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We propose a density functional to find the ground state energy and density of interacting particles, where both the density and the pair density can adjust in the presence of an inhomogeneous potential. As a proof of principle we formulate…

Strongly Correlated Electrons · Physics 2015-06-11 J. Lorenzana , Z. -J. Ying , V. Brosco

The central quantity of density functional theory is the so-called exchange-correlation functional. This quantity encompasses all non-trivial many-body effects of the ground-state and has to be approximated in any practical application of…

Materials Science · Physics 2012-06-29 Miguel A. L. Marques , Micael J. T. Oliveira , Tobias Burnus

Finite temperature correlation functions in integrable quantum field theories are formulated only in terms of the usual, temperature-independent form factors, and certain thermodynamic filling fractions which are determined from the…

High Energy Physics - Theory · Physics 2009-10-31 A. Leclair , G. Mussardo

Density Functional Theory (DFT) is one of the most widely used methods for "ab initio" calculations of the structure of atoms, molecules, crystals, surfaces, and their interactions. Unfortunately, the customary introduction to DFT is often…

Physics Education · Physics 2010-12-07 Nathan Argaman , Guy Makov

A new formalism to describe steady-state electronic and thermal transport in the framework of density functional theory is presented. A one-to-one correspondence is proven between the three basic variables of the theory, i.e., the density…

Mesoscale and Nanoscale Physics · Physics 2022-04-26 Nahual Sobrino , Florian Eich , Gianluca Stefanucci , Roberto D'Agosta , Stefan Kurth

We present a finite-temperature extension of the retarded cumulant Green's function for calculations of exited-state and thermodynamic properties of electronic systems. The method incorporates a cumulant to leading order in the screened…

Strongly Correlated Electrons · Physics 2017-11-01 J. J. Kas , J. J. Rehr

It is shown that the DFT exchange and correlation functionals satisfy an expression that couples exchange and correlation functionals and functional derivatives evaluated at three different densities and for two particle numbers. This…

Materials Science · Physics 2015-05-30 Daniel P. Joubert

A quantum field-theoretical model which describes spatially non-homogeneous one-dimensional non-relativistic repulsive Bose gas in an external harmonic potential is considered. We calculate the two-point thermal correlation function of the…

Statistical Mechanics · Physics 2018-09-19 N. M. Bogoliubov , C. Malyshev

We derive a local approximation for the correlation energy in two-dimensional electronic systems. In the derivation we follow the scheme originally developed by Colle and Salvetti for three dimensions, and consider a Gaussian approximation…

Strongly Correlated Electrons · Physics 2008-11-21 S. Pittalis , E. Rasanen , M. Marques

Simulation of warm dense matter requires computational methods that capture both quantum and classical behavior efficiently under high-temperature, high-density conditions. Currently, density functional theory molecular dynamics is used to…

Chemical Physics · Physics 2015-10-21 Attila Cangi , Aurora Pribram-Jones

We demonstrate that ground state energies approaching chemical accuracy can be obtained by combining the adiabatic connection fluctuation-dissipation theorem (ACFDT) with time-dependent density functional theory (TDDFT). The key ingredient…

Materials Science · Physics 2014-05-29 Thomas Olsen , Kristian S. Thygesen

We consider finite temperature dynamical correlation functions in the interacting delta-function Bose gas. In the low-temperature limit the asymptotic behaviour of correlation functions can be determined from conformal field theory. In the…

Statistical Mechanics · Physics 2009-10-31 Fabian H. L. Essler , Vladimir E. Korepin , Franck T. Latremoliere

The exchange-correlation energy in Kohn-Sham density functional theory can be expressed exactly in terms of the change in the expectation of the electron-electron repulsion operator when, in the many-electron hamiltonian, this same operator…

Strongly Correlated Electrons · Physics 2009-08-05 Paola Gori-Giorgi , Giovanni Vignale , Michael Seidl

We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…

Soft Condensed Matter · Physics 2012-03-13 Trond S. Ingebrigtsen , Lasse Bøhling , Thomas B. Schrøder , Jeppe C. Dyre

In this paper the relationship between the density functional theory of freezing and phase field modeling is examined. More specifically a connection is made between the correlation functions that enter density functional theory and the…

Materials Science · Physics 2007-05-23 K. R. Elder , Nikolas Provatas , Joel Berry , Peter Stefanovic , Martin Grant

Using an accurate semi-analytic wavefunction for two electron atoms, we construct the external potential for varying strength of electron-electron (e-e) interaction. Using this potential we explicitly calculate the energy of their positive…

Atomic and Molecular Clusters · Physics 2016-02-18 Rabeet Singh Chauhan , Manoj K. Harbola

We present an accurate local density-functional for electronic-structure calculations within the density functional theory (DFT). The functional is derived by analyzing the structure of the standard perturbative expansion of the correlation…

Materials Science · Physics 2024-11-28 Mario Benites , Angel Rosado , Efstratios Manousakis

Time-dependent density functional theory is extended to include dissipative systems evolving under a master equation, providing a Hamiltonian treatment for molecular electronics. For weak electric fields, the isothermal conductivity is…

Materials Science · Physics 2007-05-23 Kieron Burke , Roberto Car , Ralph Gebauer

A single-term density functional model for nondynamic and strong correlation is presented, based on single-determinant Kohn-Sham density functional theory. It is derived from modeling the adiabatic connection and contains only two nonlinear…

Chemical Physics · Physics 2015-12-21 Jing Kong , Emil Proynov

Another way to evaluate the spectral-correlation properties of thermal fields of solids is suggested. Such a method takes into account detailed structure of the interface transition layer separating one bulk region from those of the vacuum…

Quantum Physics · Physics 2015-06-15 Illarion Dorofeyev