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The electronic structure of solids can routinely be calculated by standard methods like density functional theory. However, in complicated situations like interfaces, grain boundaries or contact geometries one needs to resort to more…

Materials Science · Physics 2025-11-18 Henrik Dick , Thomas Dahm

We introduce a new type of Wannier functions (WFs) obtained by minimizing the conventional spread functional with a penalty term proportional to the variance of the spread distribution. This modified Wannierisation scheme is less prone to…

Other Condensed Matter · Physics 2021-11-09 Pietro F. Fontana , Ask H. Larsen , Thomas Olsen , Kristian S. Thygesen

A standard task in solid state physics and quantum chemistry is the computation of localized molecular orbitals known as Wannier functions. In this manuscript, we propose a new procedure for computing Wannier functions in one-dimensional…

Mathematical Physics · Physics 2025-10-21 Abinand Gopal , Hanwen Zhang

We discuss a method for determining the optimally-localized set of generalized Wannier functions associated with a set of Bloch bands in a crystalline solid. By ``generalized Wannier functions'' we mean a set of localized orthonormal…

Materials Science · Physics 2009-10-30 Nicola Marzari , David Vanderbilt

A non-iterative method is presented to calculate the closest Wannier functions (CWFs) to a given set of localized guiding functions, such as atomic orbitals, hybrid atomic orbitals, and molecular orbitals, based on minimization of a…

Materials Science · Physics 2023-07-03 Taisuke Ozaki

In insulators, the method of Marzari and Vanderbilt [Phys. Rev. B {\bf 56}, 12847 (1997)] can be used to generate maximally localized Wannier functions whose centers are related to the electronic polarization. In the case of layered…

Materials Science · Physics 2009-12-17 Xifan Wu , Oswaldo Diéguez , Karin M. Rabe , David Vanderbilt

We investigate the interplay of band structure topology and localization properties of Wannier functions. To this end, we extend a recently proposed compressed sensing based paradigm for the search for maximally localized Wannier functions…

Mesoscale and Nanoscale Physics · Physics 2014-09-12 J. C. Budich , J. Eisert , E. J. Bergholtz , S. Diehl , P. Zoller

The construction of optimally localized Wannier functions (and Wannier functions in general) for a Chern insulator has been considered to be impossible owing to the fact that the second moment of such functions is generally infinite. In…

Materials Science · Physics 2024-04-12 Thivan M. Gunawardana , Ari M. Turner , Ryan Barnett

We discuss a maximally localized Wannier function approach for constructing lattice models from first-principles electronic structure calculations, where the effective Coulomb interactions are calculated in the constrained…

Strongly Correlated Electrons · Physics 2009-11-13 Takashi Miyake , F. Aryasetiawan

Wannier function expansions are well suited for the description of photonic- crystal-based defect structures, but constructing maximally localized Wannier functions by optimizing the phase degree of freedom of the Bloch modes is crucial for…

Optics · Physics 2015-05-27 Tobias Stollenwerk , Dmitry N. Chigrin , Johann Kroha

It is proved that for general, not necessarily periodic quasi one dimensional systems, the band position operator corresponding to an isolated part of the energy spectrum has discrete spectrum and its eigenfunctions have the same spatial…

Other Condensed Matter · Physics 2008-03-11 H. D. Cornean , A. Nenciu , G. Nenciu

Localized bases play an important role in understanding electronic structure. In periodic insulators, a natural choice of localized basis is given by the Wannier functions which depend a choice of unitary transform known as a gauge…

Mathematical Physics · Physics 2021-02-24 Kevin D. Stubbs , Alexander B. Watson , Jianfeng Lu

Over the last two decades, following the early developments on maximally localized Wannier functions, an ecosystem of electronic-structure simulation techniques and software packages leveraging the Wannier representation has flourished.…

We present an alternative formalism for calculating the maximally localized Wannier functions in crystalline solids, obtaining an expression which is extremely simple and general. In particular, our scheme is exactly invariant under…

Materials Science · Physics 2011-03-03 Massimiliano Stengel , Nicola A. Spaldin

Wannier functions provide a localized representation of spectral subspaces of periodic Hamiltonians, and play an important role for interpreting and accelerating Hartree-Fock and Kohn-Sham density functional theory calculations in quantum…

Computational Physics · Physics 2018-01-29 Anil Damle , Antoine Levitt , Lin Lin

We present a semi-automated method for obtaining an initial estimate of Wannier functions, designed to facilitate the construction of Wannier functions for describing low-energy effective models of solids, particularly those relevant to…

Strongly Correlated Electrons · Physics 2025-12-24 Tatsuki Oikawa , Kota Ido , Takahiro Misawa , Takashi Koretsune , Kazuyoshi Yoshimi

We have developed a practical scheme to construct partly occupied, maximally localized Wannier functions (WFs) for a wide range of systems. We explain and demonstrate how the inclusion of selected unoccupied states in the definition of the…

Materials Science · Physics 2009-11-11 K. S. Thygesen , L. B. Hansen , K. W. Jacobsen

We propose a general method of constructing Wannier functions in disordered systems directly out of energy eigenstates. This method consists of two successive operations: (i) a phase transformation setting the proper localization center;…

Disordered Systems and Neural Networks · Physics 2015-12-24 Junbo Zhu , Zhu Chen , Biao Wu

Time-dependent Wannier functions were initially proposed as a means for calculating the polarization current in crystals driven by external fields. In this work, we present a simple gauge where Wannier states are defined based on the…

Materials Science · Physics 2024-10-29 Cristian M. Le , Hannes Hübener , Ofer Neufeld , Angel Rubio

We present a new scheme for the construction of highly localized lattice Wannier functions. The approach is based on a heuristic criterion for localization and takes the symmetry constraints into account from the start. We compare the local…

Materials Science · Physics 2009-10-31 Jorge Iniguez , Alberto Garcia , J. M. Perez-Mato