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Related papers: Connection formulas for thermal density functional…

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A previous analysis of scaling, bounds, and inequalities for the non-interacting functionals of thermal density functional theory is extended to the full interacting functionals. The results are obtained from analysis of the related…

Statistical Mechanics · Physics 2016-12-14 James W. Dufty , S. B. Trickey

The correlation energy in density functional theory can be expressed exactly in terms of the change in the probability of finding two electrons at a given distance $r_{12}$ (intracule density) when the electron-electron interaction is…

Other Condensed Matter · Physics 2017-08-23 Paola Gori-Giorgi , Michael Seidl , Andreas Savin

A curious behavior of electron correlation energy is explored. Namely, the correlation energy is the energy that tends to drive the system toward that of the uniform electron gas. As such, the energy assumes its maximum value when a…

Materials Science · Physics 2019-12-17 Teepanis Chachiyo , Hathaithip Chachiyo

Effects of collective modes on thermoelectric properties of a charge density system is studied. We derive the temperature dependence of thermoelectric power and thermal conductivity by applying the linear response theory to Fr\"ohlich…

Other Condensed Matter · Physics 2007-05-23 Hiroyuki Yoshimoto , Susumu Kurihara

We discuss energy densities in the strong-interaction limit of density functional theory, deriving an exact expression within the definition (gauge) of the electrostatic potential of the exchange-correlation hole. Exact results for small…

Chemical Physics · Physics 2012-11-14 André Mirtschink , Michael Seidl , Paola Gori-Giorgi

We consider gapless models of statistical mechanics. At zero temperatures correlation functions decay asymptotically as powers of distance in these models. Temperature correlations decay exponentially. We used an example of solvable model…

High Energy Physics - Theory · Physics 2009-10-30 Vladimir Korepin , Nikita Slavnov

As density functional theory conventionally assumes that the density of a chosen model system (e.g., the Kohn-Sham system) is the same as the exact one, one might expect that approximations to the exact density introduce supplementary…

Chemical Physics · Physics 2009-02-17 A. Savin

The adiabatic connection curve of density functional theory (DFT) is accurately calculated beyond the physical interaction strength for Hooke's atom, two interacting electrons in a harmonic well potential. Extrapolation of the accurate…

Chemical Physics · Physics 2007-05-23 R. J. Magyar , W. Terilla , K. Burke

Over the years, several schemes have been proposed to describe multireference systems with Kohn-Sham Density Functional Theory. Problematic is the combination of two aspects: the Kohn-Sham reference wavefunction is usually taken to be a…

Strongly Correlated Electrons · Physics 2019-08-01 Pablo Ramos , Michele Pavanello

Understanding the properties of warm dense hydrogen is of key importance for the modeling of compact astrophysical objects and to understand and further optimize inertial confinement fusion (ICF) applications. The work horse of warm dense…

We consider the one-dimensional delta-interacting electron gas in the case of infinite repulsion. We use determinant representations to study the long time, large distance asymptotics of correlation functions of local fields in the gas…

Condensed Matter · Physics 2009-10-31 F. Göhmann , A. G. Izergin , V. E. Korepin , A. G. Pronko

In the current density functional theory of linear and nonlinear time-dependent phenomena, the treatment of exchange and correlation beyond the level of the adiabatic local density approximation is shown to lead to the appearance of…

Condensed Matter · Physics 2009-10-30 G. Vignale , C. A. Ullrich , S. Conti

Most present applications of time-dependent density functional theory use adiabatic functionals, i.e. the effective potential at time t is determined solely by the density at the same time. This paper discusses a method that aims to go…

Strongly Correlated Electrons · Physics 2009-11-10 Yair Kurzweil , Roi Baer

We present a graphical analysis of the adiabatic connections underlying double-hybrid density-functional methods that employ second-order perturbation theory. Approximate adiabatic connection formulae relevant to the construction of these…

Chemical Physics · Physics 2013-06-26 Yann Cornaton , Odile Franck , Andrew M. Teale , Emmanuel Fromager

A generalized adiabatic connection for ensembles (GACE) is presented. In contrast to the traditional adiabatic connection formulation, both ensemble weights and interaction strength can vary along a GACE path while the ensemble density is…

Chemical Physics · Physics 2015-06-16 Odile Franck , Emmanuel Fromager

Density functional theory has made great success in solid state physics, quantum chemistry and in computational material sciences. In this work we show that density functional theory could shed light on phase transitions and entanglement at…

Statistical Mechanics · Physics 2017-08-11 Bo-Bo Wei

The capability of density-functional theory to deal with the ground-state of strongly correlated low-dimensional systems, such as semiconductor quantum dots, depends on the accuracy of functionals developed for the exchange and correlation…

Strongly Correlated Electrons · Physics 2009-02-25 S. Pittalis , E. Rasanen , C. Proetto , E. K. U. Gross

Correlated systems at both zero and nonzero temperature are treated here from a novel angle using a functional method. This functional method is an extension of the usual effective potential method. Here, however the effective action is…

Condensed Matter · Physics 2007-05-23 A. Rebei , W. N. G. Hitchon

Finite temperature density functional theory provides, in principle, an exact description of the thermodynamical equilibrium of many-electron systems. In practical applications, however, the functionals must be approximated. Efficient and…

Statistical Mechanics · Physics 2015-05-19 S. Pittalis , C. R. Proetto , A. Floris , A. Sanna , C. Bersier , K. Burke , E. K. U. Gross

We investigate the construction of approximated exchange-correlation functionals by interpolating locally along the adiabatic connection between the weak- and the strong-coupling regimes, focussing on the effect of using approximate…

Chemical Physics · Physics 2017-04-05 Stefan Vuckovic , Lucas O. Wagner , Andrew M. Teale , Paola Gori-Giorgi