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We investigate interactions between the proton spin, the deuteron spin, and the orbital angular momentum in the electronic ground state of the HD molecule. These interactions lead to hyperfine splittings of molecular energy levels. Our…

Chemical Physics · Physics 2020-07-29 Jacek Komasa , Mariusz Puchalski , Krzysztof Pachucki

We report the production of ultracold heteronuclear Cs$^*$Yb molecules through one-photon photoassociation applied to an ultracold atomic mixture of Cs and Yb confined in an optical dipole trap. We use trap-loss spectroscopy to detect…

We have systematically investigated the ground-state hyperfine structure for alkali-metal atoms ^{87}Rb, ^{133}Cs, ^{211}Fr and alkali-metal-like ions ^{135}Ba^+, ^{225}Ra^+, which are of particular interest for parity violation studies.…

Atomic Physics · Physics 2017-12-20 J. S. M. Ginges , A. V. Volotka , S. Fritzsche

Using an ultracold gas of $^{87}$Rb$^{133}$Cs molecules, we perform hyperfine-resolved spectroscopy of transitions from the vibronic ground state to the lowest rovibrational states of the electronic state $\mathrm{b}\,^3\Pi_0$, as a…

A version of the configuration interaction method, which has been recently developed to deal with large number of valence electrons, has been used to calculate magnetic dipole and electric quadrupole hyperfine structure constants for a…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

We present a detailed formalism of the microscopic particle-rotor model for hypernuclear low-lying states based on a covariant density functional theory. In this method, the hypernuclear states are constructed by coupling a hyperon to…

Nuclear Theory · Physics 2015-04-21 H. Mei , K. Hagino , J. M. Yao , T. Motoba

The electronic structure of the ICl+ molecular ion is investigated by using high-level multireference configuration interaction (MRCI) method. To improve computational accuracy, Davidson corrections, spin-orbit coupling (SOC), and…

Atomic Physics · Physics 2025-11-25 Rui Li , Ronglong Dou , Ting Gao , Qinan Li , Chaoqun Song

Calculations of the magnetic hyperfine structure rely on the input of nuclear properties -- nuclear magnetic moments and nuclear magnetization distributions -- as well as quantum electrodynamic (QED) radiative corrections for high-accuracy…

Atomic Physics · Physics 2018-09-19 J. S. M. Ginges , A. V. Volotka

Variational quantum algorithms on bosonic quantum processors are an emerging paradigm for quantum chemistry calculations, exploiting the natural alignment between molecular structure and harmonic oscillator-based hardware. We introduce the…

Quantum Physics · Physics 2026-04-21 Marlon F. Jost , Sijia S. Dong

A relativistic wave equation for bound states of two fermions with arbitrary masses which are exposed to a magnetic field is derived from quantum electrodynamics. The interaction kernels are based upon the generalized invariant M-matrices…

High Energy Physics - Phenomenology · Physics 2007-05-23 Andrei G. Terekidi , Jurij W. Darewych , Marko Horbatsch

High resolution angle-resolved photoemission spectroscopy data along the (0,0)-($\pi$,$\pi$) nodal direction with significantly improved statistics reveal fine structure in the electron self-energy of the underdoped…

We have measured hyperfine structure in the first-excited $P$ state ($D$ lines) of all the naturally-occurring alkali atoms. We use high-resolution laser spectroscopy to resolve hyperfine transitions, and measure intervals by locking the…

Atomic Physics · Physics 2010-08-20 Dipankar Das , Vasant Natarajan

Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and…

Chemical Physics · Physics 2016-11-01 V. Laporta , J. Tennyson , R. Celiberto

The observation of the exotic quarkonium state Z_c(3900) by the BESIII and Belle collaborations supports the concept of hadronic molecules. Charmonium states interpreted as such molecules would be bound states of heavy particles with small…

High Energy Physics - Phenomenology · Physics 2014-01-20 E. Wilbring , H. -W. Hammer , U. -G. Meißner

Measuring the hyperfine structure (HFS) of long-lived $^3P_2$ states of divalent atoms may offer the opportunity of extracting relatively unexplored nuclear magnetic octupole and electric hexadecapole moments. Here, using relativistic…

Atomic Physics · Physics 2009-11-13 K. Beloy , A. Derevianko , W. R. Johnson

The multi-configuration Dirac-Hartree-Fock method was employed to calculate the total and excitation energies, oscillator strengths and hyperfine structure constants for low-lying levels of Sm I. In the first-order perturbation…

Atomic Physics · Physics 2015-09-16 Fuyang Zhou , Yizhi Qu , Jiguang Li , Jianguo Wang

The hyperfine structures of the $2\,^3\!S_1$ and $2\,^3\!P_J$ states of the $^7$Be$^{2+}$ and $^9$Be$^{2+}$ ions are investigated within the framework of the nonrelativistic quantum electrodynamics (NRQED). The uncertainties of present…

We demonstrate the importance of electron correlation effects in the hyperfine structure constants of many low-lying states in $^{210}$Fr and $^{212}$Fr. This is achieved by calculating the magnetic dipole and electric quadrupole hyperfine…

Atomic Physics · Physics 2015-05-20 B. K. Sahoo , D. K. Nandy , B. P. Das , Y. Sakemi

Long-range bound states of the excited heteronuclear 3He*--4He* system that dissociate to either 3He(1s2s 3S_1) + 4He(1s2p 3P_j) or 3He(1s2p 3P_j) + 4He(1s2s 3S_1), where j=0, 1, 2, are investigated using both single-channel and…

Atomic and Molecular Clusters · Physics 2015-05-04 Daniel G. Cocks , Gillian Peach , Ian B. Whittingham

Molecular spin qubits with long spin coherence time as well as non-invasive operation methods on such qubits are in high demand. It was shown that both molecular electronic and nuclear spin levels can be used as qubits. In solid state…

Materials Science · Physics 2020-10-28 Robert L. Smith , Aleksander L. Wysocki , Kyungwha Park