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We propose a numerical method using the discrete variable representation (DVR) for constructing real-valued Wannier functions localized in a unit cell for both symmetric and asymmetric periodic potentials. We apply these results to finding…

Quantum Gases · Physics 2016-09-14 Saurabh Paul , Eite Tiesinga

We introduce a maximally-localized Wannier function representation of Bloch excitons, two-particle correlated electron-hole excitations, in crystalline solids, where the excitons are maximally-localized with respect to an average…

Materials Science · Physics 2023-08-08 Jonah B. Haber , Diana Y. Qiu , Felipe H. da Jornada , Jeffrey B. Neaton

Bands with non-trivial topological indices have a topological obstruction preventing them from being represented by exponentially localized Wannier states. Here, we propose a procedure to construct exponentially localized Wannier functions…

Mesoscale and Nanoscale Physics · Physics 2025-05-29 Trey Cole , David Vanderbilt

We propose a method for calculating Wannier functions of periodic solids directly from a modified variational principle for the energy, subject to the requirement that the Wannier functions are orthogonal to all their translations…

Materials Science · Physics 2014-03-28 Farzin Barekat , Ke Yin , Russel E. Caflisch , Stanley J. Osher , Rongjie Lai , Vidvuds Ozolins

When using Wannier functions to study the electronic structure of multi-parameter Hamiltonians $H^{(\boldsymbol k,\bf \lambda)}$ carrying a dependence on crystal momentum $\boldsymbol k$ and an additional periodic parameter $\bf\lambda$,…

Materials Science · Physics 2015-06-11 Jan-Philipp Hanke , Frank Freimuth , Stefan Blügel , Yuriy Mokrousov

We describe and implement a first-principles algorithm based on maximally-localized Wannier functions for calculating the shift-current response of piezoelectric crystals in the independent-particle approximation. The proposed algorithm…

Materials Science · Physics 2018-06-29 Julen Ibañez-Azpiroz , Stepan S. Tsirkin , Ivo Souza

We consider a periodic Schroedinger operator and the composite Wannier functions corresponding to a relevant family of its Bloch bands, separated by a gap from the rest of the spectrum. We study the associated localization functional…

Mathematical Physics · Physics 2013-09-26 Gianluca Panati , Adriano Pisante

The ionization potential of molecular chains is well-known to be a tunable nano-scale property that exhibits clear quantum confinement effects. State-of-the-art methods can accurately predict the ionization potential in the small molecule…

Chemical Physics · Physics 2024-03-28 Guy Ohad , Michal Hartstein , Tim Gould , Jeffrey B. Neaton , Leeor Kronik

We extend the Intrinsic Atomic Orbital (IAO) method for localisation of molecular orbitals to calculate well-localised generalised Wannier functions in crystals using the Pipek--Mezey locality metric. We furthermore present a one-shot…

Materials Science · Physics 2024-07-02 Andrew Zhu , David P. Tew

We present an ab initio inelastic quantum transport approach based on maximally localized Wannier functions. Electronic-structure properties are calculated with density-functional theory in a planewave basis, and electron-vibration coupling…

Mesoscale and Nanoscale Physics · Physics 2013-06-12 Sejoong Kim , Nicola Marzari

Functionals that strive to correct for such self-interaction errors, such as those obtained by imposing the Perdew-Zunger self-interaction correction or the generalized Koopmans' condition, become orbital dependent or orbital-density…

Materials Science · Physics 2011-08-30 Cheol-Hwan Park , Andrea Ferretti , Ismaila Dabo , Nicolas Poilvert , Nicola Marzari

We provide a mathematically proven, simple and efficient algorithm to build localised Wannier functions, with the only requirement that the system has vanishing Chern numbers. Our algorithm is able to build localised Wannier for topological…

Mathematical Physics · Physics 2019-03-27 David Gontier , Antoine Levitt , Sami Siraj-Dine

The projection of the eigenfunctions obtained in standard plane-wave first-principle electronic-structure calculations into atomic-orbital basis sets is proposed as a formal and practical link between the methods based on plane waves and…

Condensed Matter · Physics 2009-10-28 Daniel Sanchez-Portal , Emilio Artacho , Jose M. Soler

Wannier functions have widespread utility in condensed matter physics and beyond. Topological physics, on the other hand, has largely involved the related notion of compactly-supported Wannier-type functions, which arise naturally in flat…

Mesoscale and Nanoscale Physics · Physics 2025-05-21 Pratik Sathe , Rahul Roy

The existence and construction of exponentially localised Wannier functions for insulators is a well-studied problem. In comparison, the case of metallic systems has been much less explored, even though localised Wannier functions…

Mathematical Physics · Physics 2019-02-04 Horia Cornean , David Gontier , Antoine Levitt , Domenico Monaco

This paper proposes a novel localized Fourier extension method for approximating non-periodic functions via domain segmentation. By partitioning the computational domain into subregions with uniform discretization scales, the method…

Numerical Analysis · Mathematics 2025-08-29 Zhenyu Zhao , Yanfei Wang

We present a theoretical method for calculating optical absorption spectra based on maximally localized Wannier functions, which is suitable for large periodic systems. For this purpose, we calculate the exciton Hamiltonian, which…

Mesoscale and Nanoscale Physics · Physics 2023-09-14 Konrad Merkel , Frank Ortmann

We present an efficient approach to precisely simulate tight binding models with optical lattices, based on programmable digital-micromirror-device (DMD) techniques. Our approach consists of a subroutine of Wegner-flow enabled precise…

Quantum Gases · Physics 2020-10-20 Xingze Qiu , Jie Zou , Xiaodong Qi , Xiaopeng Li

Memory function formalism or projection operator technique is an extremely useful method to study the transport and optical properties of various condensed matter systems. A recent revival of its uses in various correlated electronic…

Strongly Correlated Electrons · Physics 2016-09-22 Nabyendu Das , Pankaj Bhalla , Navinder Singh

Wannier90 is an open-source computer program for calculating maximally-localised Wannier functions (MLWFs) from a set of Bloch states. It is interfaced to many widely used electronic-structure codes thanks to its independence from the basis…

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