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By employing monomer-resolved computer simulations and analytical considerations based on polymer scaling theory, we analyze the conformations and interactions of multiarm star polymers strongly adsorbed on a smooth, two-dimensional plane.…

Soft Condensed Matter · Physics 2015-06-15 S. A. Egorov , J. Paturej , C. N. Likos , A. Milchev

The detachment of a semi-ordered monolayer of polystyrene microspheres adhered to an aluminum-coated glass substrate is studied using a laser-induced spallation technique. The microsphere-substrate adhesion force is estimated from substrate…

Mesoscale and Nanoscale Physics · Physics 2016-03-22 Morgan Hiraiwa , Melicent Stossel , Amey Khanolkar , Junlan Wang , Nicholas Boechler

We investigate the adsorption of a flexible polymer at a hexagonally patterned monolayer. All conformational polymer phases are identified, which enables the construction of a hyperphase diagram, parameterized by temperature and monolayer…

Soft Condensed Matter · Physics 2019-12-03 Benjamin Liewehr , Michael Bachmann

Adsorption of dimers is modelled using random sequential adsorption algorithm. The interaction between molecules is given by screened electrostatic potential. The paper focuses on the properties of adsorbed monolayers as well as the…

Materials Science · Physics 2013-05-14 Michal Ciesla , Jakub Barbasz

Nanomechanical resonators offer important benefits for the sensing of physical stimuli such as the mass of an added molecule. To map out the local shape properties of the physical stimuli, such as the distribution of the mass density of a…

Applied Physics · Physics 2017-09-06 Mert Yüksel , M. Selim Hanay

The recently developed two-stage growth model of synthesis of monodispersed polycrystalline colloidal particles is utilized and improved to explain growth of uniform cadmium sulfide spheres. The model accounts for the coupled processes of…

Soft Condensed Matter · Physics 2010-09-22 Sergiy Libert , Vyacheslav Gorshkov , Dan Goia , Egon Matijevic , Vladimir Privman

Colloidal particles with mobile binding molecules constitute a powerful platform for probing the physics of self-assembly. Binding molecules are free to diffuse and rearrange on the surface, giving rise to spontaneous control over the…

Soft Condensed Matter · Physics 2023-05-29 Gaurav Mitra , Chuan Chang , Angus McMullen , Daniela Puchall , Jasna Brujic , Glen M. Hocky

Light-activated colloidal assembly and swarming can act as model systems to explore non-equilibrium state of matter. In this context, creating new experimental platforms to facilitate and control two-dimensional assembly of colloidal…

Control of physical behaviors of nematic colloids and colloidal crystals has been demonstrated by tuning particle shape, topology, chirality and surface charging. However, the capability of altering physical behaviors of such soft matter…

Soft Condensed Matter · Physics 2021-01-12 Ye Yuan , Patrick Keller , Ivan I. Smalyukh

The surface tension, the adsorption, and the depletion thickness of polymers close to a single nonadsorbing colloidal sphere are computed by means of Monte Carlo simulations. We consider polymers under good-solvent conditions and in the…

Soft Condensed Matter · Physics 2014-05-06 Giuseppe D'Adamo , Andrea Pelissetto , Carlo Pierleoni

The spontaneous assembly of particles in suspension provides a strategy for inexpensive fabrication of devices with nanometer-scale control, such as single-electron transistors for memory or logic applications. A scaleable and robust method…

Soft Condensed Matter · Physics 2007-05-23 C. R. Knutson , K. D. McCarthy , R. Shenhar , V. M. Rotello , T. Emrick , T. P. Russell , M. T. Tuominen , A. D. Dinsmore

Micrometre sized colloidal particles can be viewed as large atoms with tailorable size, shape and interactions. These building blocks can assemble into extremely rich structures and phases, in which the thermal motions of particles can be…

Soft Condensed Matter · Physics 2017-11-10 Bo Li , Di Zhou , Yilong Han

We report adaptive resolution molecular dynamics simulations of a flexible linear polymer in solution. The solvent, i.e., a liquid of tetrahedral molecules, is represented within a certain radius from the polymer's center of mass with a…

Soft Condensed Matter · Physics 2007-05-23 Matej Praprotnik , Luigi Delle Site , Kurt Kremer

We study the adsorption of semiflexible polymers such as polyelectrolytes or DNA on planar and curved substrates, e.g., spheres or washboard substrates via short-range potentials using extensive Monte-Carlo simulations, scaling arguments,…

Soft Condensed Matter · Physics 2015-08-19 Tobias A. Kampmann , Horst-Holger Boltz , Jan Kierfeld

Microgels are colloidal-scale particles individually made of crosslinked polymer networks that can swell and deswell in response to external stimuli, such as changes to temperature or pH. Despite a large amount of experimental activities on…

Soft Condensed Matter · Physics 2019-02-08 Nicoletta Gnan , Lorenzo Rovigatti , Maxime Bergman , Emanuela Zaccarelli

When a gel absorbs solvent from surrounding, stress field is created in the gel, and this causes complex dynamics of the swelling behavior. Here we study this effect for disk-shaped gel by rigorously solving the diffusio-mechanical coupling…

Soft Condensed Matter · Physics 2021-05-17 Xingkun Man , Masao Doi

Molecular dynamics simulations are used to study the spreading of binary polymer nanodroplets in a cylindrical geometry. The polymers, described by the bead-spring model, spread on a flat surface with a surface-coupled Langevin thermostat…

Soft Condensed Matter · Physics 2007-05-23 David R. Heine , Gary S. Grest , Edmund B. Webb

The rotational diffusive motion of a self-propelled, attractive spherical colloid immersed in a solution of self-avoiding polymers is studied by mesoscale hydrodynamic simulations. A drastic enhancement of the rotational diffusion by more…

Soft Condensed Matter · Physics 2020-03-09 Kai Qi , Elmar Westphal , Gerhard Gompper , Roland G. Winkler

Swelling is a volumetric-growth process in which a porous material expands by spontaneous imbibition of additional pore fluid. Swelling is distinct from other growth processes in that it is inherently poromechanical: Local expansion of the…

Soft Condensed Matter · Physics 2025-05-13 Thibault Bertrand , Jorge Peixinho , Shomeek Mukhopadhyay , Christopher W. MacMinn

Colloidal molecules are ideal model systems for mimicking real molecules and can serve as versatile building blocks for the bottom-up self-assembly of flexible and smart materials. While most colloidal molecules are rigid objects, the…