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The 5$\textit{d}$ transition-metal oxides provide an intriguing platform for generating an efficient spin current due to a unique electronic structure dominated by 5d electrons with strong spin-orbit coupling. Here, we report on the effect…

Materials Science · Physics 2025-06-02 Tetsuro Morimoto , Kohei Ueda , Junichi Shiogai , Takanori Kida , Masayuki Hagiwara , Jobu Matsuno

The spin-orbit coupling (SOC) interactions, electron correlation effects and Hund coupling cooperate and compete with each other, leading to novel properties, quantum phase and non-trivial topological electronic behavior in iridium oxides.…

Strongly Correlated Electrons · Physics 2018-12-19 Xing Ming , Xiangang Wan , Carmine Autieri , Jianfeng Wen , Xiaojun Zheng

We have carried out a detailed first-principles study of a d$^{4.5}$ quaternary iridate Ba$_3$YIr$_2$O$_9$ both in its 6H-perovskite-type ambient pressure (AP) phase and also for the high pressure (HP) cubic phase. Our analysis reveals that…

Strongly Correlated Electrons · Physics 2015-11-11 S. K. Panda , S. Bhowal , Ying Li , S. Ganguly , Roser Valentí , L. L. Nordström , I. Dasgupta

Magnetic materials with strong spin-orbit coupling (SOC) are essential for the advancement of spin-orbitronic devices, as they enable efficient spin-charge conversion, complex magnetic structures, spin-valley physics, topological phases and…

Spin-orbit coupling (SOC) is pivotal for various fundamental spin-dependent phenomena in solids and their technological applications. In semiconductors, these phenomena have been so far studied in relatively weak electron-electron…

Mesoscale and Nanoscale Physics · Physics 2021-06-09 D. Maryenko , M. Kawamura , A. Ernst , V. K. Dugaev , E. Ya. Sherman , M. Kriener , M. S. Bahramy , Y. Kozuka , M. Kawasaki

Spin-orbit effects in heavy 5$d$ transition metal oxides, in particular, iridates, have received enormous current interest due to the prediction as well as the realization of a plethora of exotic and unconventional magnetic properties.…

Strongly Correlated Electrons · Physics 2021-09-22 Sayantika Bhowal , Indra Dasgupta

Complex oxides with $4d$ and $5d$ transition-metal ions recently emerged as a new paradigm in correlated electron physics, due to the interplay between spin-orbit coupling and electron interactions. For $4d$ and $5d$ ions, the spin-orbit…

Strongly Correlated Electrons · Physics 2021-05-19 Tomohiro Takayama , Jiri Chaloupka , Andrew Smerald , Giniyat Khaliullin , Hidenori Takagi

The metal-insulator and spin state transitions of CoO under high pressure are studied by using density functional theory combined with dynamical mean-field theory. Our calculations predict that the metal-insulator transition in CoO is a…

Strongly Correlated Electrons · Physics 2014-12-04 Li Huang , Yilin Wang , Xi Dai

We investigated the electronic and magnetic properties of the pyrochlore oxide Cd$_2$Os$_2$O$_7$ using the density-functional theory plus on-site repulsion ($U$) method, and depict the ground-state phase diagram with respect to $U$. We…

Strongly Correlated Electrons · Physics 2012-06-15 Hiroshi Shinaoka , Takashi Miyake , Shoji Ishibashi

Spin-orbit coupling (SOC), the core of numerous condensed-matter phenomena such as nontrivial band gap, magnetocrystalline anisotropy, etc, is generally considered to be appreciable only in heavy elements, detrimental to the synthetization…

Materials Science · Physics 2022-02-21 Jiayu Li , Qiushi Yao , Lin Wu , Zongxiang Hu , Boya Gao , Xiangang Wan , Qihang Liu

Strong spin-orbit coupling (SOC) effects of heavy $d$-orbital elements have long been neglected in describing the ground states of their compounds thereby overlooking a variety of fascinating and yet unexplored magnetic and electronic…

Evolution of composite spin-orbital order and coupled spin-orbital excitations is studied in a variety of $d^4$ systems with $n$=$4$ electrons in the $t_{2g}$ orbital sector using the generalised self-consistent + fluctuations approach for…

Strongly Correlated Electrons · Physics 2025-04-30 Shahid Ahmad , Harshvardhan Parmar , Shubhajyoti Mohapatra , Avinash Singh

We investigated the electronic structures of the 5$d$ Ruddlesden-Popper series Sr$_{n+1}$Ir$_{n}$O$_{3n+1}$ ($n$=1, 2, and $\infty$) using optical spectroscopy and first-principles calculations. As 5$d$ orbitals are spatially more extended…

Strongly Correlated Electrons · Physics 2009-11-13 S. J. Moon , H. Jin , K. W. Kim , W. S. Choi , Y. S. Lee , J. Yu , G. Cao , A. Sumi , H. Funakubo , C. Bernhard , T. W. Noh

The layered 5d transition metal oxides like Sr2IrO4 have attracted significant interest recently due to a number of exotic and new phenomena induced by the interplay between the spin-orbit coupling, bandwidth W and on-site Coulomb…

Using ab initio calculations, we have investigated an insulating tetragonally distorted perovskite BaCrO$_3$ with a formal $3d^2$ configuration, the volume of which is apparently substantially enhanced by a strain due to SrTiO$_3$…

Strongly Correlated Electrons · Physics 2014-11-24 Hyo-Sun Jin , Kyo-Hoon Ahn , Myung-Chul Jung , K. -W. Lee

5d transition metal oxides offer new opportunities to test our understanding of the interplay of correlation effects and spin-orbit interactions in materials in the absence of a single dominant interaction. The subtle balance between…

Understanding the interplay of strong correlation and temperature in nodal-line semimetals can offer novel ways to control spin currents. Here we consider the 3d-5d double-perovskite Ba$_{2}$CoWO$_{6}$, which features…

Strongly Correlated Electrons · Physics 2024-08-29 Jyotirmoy Sau , Sourav Chakraborty , Sourabh Saha , Kalpataru Pradhan , Anamitra Mukherjee , Manoranjan Kumar

The insulating ground state of the 5d transition metal oxide CaIrO3 has been classified as a Mott-type insulator. Based on a systematic density functional theory (DFT) study with local, semilocal, and hybrid exchange-correlation…

Strongly Correlated Electrons · Physics 2015-09-04 Sun-Woo Kim , Chen Liu , Hyun-Jung Kim , Jun-Ho Lee , Yongxin Yao , Kai-Ming Ho , Jun-Hyung Cho

Transition metal oxides, in particular, 3d or 4d perovskites have provided diverse emergent physics that originates from the coupling of various degrees of freedom such as spin, lattice, charge, orbital, and also disorder. 5d perovskites…

Strongly Correlated Electrons · Physics 2016-04-19 Abhijit Biswas , Ki-Seok Kim , Yoon Hee Jeong

We address the concomitant metal-insulator transition (MIT) and antiferromagnetic ordering in the novel pyrochlore iridate Eu2Ir2O7 by combining x-ray absorption spectroscopy, x-ray and neutron diffractions and density functional theory…