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We measure electronic conductance through single conjugated molecules bonded to Au metal electrodes with direct Au-C covalent bonds using the scanning tunneling microscope based break-junction technique. We start with molecules terminated…

Electron transport properties of C$_{20}$ molecules suspended between gold electrodes are investigated using first-principles calculations. Our study reveals that the conductances are quite sensitive to the number of C$_{20}$ molecules…

Condensed Matter · Physics 2009-11-10 Megumi Otani , Tomoya Ono , Kikuji Hirose

We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Latha Venkataraman , Young S. Park , Adam C. Whalley Colin Nuckolls , Mark S. Hybertsen , Michael L. Steigerwald

We report transport measurements through a single-molecule magnet, the Mn12 derivative [Mn12O12(O2C-C6H4-SAc)16(H2O)4], in a single-molecule transistor geometry. Thiol groups connect the molecule to gold electrodes that are fabricated by…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 H. B. Heersche , Z. de Groot , J. A. Folk , H. S. J. van der Zant , C. Romeike , M. R. Wegewijs , L. Zobbi , D. Barreca , E. Tondello , A. Cornia

Three terminal single-electron transistor devices utilizing Al/Al2O3 gate electrodes were developed for the study of electron transport through individual single-molecule magnets. The devices were patterned via multiple layers of optical…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 J. J. Henderson , C. M. Ramsey , E. del Barco , A. Mishra , G. Christou

We present a theoretical study of the conductance of atomic junctions comprising single noble gas atoms (He, Ne, Ar, Kr, and Xe) coupled to gold electrodes. The aim is to elucidate how the presence of noble gas atoms affects the electronic…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 L. A. Zotti , M. Bürkle , Y. J. Dappe , F. Pauly , J. C. Cuevas

A comprehensive review is presented of single molecule junction conductance measurements across families of molecules measured while breaking a gold point contact in a solution of molecules with amine end groups. A theoretical framework…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Mark S. Hybertsen , Latha Venkataraman , Jennifer E. Klare , Adam C. Whalley , Michael L. Steigerwald , Colin Nuckolls

In a semiclassical view superconductivity is attributed exclusively to the advance of atoms' outer s electrons through the nuclei of neighbor atoms in a solid. The necessary progression of holes in the opposite direction has the electric…

General Physics · Physics 2013-03-12 Manfred Bucher

We report low temperature transport measurements on suspended single walled carbon nanotubes (both individual tubes and ropes). The technique we have developed, where tubes are soldered on low resistive metallic contacts across a slit,…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. Kasumov , M. Kociak , M. Ferrier , R. Deblock , S. Gueron , B. Reulet , I. Khodos , O. Stephan , H. Bouchiat

We demonstrate superconducting vertical interconnect access (VIA) contacts to a monolayer of molybdenum disulfide (MoS$_2$), a layered semiconductor with highly relevant electronic and optical properties. As a contact material we use MoRe,…

Mesoscale and Nanoscale Physics · Physics 2021-08-04 M. Ramezani , I. Correa Sampaio , K. Watanabe , T. Taniguchi , C. Schönenberger , A. Baumgartner

The effect on molecular transport due to chemical modification of the metal-molecule interface is investigated, using as an example the prototypical molecular device formed by attaching a p-disubstituted benzene molecule onto two gold…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

Layered ternary transition-metal chalcogenides have been focused as a vein of exploration for superconductors. In this study, TiGeTe$_{6}$ single crystals were synthesized and characterized by structural and valence state analyses and…

Although it was demonstrated that discrete molecular levels determine the sign and magnitude of the thermoelectric effect in single-molecule junctions, full electrostatic control of these levels has not been achieved to date. Here, we show…

The solid-state structures of organic charge transfer (CT) salts are critical in determining their mode of charge transport, and hence their unusual electrical properties, which range from semiconducting through metallic to superconducting.…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 Andrea Vezzoli , Iain Grace , Carly Brooke , Kun Wang , Colin J. Lambert , Bingqian Xu , Richard J. Nichols , Simon J. Higgins

The binary polyhydrides of heavy rare earth lutetium that shares a similar valence electron configuration to lanthanum have been experimentally discovered to be superconductive. The lutetium polyhydrides were successfully synthesized at…

Non-equilibrium Green's functions (NEGF) formalism combined with extended Huckel (EHT) and charging model are used to study electrical conduction through single-molecule junctions. Analyzed molecular complex is composed of asymmetric…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Kamil Walczak , Sergey Edward Lyshevski

We report on syntheses and electron transport properties of polycrystalline samples of diborides (AB2) with different transition metals atoms (A=Zr,Nb,Ta). The temperature dependence of resistivity, \rho(T), and ac susceptibility of these…

Materials Science · Physics 2009-11-07 Vitaly A. Gasparov , N. S. Sidorov , I. I. Zver'kova , M. P. Kulakov

Despite its fundamental importance for nano physics and chemistry and potential device applications, the relationship between atomic structure and electronic transport in molecular nanostructures is not well understood. Thus the…

Mesoscale and Nanoscale Physics · Physics 2014-02-04 Alireza Saffarzadeh , Firuz Demir , George Kirczenow

The discovery of new high-temperature superconductors is one of the most critical problems in materials, chemistry, and physics. This work systematically investigates fluorite-like structures of XBeH8 (X is Ac, Th, Pa, U, and Np) to gain…

Superconductivity · Physics 2022-09-07 Zhongyu Wan , Tianyi Yang , Wenjun Xu , Ruiqin Zhang

Advances in theoretical calculations boosted the searches for high temperature superconductors, such as sulfur hydrides and rare-earth polyhydrides. However, the required extremely high pressures for stabilizing these superconductors…

Superconductivity · Physics 2024-09-09 Xiangru Tao , Aiqin Yang , Yundi Quan , Biao Wan , Shuxiang Yang , Peng Zhang