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Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as…

Quantum Physics · Physics 2016-01-13 James Millen , André Xuereb

The foundations of statistical mechanics, namely how equilibrium hypothesis emerges microscopically from quantum theory, is explored through investigating the environment-induced quantum decoherence processes. Based on the recent results on…

Quantum Physics · Physics 2015-12-04 Heng-Na Xiong , Ping-Yuan Lo , Wei-Min Zhang , Franco Nori , Da Hsuan Feng

Equilibrium statistical mechanics provides powerful tools to understand physics at the macroscale. Yet, the question remains how this can be justified based on a microscopic quantum description. Here, we extend the ideas of pure state…

Quantum Physics · Physics 2023-06-07 Neil Dowling , Pedro Figueroa-Romero , Felix A. Pollock , Philipp Strasberg , Kavan Modi

In the real world, one almost never knows the parameters of a thermodynamic process to infinite precision. Reflecting this, here we investigate how to extend stochastic thermodynamics to systems with uncertain parameters, including…

Statistical Mechanics · Physics 2021-03-17 Jan Korbel , David H. Wolpert

At the core of equilibrium statistical mechanics lies the notion of statistical ensembles: a collection of microstates, each occurring with a given a priori probability that depends only on a few macroscopic parameters such as temperature,…

Statistical Mechanics · Physics 2015-06-19 Dapeng Bi , Silke Henkes , Karen E. Daniels , Bulbul Chakraborty

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

The eigenstate thermalization hypothesis provides a framework for understanding thermalization in isolated quantum many-body systems by characterizing statistical properties of local observables in energy eigenstates. Here we demonstrate…

Statistical Mechanics · Physics 2026-05-11 Pavel Orlov , Rustem Sharipov , Enej Ilievski

The classical and quantum representations of thermal equilibrium are strikingly different, even for free, non-interacting particles. While the first involves particles with well-defined positions and momenta, the second usually involves…

Quantum Physics · Physics 2019-01-03 Aurélia Chenu , Agata M. Brańczyk , John E. Sipe

Heat can flow from cold to hot at any phase separation. Therefore Lynden-Bell's gravo-thermal catastrophe must be reconsidered. The original objects of Thermodynamics, the separation of phases at first order phase transitions, like boiling…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

The two-body potential of systems with long-range interactions decays at large distances as $V(r)\sim 1/r^\alpha$, with $\alpha\leq d$, where $d$ is the space dimension. Examples are: gravitational systems, two-dimensional hydrodynamics,…

Statistical Mechanics · Physics 2009-09-03 A. Campa , T. Dauxois , S. Ruffo

Statistical mechanics reveals that the properties of a macroscopic physical system emerge as an average over an ensemble of statistically independent microscopic subsystems, each occupying a specific microstate. In the study of quantum…

Statistical Mechanics · Physics 2026-03-24 Jacob T. Willson , Henrik J. Heelweg , Adam P. Willard

Understanding thermodynamics and statistical mechanics in the full general relativistic context is an open problem. I give tentative definitions of equilibrium state, mean values, mean geometry, entropy and temperature, which reduce to the…

General Relativity and Quantum Cosmology · Physics 2013-05-01 Carlo Rovelli

For studying the thermodynamic properties of systems using statistical mechanics we propose an ensemble that lies in between the familiar canonical and microcanonical ensembles. From a comparative study of these ensembles we conclude that…

Statistical Mechanics · Physics 2007-05-23 R. P. Venkataraman

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

The problems with an emergent approach to quantum statistical mechanics are discussed and shown to follow from some of the same sources as those of quantum measurement. A wavefunction of an N atom solid is described in the ground and…

Quantum Physics · Physics 2015-02-24 Clifford Chafin

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

There is no compelling reason imposing that the methods of statistical mechanics should be restricted to the dynamical systems which follow the usual Boltzmann-Gibbs prescriptions. More specifically, ubiquitous natural and artificial…

Statistical Mechanics · Physics 2009-11-10 Constantino Tsallis

One of the key objectives in investigating small stochastic systems is the development of micrometer-sized engines and the understanding of their thermodynamics. However, the primary mathematical tool used for this purpose, the overdamped…

Statistical Mechanics · Physics 2025-03-31 Shakul Awasthi , Hyunggyu Park , Jae Sung Lee

The stochastic thermodynamics provides a framework for the description of systems that are out of thermodynamic equilibrium. It is based on the assumption that the elementary constituents are acted by random forces that generate a…

Statistical Mechanics · Physics 2020-06-26 Mário J. de Oliveira

Classical arguments for thermalization of isolated systems do not apply in a straightforward way to the quantum case. Recently, there has been interest in diagnostics of quantum chaos in many- body systems. In the classical case, chaos is a…

Statistical Mechanics · Physics 2019-06-26 Yuri D. Lensky , Xiao-Liang Qi