate distributions include the Juettner function as well as…

Statistical Mechanics · Physics 2008-07-08 David Cubero , Jesús Casado-Pascual , Jörn Dunkel , Peter Talkner , Peter Hänggi

The microscopic foundation of the generalized equilibrium statistical mechanics based on the Tsallis entropy is given by using the Gibbs idea of statistical ensembles of the classical and quantum mechanics. The equilibrium distribution…

Statistical Mechanics · Physics 2007-05-23 A. S. Parvan

We study the relaxation of a quantum system towards the thermal equilibrium using tools developed within the context of quantum information theory. We consider a model in which the system is a qubit, and reaches equilibrium after several…

Quantum Physics · Physics 2009-11-07 Valerio Scarani , Mario Ziman , Peter Stelmachovic , Nicolas Gisin , Vladimir Buzek

In their seminal work, Fermi, Pasta, Ulam and Tsingou explored the connection between statistical mechanics and dynamical properties, such as chaos and ergodicity. Even today, seventy years later, the topic is not fully understood: while…

Statistical Mechanics · Physics 2026-04-01 Marco Baldovin , Marco Cattaneo , Dario Lucente , Paolo Muratore-Ginanneschi , Angelo Vulpiani

Equilibrium statistical mechanics is intended to link the microscopic dynamics of particles to the thermodynamic laws for macroscopic quantities. However, the modern statistical theory is faced with significant difficulties, as applied to…

Statistical Mechanics · Physics 2016-03-15 A. G. Godizov , A. A. Godizov

We report universal statistical properties displayed by ensembles of pure states that naturally emerge in quantum many-body systems. Specifically, two classes of state ensembles are considered: those formed by i) the temporal trajectory of…

Noncommutativity of observables is a central feature of quantum physics. It plays a fundamental role in the formulation of the uncertainty principle for complementary variables and strongly affects the laws of thermodynamics for systems…

Quantum Physics · Physics 2025-10-07 Franklin L. S. Rodrigues , Eric Lutz